全文获取类型
收费全文 | 8102篇 |
免费 | 1528篇 |
国内免费 | 1457篇 |
专业分类
化学 | 6070篇 |
晶体学 | 173篇 |
力学 | 540篇 |
综合类 | 102篇 |
数学 | 769篇 |
物理学 | 3433篇 |
出版年
2024年 | 17篇 |
2023年 | 112篇 |
2022年 | 252篇 |
2021年 | 324篇 |
2020年 | 373篇 |
2019年 | 322篇 |
2018年 | 316篇 |
2017年 | 310篇 |
2016年 | 409篇 |
2015年 | 459篇 |
2014年 | 597篇 |
2013年 | 705篇 |
2012年 | 703篇 |
2011年 | 780篇 |
2010年 | 631篇 |
2009年 | 581篇 |
2008年 | 666篇 |
2007年 | 625篇 |
2006年 | 551篇 |
2005年 | 437篇 |
2004年 | 339篇 |
2003年 | 265篇 |
2002年 | 263篇 |
2001年 | 248篇 |
2000年 | 167篇 |
1999年 | 129篇 |
1998年 | 83篇 |
1997年 | 81篇 |
1996年 | 79篇 |
1995年 | 55篇 |
1994年 | 33篇 |
1993年 | 40篇 |
1992年 | 22篇 |
1991年 | 24篇 |
1990年 | 22篇 |
1989年 | 12篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 9篇 |
1985年 | 11篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1979年 | 1篇 |
1971年 | 1篇 |
1957年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Summary By regarding geomaterials under loading as a mixture of intact and damaged parts, we investigate the influence of damage on the properties of strain localization in elastoplastic geomaterials at plane stress and plane strain. Conditions for the onset of strain localization including the effects of damage are derived for the cases of plane strain and plane stress. Discussed are the inclination of the localized band and the hardening modulus corresponding to the onset of strain localization. It is shown that the properties of the strain localization are dependent on the damage and the capacity of bearing hydrostatic pressure by the damaged part, and that damage may induce an earlier onset of strain localization and lead to instability of a geomaterial.accepted for publication 11 March 2004 相似文献
992.
本文将汽车绕流模块化为各典型局部流动,通过常用湍流模型对各典型局部流动进行数值模拟,结果验证了湍流模型对转捩的捕捉能力是准确模拟汽车绕流的关键. 在分析汽车绕流分离及转捩机理的基础上,优化了稳态和瞬态求解方法,改进了湍流模型对转捩的预测能力,进而提高了湍流模型在汽车流场模拟上的精度. 针对汽车绕流的稳态问题,将流线曲率因子及 响应阈值引入 LRN $k$-$\varepsilon $ (low Reynolds number $k$-$\varepsilon $) 模型,获得了一种能够更准确预 测转捩的改进低雷诺数湍流模型 (modified LRN $k$-$\varepsilon $),改善了原模型对湍流耗散率的过强依赖性及全应力发展预测不足等问题;针对汽车绕流瞬态求解,通过分析 RANS/LES 混合湍流模型的构造思想及特点,引入约束大涡模拟方法,结合本文提出的改进的 LRN $k$-$\varepsilon $ 湍流模型,提出了一种能准确捕捉转捩现象 的转捩 LRN CLES 模型. 分别将改进的模型用于某实车外流场和风振噪声仿真中,通过 Ansys Fluent 求解器计算,并将计算结果与常用湍流模型的仿真结果、HD-2 风洞试验结果和实车道路实验结果进行对比,表明改进后的湍流模型能够更准确模拟复杂实车的稳态和瞬态特性,为汽车气动特性的研究提供了可靠理论依据及有效数值解决方法. 相似文献
993.
994.
Synthesis of Carbon/Sulfur Nanolaminates by Electrochemical Extraction of Titanium from Ti2SC
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Meng‐Qiang Zhao Morgane Sedran Zheng Ling Maria R. Lukatskaya Olha Mashtalir Michael Ghidiu Boris Dyatkin Darin J. Tallman Prof. Thierry Djenizian Prof. Michel W. Barsoum Prof. Yury Gogotsi 《Angewandte Chemie (International ed. in English)》2015,54(16):4810-4814
Herein we electrochemically and selectively extract Ti from the MAX phase Ti2SC to form carbon/sulfur (C/S) nanolaminates at room temperature. The products are composed of multi‐layers of C/S flakes, with predominantly amorphous and some graphene‐like structures. Covalent bonding between C and S is observed in the nanolaminates, which render the latter promising candidates as electrode materials for Li‐S batteries. We also show that it is possible to extract Ti from other MAX phases, such as Ti3AlC2 , Ti3SnC2 , and Ti2GeC, suggesting that electrochemical etching can be a powerful method to selectively extract the “M” elements from the MAX phases, to produce “AX” layered structures, that cannot be made otherwise. The latter hold promise for a variety of applications, such as energy storage, catalysis, etc. 相似文献
995.
Revealing the Charge‐Transfer Interactions in Self‐Assembled Organic Cocrystals: Two‐Dimensional Photonic Applications
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Weigang Zhu Dr. Renhui Zheng Xiaolong Fu Prof. Hongbing Fu Prof. Qiang Shi Dr. Yonggang Zhen Dr. Huanli Dong Prof. Wenping Hu 《Angewandte Chemie (International ed. in English)》2015,54(23):6785-6789
A new crystal of a charge‐transfer (CT) complex was prepared through supramolecular assembly and it has unique two‐dimensional (2D) morphology. The CT nature of the ground and excited states of this new Bpe‐TCNB cocrystal (BTC) were confirmed by electron spin resonance measurements, spectroscopic studies, and theoretical calculations, thus providing a comprehensive understanding of the CT interactions in organic donor–acceptor systems. And the lowest CT1 excitons are responsible for the efficient photoluminescence (ΦPL=19 %), which can actively propagate in individual 2D BTCs without anisotropy, thus implying that the optical waveguide property of the crystal is not related to the molecular stacking structure. This unique 2D CT cocrystal exhibits potential for use in functional photonic devices in the next‐generation optoelectronic communications. 相似文献
996.
Fluorescent In Situ Targeting Probes for Rapid Imaging of Ovarian‐Cancer‐Specific γ‐Glutamyltranspeptidase
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Feiyi Wang Prof. Ying Zhu Li Zhou Liang Pan Zhifen Cui Qiang Fei Sihang Luo Dr. Dun Pan Prof. Rui Wang Prof. Chunchang Zhao Prof. He Tian Prof. Chunhai Fan 《Angewandte Chemie (International ed. in English)》2015,54(25):7349-7353
γ‐Glutamyltranspeptidase (GGT) is a tumor biomarker that selectively catalyzes the cleavage of glutamate overexpressed on the plasma membrane of tumor cells. Here, we developed two novel fluorescent in situ targeting (FIST) probes that specifically target GGT in tumor cells, which comprise 1) a GGT‐specific substrate unit (GSH), and 2) a boron–dipyrromethene (BODIPY) moiety for fluorescent signalling. In the presence of GGT, sulfur‐substituted BODIPY was converted to amino‐substituted BODIPY, resulting in dramatic fluorescence variations. By exploiting this enzyme‐triggered photophysical property, we employed these FIST probes to monitor the GGT activity in living cells, which showed remarkable differentiation between ovarian cancer cells and normal cells. These probes represent two first‐generation chemodosimeters featuring enzyme‐mediated rapid, irreversible aromatic hydrocarbon transfer between the sulfur and nitrogen atoms accompanied by switching of photophysical properties. 相似文献
997.
We report a self‐propelled Janus silica micromotor as a motion‐based analytical method for achieving fast target separation of polyelectrolyte microcapsules, enriching different charged organics with low molecular weights in water. The self‐propelled Janus silica micromotor catalytically decomposes a hydrogen peroxide fuel and moves along the direction of the catalyst face at a speed of 126.3 μm s?1. Biotin‐functionalized Janus micromotors can specifically capture and rapidly transport streptavidin‐modified polyelectrolyte multilayer capsules, which could effectively enrich and separate different charged organics in water. The interior of the polyelectrolyte multilayer microcapsules were filled with a strong charged polyelectrolyte, and thus a Donnan equilibrium is favorable between the inner solution within the capsules and the bulk solution to entrap oppositely charged organics in water. The integration of these self‐propelled Janus silica micromotors and polyelectrolyte multilayer capsules into a lab‐on‐chip device that enables the separation and analysis of charged organics could be attractive for a diverse range of applications. 相似文献
998.
999.
Inside Cover: Interception of Cobalt‐Based Carbene Radicals with α‐Aminoalkyl Radicals: A Tandem Reaction for the Construction of β‐Ester‐γ‐amino Ketones (Angew. Chem. Int. Ed. 4/2015)
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
1000.
Six known compounds, isoroquefortine C (1), griseofulvin (2), ergosterol peroxide (3), 3β-hydroxy-(22E,24R)-ergosta-5,8,22-trien-7-one (4), cerevisterol (5) and (22E,24R)-6β-methoxyergosta-7,22-diene-3β,5α-diol (6), were produced by the fungus Penicillium brasilianum, and their structures were elucidated by spectroscopic methods. This is the first report on isoroquefortine C as naturally occurring compound. Their bioactivities against five phytopathogenic fungi (Gibeberalla saubinetti, Fusarium solani, Botrytis cinerea, Colletotrichum gloeosporioides and Alternaria solani) and four pathogenic bacteria (Escherichia coli, Bacillus subtilis, Staphyloccocus aureus and Bacillus cereus), as well as allelopathic activities on Raphanus sativus were tested. Compound 1 exhibited a remarkable antifungal activity with minimum inhibitory concentration (MIC) of 12.5 μM against C. gloeosporioides, in comparison with positive control hymexazol (MIC 25 μM). Compound 2 displayed strong inhibitory effects on the growth of A. solani and S. aureus with MIC of 3.13 μM for each. Compounds 2 and 3 displayed a significant growth-inhibition activity on R. sativus. 相似文献