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971.
A. Krämer-Flecken H. R. Koslowski Y. Liang O. Zimmermann W. Biel K. H. Finken X. Loozen O. Schmitz M. Tokar R. Wolf S. Soldatov V. Vershkov 《Czechoslovak Journal of Physics》2005,55(3):295-306
Within the last year of TEXTOR operation a major part of the experiments were dedicated to the interaction of the ergodized plasma edge, induced by the dynamic ergodic divertor (DED), with the core plasma. Systematic experiments are performed in the 3/1 configuration of the DED. Depending on , the DED generates a locked 2/1 mode in the plasma at a critical current in the DED coils. Different diagnostics were used to measure the plasma response in the core and edge. The investigations in this paper are focused on the measurement of density fluctuation and the analysis of the coherent-mode structure outside the q = 2 surface using O-mode poloidal correlation reflectometry. A reduction of the quasi-coherent mode amplitude and frequency is observed, caused by the 2/1 mode together with a decrease of the density scale length. Moreover, the deduced poloidal rotation velocity at the q = 3 surface changes from the electron to the ion diamagnetic drift direction with the onset of the 2/1 island. Also a reduction of the density fluctuations is observed as well as a decrease in the poloidal correlation length. From Ar-injection a delayed inward propagation of the emission maximum is observed for different Ar ionization stages when the 2/1 mode is generated.Similar experiments with a slowly rotating DED show that the steepened density gradients are spatially localized and confirm the hypothesis that the 2/1 mode is responsible for the observations.Presented at the Workshop Electric Fields Structures and Relaxation in Edge Plasmas, Nice, France, October 26–27, 2004. 相似文献
972.
The second-order partial derivative of the Stokes signal with respect to frequency and position shows a maximum or minimum at the boundary between two different strained sections. This idea is used to locate the boundary of different stress regions. Knowing the boundaries, we then fit the Brillouin spectrum at the middle between them to get the strain value. This allows a location accuracy of between 5 and 10 cm, which is shorter than the pulse length of 20 cm used in the experiment. The lowest detectable Brillouin frequency difference between two strain sections is 1.2 MHz. 相似文献
973.
974.
Miao W Luo X Wu S Liang Y 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(1-2):413-416
Order-disorder transitions of 9-monolayer Langmuir-Blodgett (LB) films of 7-(2-octadecyloxycarbonylethyl)guanine (ODCG) before and after recognition to cytidine were investigated by Fourier transform infrared (FTIR) spectroscopy. The different order-disorder transitions suggest that molecular recognition between ODCG and cytidine influence these two LB films on the order-disorder process of alkyl tailchain. Cleavage of the multi-hydrogen bonds was also observed by the infrared spectroscopy at elevated temperature. 相似文献
975.
976.
Wuu-Jyh Liang Chien-Pang Wu Ping-Lin Kuo 《Journal of Polymer Science.Polymer Physics》2004,42(10):1928-1937
Organic–inorganic hybrid nanocomposites of poly(ethylene glycol)/siloxane were obtained via the sol–gel approach. In these composites, nanometric siloxane heterogeneity was embedded into a polymer matrix with a covalent bond at the interfaces. The 29Si magic-angle spinning (MAS) spectrum exhibited a high degree of condensation through the relative abundance of T0 [RSi(OR)3], T1 [RSi(OR)2(OSi)], T2 [RSi(OR)(OSi)2], and T3 [RSi(OSi)3] silicone nuclei. The effect of lithium salt concentration on ionic interaction, conductivity, and thermal properties of these composite electrolytes were investigated by Fourier transform infrared spectroscopy, DSC, thermogravimetric analysis, alternating current impedance, and solid-state 7Li MAS NMR measurements. These observations indicated that the different types of complexes by the interactions of Li+ and ClO ions are formed within a hybrid host, and the formation of transient crosslinks between Li+ ions and the ether oxygens results in an increased glass-transition temperature of the polyether segment and decomposed rate of composite electrolyte. 7Li MAS NMR measurements revealed the changes in line shape of lithium resonances with different LiClO4 contents, suggesting that a significant degree of ionic association is present in the polymer-salt complexes. The behavior of ion transport in these composite electrolytes was correlated with the interactions between ions and polymer host. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1928–1937, 2004 相似文献
977.
By combining supercritical drying technique with AAO template-assisted electrodeposition, noncollapsed, vertically aligned, and free-standing nanowire arrays on a conductive Au film have been fabricated. We also demonstrate that these free-standing nanowire arrays can be feasibly used for fabricating nanowire-based electrically driven devices. 相似文献
978.
Asymmetric catalysis with CO2: direct synthesis of optically active propylene carbonate from racemic epoxides 总被引:3,自引:0,他引:3
Lu XB Liang B Zhang YJ Tian YZ Wang YM Bai CX Wang H Zhang R 《Journal of the American Chemical Society》2004,126(12):3732-3733
This communication describes a convenient route to optically active propylene carbonate by a catalytic kinetic resolution process resulting from the coupling reaction of CO2 and racemic epoxides using simple chiral SalenCo(III)/quaternary ammonium halide catalyst systems. 相似文献
979.
Since two solvent polarity parameters, e.g., the Et(30) defined by Reichardt and the pi* defined by Kamlet and Taft, respectively, plotted with the K coefficient of the Mark-Houwink-Sakurada equation, presented good linear fits, this paper suggests applying the extrapolating method in the same way as the Zisman plot to obtain similar polarity parameters for polymers. In order to verify those obtained polarity parameter values for various polymers, literature-reported polarity values determined using other techniques are referenced and indicate that this paper introduced a simplified approach that can be applied to evaluate the polarity parameters for polymers. In this paper, since we observe that various polymers are of interest to present absolutely different slope tendencies, e.g., positive and negative, it is also suggested that polarity properties of polymers may be reinterpreted. 相似文献
980.
For the first time, three peralkylated-beta-cyclodextrins (beta-CD), permethylated-beta-CD, perethylated-beta-CD and perpentylated-beta-CD, were coated onto the fused-silica capillary by sol-gel method with simplicity and rapidity. Multiple steps in conventional column preparation technology were avoided. Also, these new columns demonstrated many inherent advantages, the main being the outstanding thermal stability (up to 300 degrees C), high number of theoretical plates, excellent column-to-column and run-to-run reproducibility, and pronounced selectivity for positional isomers and enantiomers. Using n-tridecane as a test reagent (k = 4.18), an efficiency value of 3520 theoretical plates/m was obtained on a sol-gel perpentylated-beta-CD capillary column (15 m x 0.25 mm I.D.). On the basis of the results, we proposed that the peralkylated-beta-CD, which has no terminal hydroxyl group, is encapsulated in the sol-gel network and the whole matrix is chemically bonded to the surface of the fused-silica tubing. 相似文献