全文获取类型
收费全文 | 36409篇 |
免费 | 6773篇 |
国内免费 | 5750篇 |
专业分类
化学 | 26873篇 |
晶体学 | 575篇 |
力学 | 2329篇 |
综合类 | 395篇 |
数学 | 4014篇 |
物理学 | 14746篇 |
出版年
2024年 | 108篇 |
2023年 | 658篇 |
2022年 | 1305篇 |
2021年 | 1426篇 |
2020年 | 1474篇 |
2019年 | 1530篇 |
2018年 | 1326篇 |
2017年 | 1364篇 |
2016年 | 1788篇 |
2015年 | 1978篇 |
2014年 | 2396篇 |
2013年 | 2989篇 |
2012年 | 3488篇 |
2011年 | 3522篇 |
2010年 | 2619篇 |
2009年 | 2678篇 |
2008年 | 2896篇 |
2007年 | 2404篇 |
2006年 | 2232篇 |
2005年 | 1798篇 |
2004年 | 1344篇 |
2003年 | 1129篇 |
2002年 | 1144篇 |
2001年 | 926篇 |
2000年 | 748篇 |
1999年 | 616篇 |
1998年 | 444篇 |
1997年 | 403篇 |
1996年 | 354篇 |
1995年 | 286篇 |
1994年 | 289篇 |
1993年 | 224篇 |
1992年 | 175篇 |
1991年 | 143篇 |
1990年 | 139篇 |
1989年 | 88篇 |
1988年 | 80篇 |
1987年 | 61篇 |
1986年 | 70篇 |
1985年 | 47篇 |
1984年 | 24篇 |
1983年 | 28篇 |
1982年 | 13篇 |
1981年 | 14篇 |
1980年 | 9篇 |
1979年 | 19篇 |
1978年 | 7篇 |
1977年 | 11篇 |
1957年 | 8篇 |
1925年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
92.
A computational kinetics model of the CuBr laser with added hydrogen is presented. The space-time behaviour of the lasers and lasants is described in detail. Besides the discharge field, it is confirmed that the dissociation/recombination of the CuBr molecule plays an important role in the plasma electron temperature. The radial field, which peaks at 30% of the discharge field and has two opposite directions along the radius, results in the skin of electron density and the black centre of the large-bore laser beam. 相似文献
93.
94.
95.
96.
The convection in atmosphere discussed in ref. [1] is rigorously treated by considering the variation of environmental temperature
with the height. This represents an example of applications of the elementary catastrophe theory in Hamiltonian systems. 相似文献
97.
98.
Upon the electrochemical oxidation of tris(2,2′-bipyridyl) ruthenium(II) [Ru(bpy)2+3] and hydroxyl carboxylic acids, for instance, citric acid, tartaric acid, malic acid, and
-gluconic acid, bright electrochemiluminescences (ECLs) were observed. Different luminescent reactions were presented depending on the applied potential. The light emission was mainly caused by the reaction between alkoxide radical ion and Ru(bpy)3+3below the potential +1.80 V (vs Ag/AgCl). The luminescence intensity obviously increased because of the more complex reaction process. The luminescence wavelength of 608 nm, which could be found either at higher potential than +1.80 V or in the potential range from +1.30 to +1.80 V, confirmed that ECL was caused by Ru(bpy)2+3*. The factors which affect the determination and HPLC separation of the four acids were also investigated. 相似文献
99.
A series of ferrocenylaldimines (Fc-CH=N-R) has been prepared by Schiff base condensation of formylferrocene with polyacenylamines RNH2 where R = naphthyl, 5,6,7,8-tetrahydronaphthyl, anthracenyl, and pyrenyl groups. This step was followed by oxidation with TCNQ to give [Fc-CH = N-R][TCNQ]2 salts. The electronic state of iron in these compounds was investigated by means of57Fe Mössbauer spectroscopy. 相似文献
100.
Vinyl-containing poly(acrylic acid-co-itaconic acid) copolymers were synthesized and used to formulate light-curable cements containing reactive glass fillers (Fuji II LC). The conditions for light curing were studied and optimized. Effects of molecular weight (MW), grafting ratio, comonomer, liquid composition, powder/liquid (P/L) ratio, glass powder and aging were evaluated. The results show that the vinyl-containing glass-ionomer cements (GICs) prepared in this study exhibit higher compressive strength (CS, 225.6 MPa), diametral tensile strength (DTS, 28.4 MPa) and much higher flexural strength (FS, 116.4 MPa), as compared to commercial Fuji II LC GIC (186.6 in CS, 19.1 in DTS and 57.1 in FS). The optimal light-exposure time was found to be around 10 min, and concentrations of CQ and DC were 0.5% (by weight) and 1.0%, respectively. Effects of MW, grafting ratio, P/L ratio and content of polymer in the liquid formulation were significant. The highest strengths were found for the optimal formulations where the MW was 15,000 (weight average), grafting ratio 25 mol%, P/L ratio 2.7 and liquid composition 50:20:30. During aging, the cement showed an increase of strength over the first week and then no change for a month. SEM analysis suggests that more integrated microstructures and smaller glass particles can lead to higher FS and higher polymer content in GICs leads to tough fracture surface and plastic deformation. 相似文献