全文获取类型
收费全文 | 4660篇 |
免费 | 584篇 |
国内免费 | 445篇 |
专业分类
化学 | 3426篇 |
晶体学 | 50篇 |
力学 | 261篇 |
综合类 | 36篇 |
数学 | 489篇 |
物理学 | 1427篇 |
出版年
2024年 | 18篇 |
2023年 | 75篇 |
2022年 | 126篇 |
2021年 | 174篇 |
2020年 | 153篇 |
2019年 | 170篇 |
2018年 | 152篇 |
2017年 | 129篇 |
2016年 | 217篇 |
2015年 | 185篇 |
2014年 | 234篇 |
2013年 | 328篇 |
2012年 | 324篇 |
2011年 | 368篇 |
2010年 | 249篇 |
2009年 | 247篇 |
2008年 | 274篇 |
2007年 | 250篇 |
2006年 | 253篇 |
2005年 | 180篇 |
2004年 | 171篇 |
2003年 | 147篇 |
2002年 | 175篇 |
2001年 | 131篇 |
2000年 | 106篇 |
1999年 | 110篇 |
1998年 | 95篇 |
1997年 | 85篇 |
1996年 | 52篇 |
1995年 | 71篇 |
1994年 | 60篇 |
1993年 | 50篇 |
1992年 | 51篇 |
1991年 | 31篇 |
1990年 | 36篇 |
1989年 | 15篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 26篇 |
1985年 | 24篇 |
1984年 | 17篇 |
1983年 | 15篇 |
1982年 | 12篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 10篇 |
1977年 | 4篇 |
1974年 | 7篇 |
1973年 | 7篇 |
1969年 | 4篇 |
排序方式: 共有5689条查询结果,搜索用时 15 毫秒
71.
Xiangming He Weihua Pu Jianguo Ren Li Wang Jiulin Wang Changyin Jiang Chunrong Wan 《Ionics》2008,14(4):335-337
The charge/discharge characteristics of the sulfur composite cathodes were investigated at different temperatures and different
current densities. The composite presented the discharge capacities of 854 and 632 mAh g−1 at 60 and −20 °C, respectively, while it had the discharge capacities of 792 mAh g−1 at 25 °C. The composite presented the discharge capacities of 792 and 604 mAh g−1 at 55.6 and 667 mA g−1, respectively, at room temperature. The results showed that the sulfur composite cathodes presented good charge/discharge
characteristics between 60 and −20 °C and at a high c-rate up to 667 mA g−1. 相似文献
72.
A Novel UWB Antenna with Small Side-Leakage 总被引:2,自引:0,他引:2
Wang Xianghui Jiang Yangsheng Wan Wenbing 《International Journal of Infrared and Millimeter Waves》2004,25(9):1325-1335
A successful design for a UWB (ultra-wideband antennas) antenna based on NRD-guide (nonradiative dielectric waveguide) with small side-leakage is presented. The rule of the theoretical selection of its parameters, if NRD-guide is used as the UWB antennas, is studied firstly, then the temporal propagation characteristics of the NRD-guide and the radiation characteristics for an tapered open-ended NRD-guide are calculated by FDTD (finite-difference time-domain) method. 相似文献
73.
Tomographic analysis of the central magnetohydrodynamic oscillations on the HT-7 tokamak 总被引:1,自引:0,他引:1 下载免费PDF全文
Multi-channel soft x-ray (SX) detectors are applied to generate images of
magnetohydrodynamic (MHD) oscillation on the HT-7 tokamak, and the data
from SX cameras are analysed by using the
Fourier--Bessel harmonic reconstruction method and the singular value
decomposition. The image
reconstruction of SX emissivity is obtained on the assumption of plasma
rigid rotation. One of the important phenomena in the HT-7 discharge is the
transition from the sawtooth oscillations to the MHD oscillations when the
plasma density grows higher. The MHD structure
observed in the SX tomography is featured as follows: the magnetic surface of MHD
structure is made up of the crescent-shaped ``hot core' and the circular
``cold bubble'. The structure of the magnetic surface is relatively stable.
It rotates in the direction of the electron diamagnetic drift at a
frequency being the oscillation frequency of the MHD oscillations. 相似文献
74.
通过微弧氧化法在Na3PO4+K2Cr2O7电解液中制备了系列铬掺杂二氧化钛薄膜. X射线和扫描电镜显示薄膜的主要晶相为锐钛矿型二氧化钛,且表面为多孔结构. 在可见光照射下,薄膜对降解亚甲基蓝和分解水有着较好的光催化性能,这主要是由铬的掺杂引起的.由于铬的掺杂,一方面在二氧化钛中形成了Cr3+/Cr4+离子对,另一方面在带隙中形成了氧的空位能级. 前者降低了电子-空穴的复合几率,而后者在二氧化钛的禁带中形成了新的能级. 新能级的形成使得由二氧化钛价带跃迁至氧空位能级所需的光子能量减少. 另外探讨了微弧氧化形成掺杂二氧化钛薄膜的机制. 相似文献
75.
Da-ping Wan Hong-bin Liu Yu-ming Wang De-jin Hu Zhen-xing Gui 《Optics & Laser Technology》2008,40(2):309-314
Laser texturing is a novel technique that may be used to texture a cold roller in the process of manufacturing high quality steel sheets. With the aim of improving the quality of the textured roller by using a CO2 laser, a new laser beam modulating device is proposed. An optical beam expander with a fast rotating chopper system is designed. The laser pulse is split into two parts by the chopper blades; one is the preheating pulse that is reflected onto optical loop mirrors; the other is the directly transmitted pulse that creates the craters at the preheated spots. The preheating beam focus spot size and position can be adjusted. The focusing characteristics and optical parameter compensation for the flying optics are investigated. The heat transfer and melt process of laser texturing are numerically simulated. The effects of the double pulses on the texturing are analyzed. The effect of preheating the sample ahead of the laser texturing pulse is examined. The surface profile and bump hardness show improvements by using this approach. 相似文献
76.
Wan Yupeng Lyu Heng Du Hengyi Wang Dunjia Yin Guodong 《Research on Chemical Intermediates》2019,45(4):1669-1687
Research on Chemical Intermediates - Two pentafluorinated β-diketone ligands, 4,4,5,5,5-pentafluoro-1-(4-methoxyphenyl)pentane-1,3-dione (PFMP) and 4,4,5,5,5-pentafluoro-1-(4-dimethyl... 相似文献
77.
Hanghang Wang Haiyan Li Yonggao Zheng Pengcheng Lian Prof. Dr. Xiaobing Wan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(9):2195-2198
In this communication, an unprecedented interception of CnF2n+1(O)SO. radical with a copper-based carbene has been established. Distinguished by wide substrate scopes and mild reaction conditions, this novel radical–carbene coupling reaction (RCC reaction) provides a fundamentally different and mechanistically interesting strategy for the synthesis of perfluoroalkanesulfinate esters. 相似文献
78.
79.
Abdul Q. Ramle Asli Karakas Abdul K. M. Arof Mustafa Karakaya Mehmet Taser Aysun Gozutok Chee Chin Fei Nurhidayatullaili M. Julkapli Wan J. Basirun 《Journal of heterocyclic chemistry》2020,57(10):3566-3573
Two new macrocyclic dibenzotetraaza[14]annulene (DBTAA) compounds with indolenine ( 5 ) and pyridoindolenine ( 6 ) moieties were synthesized and characterized by spectroscopy. Both DBTAAs exhibit strong UV-Vis absorption properties in the Soret band region. The theoretical second-order nonlinear optical property, electric dipole moment (μ), dispersion-free dipole polarizability (α) and first hyper-polarizability values were calculated by density functional theory and time dependent density functional theory. The ab-initio quantum mechanical calculation by time-dependent Hartree-Fock method was utilized to investigate the dynamic dipole polarizabilities, dynamic second-order, static, and dynamic third-order (γ) hyper-polarizabilities of the DBTAAs. The configuration interaction technique of all doubly occupied molecular orbitals possesses theoretically defined single-photon absorption (OPA) specifications for the examined structures. The computed maximum OPA wavelengths on both macrocyclic compounds coincide with the preceding measurement outcomes. 相似文献
80.
Pengcheng Lian Wenhao Long Jingjing Li Yonggao Zheng Prof. Dr. Xiaobing Wan 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(52):23809-23814
This work demonstrates photoredox vicinal dichlorination of alkenes, based on the homolysis of CuCl2 in response to irradiation with visible light. This catalysis proceeds via a ligand to metal charge transfer process and provides an exciting opportunity for the synthesis of 1,2-dichloride compounds using an inexpensive, low-molecular-weight chlorine source. This new process exhibits a wide substrate scope, excellent functional group tolerance, extraordinarily mild conditions and does not require external ligands. Mechanistic studies show that the ready formation of chlorine atom radicals is responsible for the facile formation of C−Cl bonds in this synthetic process. 相似文献