共聚物组成对线形苯乙烯-丁二烯-苯乙烯嵌段共聚物粘弹弛豫与相形态的影响

研究了不同组成的苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)的相形态与粘弹弛豫.用透射电子显微镜(TEM)表征了SBS的形态,结果显示,几种SBS均呈层状结构,随着苯乙烯含量的降低,聚苯乙烯(PS)相的尺寸稍有减小,而聚丁二烯(PB)相尺寸明显增大.用动态流变学方法考察了不同温度下SBS嵌段大分子的弛豫行为,结果表明,苯乙烯含量减少,PS相玻璃化转变和有序-无序转变温度均降低;苯乙烯含量少的,在有序-无序转变过程中呈现出高且宽的损耗峰,表明有序-无序转变过程中能量的耗散主要由两相溶合时分子链间的内摩擦所决定,分子链越长,内摩擦越大,能量耗散越大.     

Rapid analysis of multicomponent pesticide mixture by GC-MS with the aid of chemometric resolution

Applications of hyphenated chromatographic techniques, especially GC-MS technique, have been reported in chemical, biological, environmental, agricultural and medical analysis. The complexity of the samples in these fields is still an obstacle for the technique to be practical and the overlapping of the multicomponent signals induces chemometric methods widely employed. In this work, taking the rapid analysis of pesticide mixture as an example, a chemometric approach was proposed for resolution of multicomponent overlapping GC-MS signal. In the method, a mass spectral library of pesticides was organized at first, then target factor analysis (TFA) was employed for testing the existence of a specific pesticide in the multicomponent overlapping GC-MS signal, and finally the chromatographic information of the pesticide was extracted by a non-negative immune algorithm (IA). A GC-MS signal of a 40-component pesticide mixture eluted within 9 min was analyzed by the method. It was found that the mass spectra and chromatographic profiles of almost all the pesticides can be obtained.     

鱼鳔膜为基质的生物传感器测定葡萄糖的研究

以鱼鳔膜为基质同定葡萄糖氧化酶,偶联氧电极,构建了葡萄糖生物传感器,通过测定溶解氧浓度的变化定量测定葡萄糖.考察了酶浓度、pH值、缓冲液浓度对传感器的影响,优化了实验条件:即酶浓度为1 mg,pH 7.0,缓冲液浓度为100 mmol/L.此传感器具有较宽的线性范围(0.016～1.2 mmol/L),较短的响应时间(...     

Li+共掺杂对Er3+-Yb3+:TiO2紫外、可见和红外发光同步增强研究

采用溶胶-凝胶(Sol-gel)法制备了Li+共掺杂的Er3+-Yb3+:TiO2粉末.976 nm激光激发下在波长350～1700nm范围内观察到了紫外、蓝色、绿色和红色上转换发光和红外下转换发光.随着Li+共掺杂浓度由0增大到20mol%,Er3+-Yb3+:TiO2的紫外、可见和红外发光强度同步增强.低Li+共掺杂浓度引起的Li+固溶以及高Li+共掺杂浓度引起的相变过程相继破坏了Er3+的晶体场对称性,导致紫外、可见和红外发光显著增强.结果表明共掺杂Li+是一种提高Er3+掺杂材料发光性能的有效方法.     

离子液体[Cnpy][NTf2] (n=2, 4, 5)的动力粘度和电导率

在298.15-338.15 K和283.15-338.15 K温度范围内,分别测量了N-烷基吡啶双三氟甲磺酸亚胺(烷基链分别为:乙基、丁基、戊基)三种疏水型离子液体的动力粘度和电导率.利用Arrhenius 方程和Fulcher 方程将测量的动力粘度和电导率对温度拟合,得到了动力粘度和电导率随温度变化方程式.从电导率和密度计算出了上述三种离子液体在283.15-338.15 K温度范围内的摩尔电导率.应用Walden 规则,描述了动力粘度与摩尔电导率之间的关系.     

Study of emulsion polymerization stabilized by amphiphilic polymer nanoparticles

Submicron-sized polystyrene (PS) microspheres with a relatively narrow particle size distribution can be easily produced through emulsion polymerization induced by γ-ray at room temperature using a new type of amphiphilic cross-linked poly(stearyl methacrylate-co-acrylamide-co-acrylic acid) particles as stabilizer. The properties of these amphiphilic particles were described, including morphology, size, ζ potential, and contact angles. The effect of the pH value and the content of amphiphilic particles on the formation and stability of emulsions were also investigated. Meanwhile, the obtained PS microspheres were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, scanning electron microscopy and X-ray photoelectron spectroscopy. In addition, through observing the morphology and size of emulsion droplets at different times under an optical microscope, we found it is interesting that Pickering emulsions formed initially disappeared gradually, which is different from the common Pickering emulsions stabilized by inorganic particles. Thus, the mechanism was further discussed.     

Synthesis and properties of 5,10,15,20‐tetra[(4‐alkoxy‐3‐ethyloxy)phenyl]porphyrin hydroxylanthanide liquid crystal complexes

Twelve 5, 10, 15, 20‐tetra[(4‐alkoxy‐3‐ethyloxy)phenyl]porphyrin hydroxylanthanide complexes Ln[(C _n OEOP)₄P](OH) (n?=?12, 14, 16;Ln?=?Tb, Dy, Er, Yb) and three ligands have been synthesized and their composition, structure and spectral properties studied. Their liquid crystalline behaviour is also presented. Differential scanning calorimetry and polarizing optical microscopy reveal that all exhibit a discotic liquid crystalline phase. X‐ray diffraction shows that the mesophase is a hexagonal columnar, Col_h. The lanthanide ion, which is coordinated to the four nitrogen atoms of the porphyrin and to the oxygen atom of the hydroxyl group, is out of the porphyrin molecular plane. All the complexes are stable below 200°C and undergo complete decomposition at 800°C. The fluorescence quantum yields of the lanthanide complexes are much lower than those of the corresponding ligands. The electrochemical studies show that the redox potentials do not change on varying the chain length.     

Asymmetrical phenyldiacetylenes liquid crystalline compounds with high birefringence and characteristics of selective reflection

A series of asymmetrically disubstituted liquid crystalline compounds with high birefringence based on phenyldiacetylenes was synthesised by coupling of intermediate molecules with a phenylacetylene fragment. The structures of the intermediates and resulting compounds were confirmed by Fourier transform infrared, ¹H nuclear magnetic resonance and Matrix assisted laser desorption ionization-time of flight (MALDI-TOF) mass spectrometry. Their liquid crystalline behaviour, including transition temperatures and phase sequences, was investigated by differential scanning calorimetry and polarising optical microscopy. As an important parameter, the birefringence was also measured, using polarising light interferometry. The results indicated that the compounds exhibited different liquid crystalline phases in the high temperature region, with high birefringence values. In addition, the selective reflection characteristics associated with birefringence under conditions which maintained the matrix nematic liquid crystal and the concentration of chiral dopant were studied.     

Highly polarized absorption and emission from polymer-stabilized smectic guest-host systems

ABSTRACT

The optical properties of luminescent molecules dissolved in liquid crystals have led to their proposed use in luminescent thin-film polarizers. These molecules are typically required to fulfil a range of criteria related to their absorption and emission properties, degree of alignment and stability; however, concurrently satisfying these requirements has proven a barrier in their practical use. We obtained highly polarized absorption and emission luminescent thin-film polarizer using reactive liquid crystalline monomers and highly dichroic luminescent dyes, both of which have polymerizable end groups. In situ photopolymerization of the liquid crystalline mixtures in the highly ordered SmB phase resulted in the formation of cross-linked polymeric networks in which the anisotropic absorption and emission of the film were fixed. The as-obtained product exhibited a high dichroic ratio (DR = 30) with a large fluorescence quantum yield (?_F = 0.77). The device is both cheap and easy to fabricate and has the potential to be used in practical electro-optic applications.     

The crucial role of C—H...O and C=O...π interactions in the building of three‐dimensional structures of dicarboxylic acid–biimidazole compounds

The supramolecular architectures of three dicarboxylic acid–biimidazole compounds, namely, 2,2′‐biimidazolium malonate, C₆H₈N₄²⁺·C₃H₂O₄²⁻, (I), 2,2′‐bi(1H‐imidazole) succinic acid, C₆H₆N₄·C₄H₆O₄, (II), and 2,2′‐biimidazolium 2,2′‐iminiodiacetate chloride, C₆H₈N₄²⁺·C₄H₆NO₄⁻·Cl⁻, (III), are reported. The crystal structures are assembled by the same process, namely double conventional N—H...O or O—H...N hydrogen bonds link the dicarboxylates and biimidazoles to form tapes, which are stacked in parallel through lone‐pair–aromatic interactions between carbonyl O atoms and biimidazole groups and are further linked via weak C—H...O interactions. The C=O...π interactions involved in stacking the tapes in (II) and the C—H...O interactions involved in linking the tapes in (II) and (III) demonstrate the crucial role of these interactions in the crystal packing. There is crystallographically imposed symmetry in all three structures. In (I), two independent malonate anions have their central C atoms on twofold axes and two biimidazolium dications each lie about independent inversion centres; in (II), the components lie about inversion centres, while in (III), the unique cation lies about an inversion centre and the iminiodiacetate and chloride anions lie across and on a mirror plane, respectively.