全文获取类型
收费全文 | 4304篇 |
免费 | 709篇 |
国内免费 | 399篇 |
专业分类
化学 | 2892篇 |
晶体学 | 62篇 |
力学 | 305篇 |
综合类 | 20篇 |
数学 | 433篇 |
物理学 | 1700篇 |
出版年
2024年 | 9篇 |
2023年 | 113篇 |
2022年 | 142篇 |
2021年 | 177篇 |
2020年 | 183篇 |
2019年 | 171篇 |
2018年 | 158篇 |
2017年 | 134篇 |
2016年 | 234篇 |
2015年 | 195篇 |
2014年 | 244篇 |
2013年 | 316篇 |
2012年 | 409篇 |
2011年 | 404篇 |
2010年 | 273篇 |
2009年 | 245篇 |
2008年 | 265篇 |
2007年 | 253篇 |
2006年 | 242篇 |
2005年 | 190篇 |
2004年 | 135篇 |
2003年 | 112篇 |
2002年 | 91篇 |
2001年 | 77篇 |
2000年 | 91篇 |
1999年 | 78篇 |
1998年 | 70篇 |
1997年 | 54篇 |
1996年 | 60篇 |
1995年 | 57篇 |
1994年 | 30篇 |
1993年 | 42篇 |
1992年 | 42篇 |
1991年 | 23篇 |
1990年 | 23篇 |
1989年 | 15篇 |
1988年 | 14篇 |
1987年 | 9篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 1篇 |
1983年 | 6篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有5412条查询结果,搜索用时 703 毫秒
41.
42.
In this paper, the spectral behavior of protein and Poniacyl Carmine 2B (PC 2B) has been studied by spectrophotometric method. The conditional constants, apparent combination constant K and maximum binding number n, were used to express the combination ability of the reactions between PC 2B and protein under a set of given conditions. The Sandell index s was used to express the sensitivity of the determination of protein. The factors, acidity, PC 2B concentration and the ionic strength, were discussed by the change of apparent combination constant and maximum binding number. It was found that acidity of the solution, PC 2B concentration and ionic strength had a significant effect on the sensitivity of the assay of protein. Under the optimal conditions, the apparent combination constant K and the maximum binding number n were 2.36 × 106 L mol?1 and 95, respectively. With further investigation, it was found that the Scatchard model was suitable in treating the data obtained in the experiments. In the buffer medium of HCl‐KCl at 1.87, the addition of protein made the maximum absorption of the system move from 527 nm to 513 nm. Its apparent molar absorptivity is 4.46 × 105 Lmol?1 cm?1 at 513 nm. Beer's law is obeyed in the range of 0 ? 55 μg mL?1. The system developed in this paper has been used for the determination of protein in milk powder successfully. 相似文献
43.
Wei L Yang B Yang R Huang C Wang J Shan X Sheng L Zhang Y Qi F Lam CS Li WK 《The journal of physical chemistry. A》2005,109(19):4231-4241
The photoionization and dissociative photoionization of acetone have been studied at the photon energy range of 8-20 eV. Photoionization efficiency spectra for ions CH3COCH3+, CH3+, C2H3+, C3H3+, C3H5+, CH(2-)CO+, CH3CO+, C3H4O+, and CH3COCH2+ have been measured. In addition, the energetics of the dissociative photoionization has been examined by ab initio Gaussian-3 (G3) calculations. The computational results are useful in establishing the dissociation channels near the ionization thresholds. With the help of G3 results, the dissociation channels for the formation of the fragment ions CH3CO+, CH2CO+, CH3+, C3H3+, and CH3COCH2+ have been established. The G3 results are in fair to excellent agreement with the experimental data. 相似文献
44.
45.
硫氰酸根的结构为N≡C-S-,其两端的N原子和S原子分别有一对和三对孤对电子,因此,硫氰酸根可采用多种不同的配位模式与金属离子发生配位。硫氰酸根可作为单齿配体与一个金属离子配位,形成M-SCN或M-NCS的单核配合物,也可以作为桥联配体同时与两个、三个甚至四个金属离子配位形成多核配合物犤1~3犦;另一方面,硫氰酸根是一个具有一定共轭性的偶极子,可传递磁相作用。因此,选择硫氰酸根作为桥联配体,将多个顺磁金属离子桥联形成一维、二维或三维结构的多核金属配合物分子,并研究它们的磁性已成为分子磁学的一个研究领域… 相似文献
46.
47.
48.
49.
50.
The keto-enol tautomerization of p-hydroxyphenylpyruvic acid (pHPP) in aqueous solutions and the complexation reaction between enolic pHPP and boric acid have been studied by electrochemical techniques including linear sweep voltammetry (LSV), pulse voltammetry, and cyclic voltammetry (CV), combining with UV spectrometry. Electrochemical techniques reveal that in aqueous solution, there are two tautomers of pHPP: enolic form and ketonic form; the former exists mainly in freshly prepared pHPP solution, and the latter exists mainly in equilibrium solution. Both enolic and ketonic pHPP are electroactive. The electrochemical oxidation of enolic pHPP gives rise to two anodic waves, I(a) and II(a), while the electrochemical oxidation of ketonic pHPP only results in the observation of the second wave II(a). The oxidation process I(a) is revealed to be associated with the quasi-reversible, two-electron two-proton oxidation of "C=C"group at the side chain of enolic pHPP, and the oxidation process II(a) is proposed to result from the irreversible oxidation of phenolic hydroxyl group. It is observed that in aqueous solution, enolic pHPP can quickly complex with boric acid to yield enol-borate complex that can also oxidize at a glassy carbon electrode to yield an anodic wave. 相似文献