全文获取类型
收费全文 | 4568篇 |
免费 | 669篇 |
国内免费 | 395篇 |
专业分类
化学 | 3294篇 |
晶体学 | 51篇 |
力学 | 240篇 |
综合类 | 23篇 |
数学 | 528篇 |
物理学 | 1496篇 |
出版年
2024年 | 8篇 |
2023年 | 111篇 |
2022年 | 172篇 |
2021年 | 181篇 |
2020年 | 166篇 |
2019年 | 150篇 |
2018年 | 141篇 |
2017年 | 109篇 |
2016年 | 202篇 |
2015年 | 208篇 |
2014年 | 251篇 |
2013年 | 285篇 |
2012年 | 349篇 |
2011年 | 391篇 |
2010年 | 241篇 |
2009年 | 238篇 |
2008年 | 283篇 |
2007年 | 260篇 |
2006年 | 235篇 |
2005年 | 200篇 |
2004年 | 167篇 |
2003年 | 152篇 |
2002年 | 127篇 |
2001年 | 103篇 |
2000年 | 90篇 |
1999年 | 114篇 |
1998年 | 105篇 |
1997年 | 93篇 |
1996年 | 92篇 |
1995年 | 83篇 |
1994年 | 56篇 |
1993年 | 34篇 |
1992年 | 37篇 |
1991年 | 33篇 |
1990年 | 25篇 |
1989年 | 17篇 |
1988年 | 21篇 |
1987年 | 20篇 |
1986年 | 13篇 |
1985年 | 9篇 |
1984年 | 15篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 9篇 |
1978年 | 2篇 |
1976年 | 7篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1972年 | 2篇 |
排序方式: 共有5632条查询结果,搜索用时 0 毫秒
11.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
12.
Wei Jun Liao Xianfeng Chen Fucheng Chen Yuping Chen Yuxing Xia Yingli Chen 《Optics & Laser Technology》2004,36(8):603-606
In this paper, we first report that a new proton source, glutaric acid, has been used to fabricate optical waveguides in Z-cut lithium niobate crystals. The relationship was experimentally established between proton-exchanged (PE) waveguide parameters and fabrication conditions. It is shown that this new organic acid can be used to obtain deep PE waveguides in fast diffusion speed (0.275 μm2/h at 221°C) and with low loss (0.2 dB/cm). It provides an alternative approach for fabricating PE waveguides in lithium niobate substrate. 相似文献
13.
1D-nanostructural zinc oxide (ZnO) with different shapes have been synthesized on p-type Si(1 0 0) and glass substrates via vapor phase growth by heating pure zinc powder at temperatures between 480 and 570 °C. The different ZnO nanostructures depend on the substrates and the growth temperatures. Scanning electron microscopy and X-ray diffraction revealed that a well-aligned nanowires array, which are vertical to the substrate of Si(1 0 0) with 18 sides on their heads, but six sides on their stems, has been formed at 480 °C. Raman study on the ZnO nanostructures shows that the coupling strength between electron and phonon determined by the ratio of the second- to the first-order Raman scattering cross-sections declines with decreasing diameter of the nanowires. However, a little changes of the coupling strength in terms of the width of the nanobelts have been observed. 相似文献
14.
A novel Y-branch waveguide with two reflectors is proposed. The normalized transmitted power for the branching angle of 50°is greater than 70%, which is higher than conventional Y-branch with such wide angle. 相似文献
15.
Tm3+/Yb3+-codoped germanate-niobic (GN) and germanium-bismuth (GB) glasses have been synthesized by conventional melting and quenching method. Intense blue and weak red emissions centered at 477 and 650 nm, corresponding to the transitions 1G4→3H6 and 1G4→3H4, respectively, were observed at room temperature. The possible up-conversion mechanisms are discussed and estimated. GN glass showed a weaker up-conversion emission than GB glass, which is inconsistent with the prediction from the difference of maximum phonon energy between GN and GB glasses. In this paper, Raman spectroscopy was employed to investigate the origin of the difference in up-conversion luminescence in the two glasses. Compared with phonon side-band spectroscopy, Raman spectroscopy extracts more information including both phonon energy and phonon density. For the first time, our results reveal that, besides the maximum phonon energy, the phonon density of host glasses is also an important factor in determining the up-conversion efficiency. 相似文献
16.
单模光纤中皮秒啁啾脉冲压缩 总被引:11,自引:2,他引:9
对单模光纤正群速色散区秒啁啾脉冲的非线性传进行了近似的解析分析和定量的数值计算。结果表明,负啁啾脉冲在传输过程中能得到有效压缩。压缩比与脉冲初始峰值功率和初始啁啾程度有关。初始峰值功率一定的脉冲,其压缩比随初始啁啾程度的增大面大,初始啁啾程度一定的脉冲,压缩比随初始峰值功率的增大而减小,表明自相位调制效应导致脉冲压缩效果变差。计算结果还表明,在脉冲时域宽度得到压缩的同时,光谱宽度也能得到同步压缩。 相似文献
17.
模拟退火法在吸收薄膜的椭偏反演算法中的应用 总被引:18,自引:4,他引:14
将一种广泛用于求解复杂系统优化问题的技术--模拟退火法--用来求解椭偏反演方程。首先假设一个薄膜模型,计算出其相应的椭偏参数(Ψ,Δ)的值,在这个计算值的基础上加入不同标准偏差的高斯噪声;然后将加入噪声后的值(Ψm,Δm)作为模拟的测量数据,采用模拟退火算法进行求解,验证得知这种方法求得的薄膜参数很接近于假设的薄膜模型参数的真值,与其他文献的报道结果一致,而且在扩大搜寻范围时,仍然可以得到准确解,从而证明了该方法的可行性以及有效性。 相似文献
18.
Feng S.-W. Tsai C.-Y. Cheng Y.-C. Liao C.-C. Yang C.C. Lin Y.-S. Ma K.-J. Chyi J.-I. 《Optical and Quantum Electronics》2002,34(12):1213-1219
A side-bump feature in a photoluminescence (PL) spectrum of an InGaN compound was widely observed. With reasonable fitting to PL spectra with three Gaussian distributions, the temperature variations of the peak positions, integrated PL intensities, and peak widths of the main and first side peaks of three InGaN/GaN multiple quantum well samples with different nominal indium contents are shown and interpreted. The existence of the side peaks is attributed to phonon–replica transitions. The variations of the peak position separations and the decreasing trends of the first side peak widths beyond certain temperatures in those samples were explained with the requirement of phonon momentum condition for phonon–replica transitions. In the sample with 25% nominal indium content, the phonon–replica transition could become stronger than the direct transition of localized states. 相似文献
19.
F.T. Yuan S.K. Chen W.M. Liao C.W. Hsu S.N. Hsiao W.C. Chang 《Journal of magnetism and magnetic materials》2006
The Au/FePt samples were prepared by depositing a gold cap layer at room temperature onto a fully ordered FePt layer, followed by an annealing at 800 °C for the purpose of interlayer diffusion. After the deposition of the gold layer and the high-temperature annealing, the gold atoms do not dissolve into the FePt Ll0 lattice. Compared with the continuous FePt film, the TEM photos of the bilayer Au(60 nm)/FePt(60 nm) show a granular structure with FePt particles embedded in Au matrix. The coercivity of Au(60 nm)/FePt(60 nm) sample is 23.5 kOe, which is 85% larger than that of the FePt film without Au top layer. The enhancement in coercivity can be attributed to the formation of isolated structure of FePt ordered phase. 相似文献
20.