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151.
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153.
Rational Design of an Ultrasensitive and Highly Selective Chemodosimeter by a Dual Quenching Mechanism for Cysteine Based on a Facile Michael‐Transcyclization Cascade Reaction
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Xiangmin Li Yongjun Zheng Hongjuan Tong Rui Qian Dr. Lin Zhou Prof. Dr. Guixia Liu Prof. Dr. Yun Tang Prof. Dr. Hao Li Prof. Dr. Kaiyan Lou Prof. Dr. Wei Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(27):9247-9256
Differentiation of biologically important thiols, such as cysteine (Cys), homocysteine (Hcy), and glutathione (GSH) is still a challenging task. Herein, we present a novel fluorescent chemodosimeter capable of selectively detecting Cys over other biothiols including Hcy and GSH and other amino acids by a facile thiol‐Michael addition/transcyclization rearrangement cascade click process. The unique transcyclization step is critical for the selectivity as a result of the kinetically favorable formation of a six‐membered ring with the Cys Michael adduct. Moreover, the probe adopts a distinctive dual quenching mechanism—photoinduced electron transfer (PET) and photoinduced intramolecular charge transfer (ICT) to deliver a drastic turn‐on fluorescence response only at the Cys‐selective transcylization step. The judicious selection of strong electron‐withdrawing naphthalimide fluorophore with maleimide group enhances the electrophilicity and thus reactivity for the cascade process leading to fast detection and ultrasensitivity with a detection limit of 2.0 nm (S/N=3). The probe has demonstrated its practical utility potential in Cys imaging in live cells. 相似文献
154.
L LinHui Ye YanLin Jiang DongXing Hua Hui Zheng Tao Li ZhiHuan Ge YuCheng Li XiangQing Lou JianLing Cao ZhongXin Song YuShou Xiao Jun Li QiTe Qiao Rui You HaiBo Chen RuiJiu Xu HuShan Wang JianSong Guo ZhongYan Zhang XueYing Li Chen Hu ZhengGuo Chen RuoFu Wang Meng Xu ZhiGuo Yue Ke Tang Bin Zang YongDong Zhang XueHeng Yao XiangWu Chen JinDa Bai Zhen 《中国科学:物理学 力学 天文学(英文版)》2011,54(1):136-140
Knockout reaction experiment was carried out by using the 6He beams at 61.2 MeV/u impinging on a CH2 target. The α core fragments at forward angles were detected in coincidence with the recoiled protons at larger angles. From this exclusive measurement the valence nucleon knockout mechanism and the core knockout mechanism can be distinguished by the relation between the polar angles of the core fragments and the recoiled protons, respectively. It is demonstrated that the core knockout mechanism may result in some strong contamination to the real invariant mass spectrum.
相似文献155.
Zhijun Yuan Qihong Lou Jun Zhou Jingxing Dong Yunrong Wei Zhijiang Wang Hongming Zhao Guohua Wu 《Optics & Laser Technology》2009,41(4):380-383
The effect of laser fluence on the crystallization of amorphous silicon irradiated by a frequency-doubled Nd:YAG laser is studied both theoretically and experimentally. An effective numerical model is set up to predict the melting threshold and the optimized laser fluence for the crystallization of 200-nm-thick amorphous silicon. The variation of the temperature distribution with time and the melt depth is analyzed. Besides the model, the Raman spectra of thin films treated with different fluences are measured to confirm the phase transition and to determine the optimized fluence. The calculating results accord well with those obtained from the experimental data in this research. 相似文献
156.
In this paper, we focus on the robust adaptive synchronization between two coupled chaotic neural networks with all the parameters unknown and time-varying delay. In order to increase the robustness of the two coupled neural networks, the key idea is that a sliding-mode-type controller is employed. Moreover, without the estimate values of the network unknown parameters taken as an updating object, a new updating object is introduced in the constructing of controller. Using the proposed controller, without any requirements for the boundedness, monotonicity and differentiability of activation functions, and symmetry of connections, the two coupled chaotic neural networks can achieve global robust synchronization no matter what their initial states are. Finally, the numerical simulation validates the effectiveness and feasibility of the proposed technique. 相似文献
157.
Based on some known facts of integrable models, this paper proposes a new (2+1)-dimensional bilinear model equation. By virtue of the formal series symmetry approach, the new model is proved to be integrable because of the existence of the higher order symmetries. The Lie point symmetries of the model constitute an infinite dimensional Kac- Moody Virasoro symmetry algebra. Making use of the infinite Lie point symmetries, the possible symmetry reductions of the model are also studied 相似文献
158.
Using front face-pumped compact active mirror laser (CAMIL) structure, we have demonstrated an Yb:YAG/YAG composite ceramic disk laser with pumping wavelength at 970 nm. The laser has been operated in both continuous-wave (CW) and Q-switching modes. Under CW operation, laser output power of 1.05 W with 2% transmission output coupler was achieved at the wavelength of 1031 nm. Q- switched laser output was gotten by using an acousto-optic Q-switch. The repetition rate ranged from 1 to 30 kHz and the pulse width varied from 166 to 700 ns. 相似文献
159.
Lou Y Chang J Jorgensen J Lemal DM 《Journal of the American Chemical Society》2002,124(51):15302-15307
The title compound, the first perhaloazulene, has been synthesized from hexachlorobutadiene and cyclopentadiene. Further chlorination of 1,3,4,5,6,7-hexachloroazulene results in addition, not substitution, under electrophilic as well as free radical conditions. Radical chlorination of the hexachloroazulene affords in good yield a single decachlorotetrahydroazulene. Treatment of this Cl(10) compound with one equiv of a phosphazene base gives a nonachlorodihydroazulene, but the addition of a second equiv results in dechlorination to 1,2,3,4,5,6,7-heptachloroazulene as well as dehydrochlorination to octachloroazulene. The former azulene is obtained cleanly from the Cl(9) compound with acid catalysis or by reduction with mercury. In the presence of calcium carbonate, however, the Cl(9) intermediate yields the dark green octachloroazulene. Although octachloronaphthalene is readily converted into its octafluoro counterpart, the isomeric octachloroazulene is far too sensitive to undergo the analogous transformation. 相似文献
160.
High-performance capillary electrophoresis with electrochemical detection was employed to analyse active ingredients of Rhododendron dauricum L., an important crude herb frequently used in Chinese medicines. Farrerol, quercetin, syringic acid, vanillic acid, 4-hydroxybenzoic acid, protocatechuic acid are major important active ingredients. Operated in a wall-jet configuration, a 300-microm diameter carbon-disk electrode was used as the working electrode, which exhibits a good response at +950 mV (vs. saturated calomel electrodes) for six analytes. Under the optimum conditions, the analytes were baseline separated within 16 min in a borax buffer (pH 8.7). Notably, excellent linearity was obtained over two orders of magnitude with detection limits (S/N=3) ranged from 9 x 10(-7) to 3.0 x 10(-6) M for all analytes. This method was successfully used in the analysis of Rhododendron dauricum L. with relatively simple extraction procedures, and the assay results were satisfactory. 相似文献