全文获取类型
收费全文 | 10209篇 |
免费 | 1931篇 |
国内免费 | 1550篇 |
专业分类
化学 | 7986篇 |
晶体学 | 141篇 |
力学 | 636篇 |
综合类 | 99篇 |
数学 | 1341篇 |
物理学 | 3487篇 |
出版年
2024年 | 24篇 |
2023年 | 165篇 |
2022年 | 311篇 |
2021年 | 353篇 |
2020年 | 376篇 |
2019年 | 442篇 |
2018年 | 363篇 |
2017年 | 313篇 |
2016年 | 531篇 |
2015年 | 609篇 |
2014年 | 629篇 |
2013年 | 775篇 |
2012年 | 905篇 |
2011年 | 902篇 |
2010年 | 722篇 |
2009年 | 683篇 |
2008年 | 715篇 |
2007年 | 581篇 |
2006年 | 519篇 |
2005年 | 486篇 |
2004年 | 443篇 |
2003年 | 402篇 |
2002年 | 510篇 |
2001年 | 423篇 |
2000年 | 266篇 |
1999年 | 221篇 |
1998年 | 191篇 |
1997年 | 132篇 |
1996年 | 118篇 |
1995年 | 108篇 |
1994年 | 86篇 |
1993年 | 70篇 |
1992年 | 55篇 |
1991年 | 58篇 |
1990年 | 38篇 |
1989年 | 28篇 |
1988年 | 21篇 |
1987年 | 16篇 |
1986年 | 10篇 |
1985年 | 8篇 |
1984年 | 14篇 |
1983年 | 11篇 |
1982年 | 4篇 |
1981年 | 13篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1976年 | 3篇 |
1974年 | 5篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
WenXiangHU XueJunHOU QingTaoPENG 《中国化学快报》2002,13(12):1199-1202
In this paper,a new HPLC method was established to determine the earbonyl compounds in air.As the absorbent,2,4-dinitrophenylhydrazint(2,4-DNPH)reaeted with earbonyls specifieally,which form the corresponding 2,4-dinitrophenylhydrazones,then analyzed by HPLC.The chromatographic conditions,the recovery rate,stability of samples,reagent blank,sampling efficiency were all studied systematically.The results showed that this established method had high sensitivity and good selectivity compared with other analytical methods,and it can detemine ten earbonyl compounds in air in 26 min simultancously. 相似文献
62.
Lei Qiao Chao Zhang Xiang‐Wen Zhang Zi‐Chuan Wang Haolin Yin Zhong‐Ming Sun 《中国化学》2020,38(3):295-304
The polypnictide complexes of rare earth cations have drawn the attention of the scientific community for their uncommon bonding modes and potential applications. Herein, we present a systematic and comprehensive summary on recent advances in the field of rare earth polypnictides, focusing on their synthesis, structures, and reactivities. The structural stabilizing effects imposed by the electropositive rare earth cations as well as the reducing capability of rare earth precursors in the synthesis of these polypnictide complexes are described in this review. We also disscuss in detail the bonding interactions and coordination modes between rare earth cations and polypnictide clusters as well as the similarities and the peculiarity of some structures. 相似文献
63.
64.
Hae‐Jeong Lee Christopher L. Soles Da‐Wei Liu Barry J. Bauer Wen‐Li Wu 《Journal of Polymer Science.Polymer Physics》2002,40(19):2170-2177
X‐ray reflectivity has been used to determine the mass uptake of probe molecules in porous thin films supported on thick silicon wafers. The adsorption occurs by capillary condensation when the films are exposed to probe vapor at controlled partial vapor pressures. The probe solvent partial pressure was varied by mixing saturated air and dry air at constant temperature or by changing sample temperature at a constant vapor concentration. Pore size distribution in the films can be calculated from the probe uptake with typical porosimetric approaches such as the application of the Kelvin equation to convert partial pressure into pore size. For illustration, the pore size distribution of three different nanoporous thin films, the primary candidate of ultra‐low‐k interlevel dielectrics in the next generation of integrated circuit chips, was determined with this technique. These samples represent different generations of low‐k dielectrics developed by industry. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2170–2177, 2002 相似文献
65.
66.
Yonghong Wen Zhi Qin Weisheng Liu 《Journal of Radioanalytical and Nuclear Chemistry》2001,250(2):285-289
The extraction of Am3+ and Eu3+ from aqueous picric acid solution by N, N-dinaphthyl-N, N-diphenyl-3,6-dioxaoctanediamide (LI) and 1, 1-(3, 6, 9-trioxaundecanedionyl)diphenothiazine (LII) was investigated by a radioactive tracer technique. Extraction distribution ratios of Am3+ and Eu3+ have been measured as a function of pH, picric acid concentration, extractant concentration, diluent and temperature. The extraction of Am3+ is preferred to that of Eu3+ for both LI and LII, and the latter gives larger separation factor than the former. The equilibrium constants and thermodynamic parameters of extraction reactions were also calculated. 相似文献
67.
68.
69.
本文利用含氢有机硅化合物与含双键的氨基酸酯的加成反应,合成了5种新的有机硅氨基酸衍生物。介绍了一种合成N-烷基取代氨基酸酯的新方法。对新化合物进行了元素和光谱分析鉴定。 相似文献
70.
Chen Xia DU Zhi Qiang WANG Qi XIN Yang Jie WU Wen Lian LI Department of Chemistry Zhengzhou University Zhengzhou Changchun institute of optics Fine Mechanics Physics Chinese Academy of Sciences Changchun 《中国化学快报》2005,(5)
In recent years, the interest in developing luminescent lanthanide complexes has been greatly stimulated by their potential use in electroluminescent displays1. Europium complexes appear most attractive in view of the high photoluminescent efficiency and the high monochromatic red light that are widely exploited in full-color displays2. It has been approved that the second ligand plays an important role in europium complexes, the synergistic complexation of the second ligand can not only lead … 相似文献