3D amorphous carbon and graphene co-modified LiFePO4 composite derived from polyol process as electrode for high power lithium-ion batteries

Amorphous carbon and graphene co-modified LiFePO_4 nanocomposite has been synthesized via a facile polyol process in connection with a following thermal treatment.Various characterization techniques,including XRD.Mossbauer spectra,Raman spectra,SEM,TEM,BET,O_2-TPO,galvano charge-discharge,CV and EIS were applied to investigate the phase composition,carbon content,morphological structure and electrochemical performance of the synthesized samples.The effect of introducing way of carbon sources on the properties and performance of LiFePO_4/C/graphene composite was paid special attention.Under optimized synthetic conditions,highly crystalized olivine-type LiFePO_4was successfully obtained with electron conductive Fe_2P and FeP as the main impurity phases.SEM and TEM analyses demonstrated the graphene sheets were randomly distributed inside the sample to create an open structured LiFePO_4 with respect to graphene,while the glucosederived carbon mainly coated over LiFeP04 particles which effectively connected the graphene sheets and LiFePO_4 particles to result in a more efficient charge transfer process.As a result,favorable electrochemical performance was achieved.The performance of the amorphous carbon-graphene co-modified LiFePO_4 was further progressively improved upon cycling in the first 200 cycles to reach a reversible specificcapacity as high as 97 mAh·g~(-1) at 10 C rate.     

A Sensor for Serotonin and Dopamine Detection in Cancer Cells Line Based on the Conducting Polymer−Pd Complex Composite

An electrochemical sensor based on the conducting polymer composite with a palladium complex (Pd(C₂H₄N₂S₂)₂) was developed for the detection of serotonin and dopamine simultaneously in the breast cancer cell and human plasma samples. The proposed sensor was fabricated using the Pd(C₂H₄N₂S₂)₂ complex‐anchored poly2,2 : 5,2‐terthiophene‐3‐(p‐benzoic acid) (pTBA) layer on the AuNPs decorated reduced graphene oxide (AuNPs@rGO) substrate, which revealed the enhanced anodic current of the target species. The sensor probe was characterized by electrochemical and surface analysis methods. The experimental parameters affecting the sensor performance were optimized, in terms of AuNPs@rGO concentration, the number of electropolymerization cycle for pTBA, immobilization time of Pd(C₂H₄N₂S₂)₂, and pH. The dynamic ranges for serotonin and dopamine were obtained from 0.02 to 200 μM, and from 0.1 to 200 μM with the detection limit of 2.5, and 24.0 nM, respectively. The reliability of proposed sensor was evaluated using cancer cell lines for the clinical applications.     

Stochastic response and reliability of electromagnetic energy harvester with mechanical impact and Coulomb friction

Nonlinear Dynamics - Combining the complex factors of mechanical impact, Coulomb friction, harmonic excitation, and Gaussian white noise, an electromagnetic energy harvesting system is analytically...     

电子性作用对MgB2超导体同位素效应的影响

通过引入电子性作用V_c,在弱耦合条件下导出了两带模型的T_c公式和同位素效应指数公式,计算了超导体MgB_2的超导转变温度和同位素效应,得到了与实验相符的结果。结果表明,带内电子性作用比带间电子性作用对同位素效应指数的影响要大。     

基于队列式缓存结构的视频图像存储算法

针对视频图像数据实时存储过程中普遍存在的丢帧问题,通过深入分析典型的存储算法,找出实时存储过程中视频图像数据丢失的原因：计算机在连续存储相同大小的文件时,存储速度在一定的范围内波动.本文采用队列式缓存结构有效地消除了存储速度波动所带来的影响,保证了在数据流速小于磁盘平均存储速度的前提下,高速视频图像数据的实时存储,解决了丢帧问题.实践验证了该算法的可行性与可靠性.     

Cerium vanadate/carbon nanotube hybrid composite nanostructures as a high-performance anode material for lithium-ion batteries

The pristine CeVO4 and CeVO4/CNT hybrid composite nanostructured samples were facilely synthesized using a simple silicone oil-bath method.From the X-ray diffra...     

一种大视场相位测量轮廓术系统标定方法

在进行大视场相位测量轮廓术系统参量标定时需要大的标定平面和精密移动台,由于携带不方便,不易进行现场标定。提出了一种用于相位测量轮廓术系统参量的高精度、现场标定方法,采用一块较小的平面标定靶在有效测量体积内不同位置多次摆放,以获取密集的数据点。先标定出摄像机的内参量和外参量,再指定一个全局参考平面和若干辅助参考平面,然后在图像平面上分区计算出每个位置标定靶上每点相对辅助参考平面的高度差和相位差,最后应用极大似然估计法估计出相位高度映射参量。实验中平面高度测量的标准偏差达到0.0433 mm。这种方法只需要较小的平面标定靶,标定过程方便、精度高,完全适合大视场三维测量相位测量轮廓术系统现场标定要求。