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11.
Yoshiaki Murata Cheng-Huang Lin Totaro Imasaka 《Fresenius' Journal of Analytical Chemistry》1993,346(6-9):543-544
Summary A supersonic jet spectrum of 9,10-dichloroanthracene is measured by stimulated-emission-pumping fluorescence dip spectrometry and conventional fluorescence spectrometry. The performance obtained is compared for these spectrometric methods, providing same information concerned with the energy level of the ground state. The former is more preferential for measurement of a high-resolution spectrum, since the spectral resolution is determined by the linewidth of the dumping laser. On the other hand, the latter is more preferential for measurement with better sensitivity at the expense of the spectral resolution, since the fluorescence throughput can be improved by increasing the slit width of the monochromator.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday 相似文献
12.
I. M. Karnaukh A. S. Moskovkin G. V. Ponomarev 《Chemistry of Heterocyclic Compounds》1994,30(1):20-25
The mass spectral behavior of 1, 2-di (mesoetioporphyr inyl-1)- and 1, 2-di (mesooctaethylporphyrlnyl) ethanes and ethylenes, their Cu and Ni complexes, as well as Ni Schiff bases of 1, 2-di (mesooctaethylporphyrinyl)ethane complexes, under ionization by electron impact and bombardment by accelerated atoms, was studied. Peaks of molecular ions, for which the basic decomposition pathways were established on the basis of an analysis of the parent and daughter ions, were observed in the electron impact mass spectra of all these compounds.For Communication 29, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 24–29, January, 1994. 相似文献
13.
S. V. Litvinenko V. I. Savich L. D. Bobrovnik 《Chemistry of Heterocyclic Compounds》1994,30(3):340-344
We have developed a method for synthesis of N-(3-clzloro-2-quinoxalyl)sulfonamides by reaction of 2,3-dichloroquinoxaline with substituted arylsufonamides. Based on the IR spectra, we have established that in the solid state, the synthesized compounds exist in the form of amide tautomers. Alkylation of these compounds leads to N-metliyl-N-(3-chloro-2-quinoxalyl)arylsulfonamides. We demonstrate the possibility of nucleophilic substitution of the halogen upon treatment with O- and N-nucleophiles. The use of bifunctional nucleophiles leads to condensed quinoxalines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 3, pp. 387–392, March, 1994. 相似文献
14.
A. Sh. Isamukhamedov N. P. Goncharova A. I. Glushetskova 《Chemistry of Natural Compounds》1994,30(2):170-174
The influence of sunflowerseed and cottonseed oils and also of fractions of normal and oxidized triacylglycerols isolated from them on cytochrome P-450 from rat liver microsomes has been investigated. 相似文献
15.
N. I. Khamidov B. T. Kadyrov N. T. Ul'chenko A. Sh. Isamukhamedov A. I. Glushenkova 《Chemistry of Natural Compounds》1994,30(4):430-433
The phsicochemical indices and the fatty-acid and triacylglycerol compositions of cottonseed and palm oils, of cottonseed
oil hydrogenate, and of compositions based on them have been determined with the aid of IR and UV spectroscopies, GLC analysis,
and chemical transformations. The compositions and amounts of the main classes of lipids in the initial oils and the hydrogenate
have been studied. It has been found that in the process of hydrogenation the amount of oxygenated components falls.
The work was conducted with the financial support of the Uzbek Fund for Fundamental Investigations. 相似文献
16.
V. I. Storozhev 《Journal of Mathematical Sciences》1995,77(6):3514-3518
On the basis of the method of successive approximations in formal series we construct systems of particular solutions of the
equations of planar and flexural harmonic vibrations of thin rectilinear anisotropic plates with a plane of symmetry of elastic
properties parallel to the faces. The solutions constructed are classified as special sk-functions of generalized complex
variables.
Translated fromTeoreticheskaya i Prikladnaya Mekhanika No. 24, 1993, pp. 54–61. 相似文献
17.
V. Palyok I.A. Szabó D.L. Beke A. Kikineshi 《Applied Physics A: Materials Science & Processing》2002,74(5):683-687
Surface relief formation at holographic recording on amorphous selenium films was demonstrated and investigated. The presence
of this optical phase modulation component is essential for ensuring significant, stable and erasable optical recording in
a-Se films at 290–320 K temperatures, where conventional photodarkening was known as insignificant and unstable. Photocrystallization
can only be observed in super-exposed a-Se films at the given experimental conditions of hologram recording. Erasing behavior
of surface relief gratings under heat treatment was also investigated in order to reveal further details of the mechanism.
Photoinduced structural transformations within the amorphous phase, connected to local ordering under the condition of light-induced
fluidity, are proposed as an explanation for the relief formation and erasing. The observed reversible optical recording process
may be useful for the various optoelectronic applications of photoconductive a-Se layers.
Received: 12 June 2000 / Accepted: 6 June 2001 / Published online: 30 August 2001 相似文献
18.
The simple relation between representations of the covering groups of SL2 and GL2 makes it possible to fuse and extend the recent metaplectic results of Shimura, Waldspurger, Flicker, and ourselves. By giving a new (purely local andL-function theoretic) treatment of the Waldspurger-Shintani correspondence, we also simplify some of Waldspurger’s original results. 相似文献
19.
The theory of tree-growing (RECPAM approach) is developed for outcome variables which are distributed as the canonical exponential family. The general RECPAM approach (consisting of three steps: recursive partition, pruning and amalgamation), is reviewed. This is seen as constructing a partition with maximal information content about a parameter to be predicted, followed by simplification by the elimination of ‘negligible’ information. The measure of information is defined for an exponential family outcome as a deviance difference, and appropriate modifications of pruning and amalgamation rules are discussed. It is further shown how the proposed approach makes it possible to develop tree-growing for situations usually treated by generalized linear models (GLIM). In particular, Poisson and logistic regression can be tree-structured. Moreover, censored survival data can be treated, as in GLIM, by observing a formal equivalence of the likelihood under random censoring and an appropriate Poisson model. Three examples are given of application to Poisson, binary and censored survival data. 相似文献
20.