5,10,15-三(五氟苯基)Corrole及其相似卟啉化合物的光物理特性

采用稳态和时间分辨的瞬态光谱技术对比研究了一种Corrole化合物5,10,15-三(五氟苯基)Corrole(FtsTPC)和一种卟啉化合物5,10,15,20-四(五氟苯基)卟啉(F20TPP)的光物理特性.结果表明:F15TPC的B带吸收峰较宽而F20TPP的强而窄,F15TPC的Q带有两个吸收峰而F20TPP有四个.F15TPC的荧光量子产率为0.15,荧光寿命为4.8 ns,F20TPP的荧光量子产率为0.05,荧光寿命为11.1 ns;与F20TPP相比F15TPC具有发光效率高、荧光寿命短的特点.F15TPC具有较大的发光速率常数和无辐射跃迁速率常数,这可能是由于F15TPC少了一个氟代苯基,致使其发色团本身的电子结构发生变化所致.另外空间结构的不对称性和非共面性也对其光物理性质有影响.     

Scalable preparation of three-atom and four-atom W states via atom-cavity-laser interaction

We propose the optical generation of W states for three atomic and four atomic qubits, with each qubit trapped in a separate cavity and coupled to the cavity laser. A single-photon source and two classical fields are employed in the present scheme. By encoding the quantum information of each qubit on the degenerate ground states of the atom, we obtain the atomic entanglement that is relatively stable against spontaneous emission. It is demonstrated that the three- and four-atomic W states can be produced deterministically via a proper manipulation of the atom-cavity interaction sequence and time. Generalization of the present scheme to prepare multi-atomic W states is also discussed.     

Feature tracking for projection registration in laboratory-scale reflective tomography laser radar imaging

In range-resolved reflective tomography laser radar imaging system, for accurate image reconstruction, all projections must be aligned to the center of target rotation. Due to the unknown location of the axis of rotation and random target translation, the center of target rotation in each projection cannot be measured accurately and images reconstructed based on range-resolved projections without registration would be dislocated. Here, we apply a feature tracking method to align projections data for tomographic reconstruction in laboratory-scale laser radar imaging. The target was placed on a spin table with an unknown and fixed axis, and the oscillatory motion of the target translation was simulated by a second order inertia filter to accord with the real satellites vibrations. The experimental simulation results demonstrate the effectiveness of this method to improve images reconstruction equality. The application of this method to actual radar imaging in remote distance was discussed and the differences were compared with the lab setups.     

Image watermarking by using phase retrieval algorithm in gyrator transform domain

We propose an image watermarking scheme based on the phase retrieval algorithm in gyrator domain. The watermark is converted into a noise-like image by Arnold transform. The scrambled image is regarded as the amplitude of gyrator spectrum. The Gerchberg-Saxton algorithm is employed to obtain the unknown phase function in gyrator pair, in which the host image is the amplitude of input function. The phase information and the parameters of the two transforms serve as the key of watermarking algorithm. The numerical simulation has demonstrated the performance of the proposed algorithm.     

Effect of annealing temperature on structure, magnetic properties and optical characteristics in Zn0.97Cr0.03O nanoparticles

The Cr-doped zinc oxide (Zn_0.97Cr_0.03O) nanoparticles were successfully synthesized by sol-gel method. The relationship between the annealing temperature (400 °C, 450 °C, 500 °C and 600 °C) and the structure, magnetic properties and the optical characteristics of the produced samples was studied. The results indicate that Cr (Cr³⁺) ions at least partially substitute Zn (Zn²⁺) ions successfully. Energy dispersive spectroscopy (EDS) measurement showed the existence of Cr ion in the Cr-doped ZnO. The samples sintered in air under the temperature of 450 °C had single wurtzite ZnO structure with prominent ferromagnetism at room temperature, while in samples sintered in air at 500 °C, a second phase-ZnCr₂O₄ was observed and the samples were not saturated in the field of 10000 Oe. This indicated that they were mixtures of ferromagnetic materials and paramagnetic materials. Compared with the results of the photoluminescence (PL) spectra, it was reasonably concluded that the ferromagnetism observed in the studied samples was originated from the doping of Cr in the lattice of ZnO crystallites.     

CaWO4晶体中F型色心电子结构的研究

运用相对论的密度泛函离散变分法(DV-Xα)研究了CaWO₄晶体中F型色心的电子结构. 计算结果表明，F和F⁺心在禁带中引入了新的施主能级；分析了晶体内可能存在的光学跃迁模式，并通过过渡态的方法计算了F，F⁺心跃迁到导带底的能量分别为1.92eV和2.42eV. 因此，从理论上推断了F和F⁺心在CaWO₄晶体中可能引起650nm和515nm的吸收，由此说明CaWO₄晶体中650nm和515nm吸收带起源于晶体中的F和F⁺心. 关键词： 4晶体')" href="#">CaWO₄晶体 +心')" href="#">F和F⁺心 DV-Xα     

Taub-NUT时空视界附近自旋场的热力学量

利用Wentzel-Kramers-Brillouin近似计算了Taub-NUT时空事件视界附近自旋为1/2，1，3/2，2等无质量场的熵密度、压强和能量密度.结果表明，自旋场附近的热力学量不仅具有与平直时空相同的主导项，还多了两项自旋依赖的附加项. 关键词： Taub-NUT时空 自旋场 热力学量     

B2C(1A1)和BC2(2A′)的结构与解析势能函数

采用单双取代的二次组态相互作用方法，分别选用6-311++G(d,p)和6-311G(df,pd)基组，对B₂C和BC₂分子的结构进行了优化，得到这两个分子的基态结构为C_2v和C_s，基态电子状态为¹A₁和²A′，同时还得到了它们的平衡几何结构、离解能、谐振频率和力常数. 关键词： 碳化硼 Murrell-Sorbie函数 谐振频率 势能函数     

W波段二次谐波回旋行波管放大器的模拟与设计

回旋行波管放大器是一种具有高功率、高频率、宽带宽的毫米波放大器，TE₀₂模二次谐波回旋行波管放大器在保持基波回旋行波管放大器的基础上极大地减小了工作磁场,从而具有广阔的应用前景. 利用两段分布式损耗的互作用结构，有效抑制了绝对不稳定性和回旋返波振荡,避免了模式互作用电路引起的模式畸变，提高了输出功率，在一定程度上克服了谐波互作用较弱的缺点，满足了扩展功率容量和放大器长时间稳定工作的要求. 非线性模拟结果和粒子模型(particle in cell)模拟结果均表明，在工作电压为100k 关键词： W波段 二次谐波 回旋行波管放大器     

胆结石中蛋白质的傅里叶变换红外光谱和表面增强拉曼光谱研究

用氯仿、乙醚、乙醇和盐酸等溶剂溶解一组人体胆结石，获取难溶物；用傅里叶变换红外光谱和表面增强拉曼光谱对难溶剩余物进行研究。结果显示，结石难溶物主要由胆红素盐和蛋白质组成，结石中的蛋白质的二级结构以α螺旋和无规卷曲构象为主，其中α螺旋构象成分较多。讨论了蛋白质在胆结石形成中的作用。