A New Strategy to Identify and Eliminate the Inner Filter Effects by Outer Filter Technique

To identify and eliminate the inner filter effects (IFEs), prepositive and side cells containing absorbents are fixed beside the fluorescer contained cell. In this way, excitation and emission lights can be quenched by primary and secondary outer filter effects respectively, depending on absorbent concentration and cell length. Herein the quenching of emission fluorescence caused by IFEs can be equally reduced by outer filter effects (OFEs) and the interference of IFEs was eliminated. This approach was experimentally used for identifying the interaction mode and mechanism between BSA and nanoAg. Results showed that the quenching of BSA fluorescence and synchronous fluorescence mainly attributes to IFEs, instead of static/dynamic fluorescent quenching. In view of the above, the elimination of the interference of IFEs by the design of OFEs plays an important part in the precise application of fluorescence detector.     

Effects of initial crystal size of diamond powder on surface residual stress and morphology in polycrystalline diamond (PCD) layer

Polycrystalline diamond compacts (PDC) were synthesized using diamond powder of average crystal size 3-20 μm by the Ni 70 Mn 25 Co 5 alloy infiltration technique at high temperature and high pressure (HPHT).The surface residual stress of polycrystalline diamond (PCD) layer was measured using micro-Raman spectroscopy with hydrostatic stress model and X-ray diffraction (XRD).Measurements of the stress levels of PCDs show that the residual compressive stresses range from 0.12 to 0.22 GPa,which increase with th...     

轴向核苷修饰硅酞菁与白蛋白非共价复合物的制备与光动力活性

通过荧光光谱法研究了5种轴向核苷(胞苷、氮杂胞苷、甲基胞苷、尿苷和甲基尿苷)衍生物修饰硅酞菁与牛血清白蛋白(BSA)的相互作用,结果表明,它们与BSA存在较强的相互作用,结合常数在(4.90~83.18)×105 mol-1·L之间。因此,进一步制备了二[5’-(2’,3’-O-异丙基)-胞苷氧基]硅酞菁(SiPc1)与BSA的非共价复合物(SiPc1-BSA),复合物中两者的摩尔比为1∶1。SiPc1-BSA与SiPc1在可见区的吸收光谱没有明显区别,两者的Q带最大吸收带均位于686nm附近,且吸收强度没有明显区别,这说明SiPc1结合到白蛋白后,其光谱性质没有受到明显改变。光动力抗癌活性测试表明,SiPc1-BSA具有较高的光动力抗癌活性,对人肝癌细胞HepG2的IC₅₀值为3.0×10-7 mol·L-1,且SiPc1-BSA的光动力活性高于SiPc1(PBS药剂形式,IC₅₀值为7.0×10-7 mol·L-1),这主要可归因于SiPc1-BSA具有更高癌细胞摄取率。     

Two types of loop algebras and their expanding Lax integrable models

Though various integrable hierarchies of evolution equations were obtained by choosing proper U in zero-curvature equation U_t-V_x+[U,V]=0, but in this paper, a new integrable hierarchy possessing bi-Hamiltonian structure is worked out by selecting V with spectral potentials. Then its expanding Lax integrable model of the hierarchy possessing a simple Hamiltonian operator \widetilde{J} is presented by constructing a subalgebra \widetilde{G } of the loop algebra \widetilde A₂. As linear expansions of the above-mentioned integrable hierarchy and its expanding Lax integrable model with respect to their dimensional numbers, their (2+1)-dimensional forms are derived from a (2+1)-dimensional zero-curvature equation.     

Study of photoconductivity and photoluminescence of organic/porous silicon complexes

In this paper, time-varying photoconductivity (PC) and the photoluminescence (PL) of different complexes were studied. Due to thick polymer layer hindering light penetrating into porous silicon (PS) layer, intrinsic PS luminescence in polymer/PS system disappeared. The physical origin of PL may be related to the recombination mechanisms involving surface defect states such as silicon oxide, siloxene. Due to carrier transfer controlled by different energy barrier, different devices prepared from different doped Si wafer showed opposite current-voltage characteristic.     

Construction of the elliptic Gaudin system based on Lie algebra

Gaudin model is a very important integrable model in both quantum field theory and condensed matter physics. The integrability of Gaudin models is related to classical r-matrices of simple Lie algebras and semi-simple Lie algebra. Since most of the constructions of Gaudin models works concerned mainly on rational and trigonometric Gaudin algebras or just in a particular Lie algebra as an alternative to the matrix entry calculations often presented, in this paper we give our calculations in terms of a basis of the typical Lie algebra, A _n , B _n , C _n , D _n , and we calculate a classical r-matrix for the elliptic Gaudin system with spin.      

光栅投影轮廓测量的系统标定技术

针对在光栅投影轮廓测量术中系统标定可操作性不强、精度不高的问题进行了全面的分析 ,在此基础上提出一种新的系统结构 ,并推导了物相关系。由于去掉了传统结构的平行和垂直两个约束条件 ,测量系统中摄像机和投影装置可以采取任意相对位置 ,操作十分灵活。对新系统提出了方便实用的标定方法 ,在其中引入了摄像机定标技术。应用该测量系统和标定技术进行实例检测 ,测量结果证明 :与传统方法相比 ,可操作性和检测精度得到了提高     

宁波市中小学生视力不良状况调查

为了解宁波市中小学生视力不良的发生率,以2010年浙江省学生体质调研数据为基础,对宁波市3085名中小学生视力进行了调查研究.结果表明:宁波市中小学生视力不良检出率为69.9%,其中男生为69.0%,女生为70.8%;城市学生视力不良检出率为71.2%,乡村学生为68.6%,可见城市学生的视力不良检出率高于乡村学生,并存在统计学意义(P<0.05);但这种城乡差异和2005年学生体质调研中得到的数据相比较,呈现弱化趋势;视力不良的检出率已不再有性别差异;在低年龄段和轻度视力不良程度内,视力不良检出率随年龄的增长突增期提前,中学学段是学生视力不良重灾区,同年龄段视力不良的检出率远超过2005年调查数据.     

P538萃取钒(Ⅳ)的研究

在20±0.5℃下，用P538环已烷溶液从硫氰酸盐介质中，萃取钒（Ⅳ）机理为离子交换机理，萃合物组成VO^2 :SCN^-:HA^-=1:1:1，萃取率为82.5%。