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Ⅱ-Ⅵ族半导体激光器的新材料——ZnO量子点 总被引:7,自引:0,他引:7
介绍了研制Ⅱ-Ⅵ族半导体激光器方面的一个新途径--自组织生长ZnO量子点微晶结构、ZnO已经实现了室温下光泵激发的受激发射,它将是继Ⅱ-Ⅵ族硒化物、Ⅲ-Ⅴ经物之后的又一种半导体激光器材料。 相似文献
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Flow-area (QA) method and ln(diameter)-velocity (ln(D)U) methods based on si-multaneous measurements of velocity (U) and arterial diameter (D) using ultrasound ... 相似文献
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Synthesis, Crystal Structure and Photoluminescent Property of a 3D Hydrogen-bonded Supramolecular Compound with Large Channels 总被引:1,自引:1,他引:0
YUE Cheng-Yang JIANG Fei-Long YUAN Da-Qiang CHEN Lian WU Ming-Yan HONG Mao-Chun 《结构化学》2008,27(4):467-470
The title compound, [Pd(2,2′-bipy)2](Haadip)2·4H2O, was synthesized via the hydrothermal reaction of PdCl2 with 5-aminodiacetic isophthalic acid (H4adip) in an acetic acid water solution. It was characterized by elemental analysis and infrared spectrum. Crystal data for C44H44N6O20Pd: monoclinic, space group P21/n, a = 11.0674(2), b = 9.9716(2), c= 20.5770(3)A, β = 92.7300(3)°, V = 2268.29(7)A^3, Z = 2, Mr = 1083.25, Dc = 1.586 g/cm^3, F(000) = 1112,μ = 0.499 mm^-1, 2(MoKa) = 0.71073 A, T = 293(2) K, 2θmax = 51.38°, GOOF = 1.067, R = 0.0268 and wR = 0.0710 for 3770 reflections with 1 〉 2σ(I). X-ray diffraction studies reveal that the title compound has an interesting 3D microporous architecture via hydrogen bonds with the cations located inside the channel. 相似文献
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Zoë C. Adams Erika J. Olson Tania L. Lopez-Silva Zhengwen Lian Audrey Y. Kim Matthew Holcomb Jrg Zimmermann Ramkrishna Adhikary Philip E. Dawson 《Chemical science》2022,13(34):10020
The characterization of self-assembling molecules presents significant experimental challenges, especially when associated with phase separation or precipitation. Transparent window infrared (IR) spectroscopy leverages site-specific probes that absorb in the “transparent window” region of the biomolecular IR spectrum. Carbon–deuterium (C–D) bonds are especially compelling transparent window probes since they are non-perturbative, can be readily introduced site selectively into peptides and proteins, and their stretch frequencies are sensitive to changes in the local molecular environment. Importantly, IR spectroscopy can be applied to a wide range of molecular samples regardless of solubility or physical state, making it an ideal technique for addressing the solubility challenges presented by self-assembling molecules. Here, we present the first continuous observation of transparent window probes following stopped-flow initiation. To demonstrate utility in a self-assembling system, we selected the MAX1 peptide hydrogel, a biocompatible material that has significant promise for use in drug delivery and medical applications. C–D labeled valine was synthetically introduced into five distinct positions of the twenty-residue MAX1 β-hairpin peptide. Consistent with current structural models, steady-state IR absorption frequencies and linewidths of C–D bonds at all labeled positions indicate that these side chains occupy a hydrophobic region of the hydrogel and that the motion of side chains located in the middle of the hairpin is more restricted than those located on the hairpin ends. Following a rapid change in ionic strength to initiate self-assembly, the peptide absorption spectra were monitored as function of time, allowing determination of site-specific time constants. We find that within the experimental resolution, MAX1 self-assembly occurs as a cooperative process. These studies suggest that stopped-flow transparent window FTIR can be extended to other time-resolved applications, such as protein folding and enzyme kinetics.To facilitate the characterization of phase-transitioning molecules, site-specific non-perturbative infrared probes are leveraged for continuous observation of the self-assembly of fibrils in a peptide hydrogel following stopped-flow initiation. 相似文献
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Incompressible multiphase flow and encapsulation simulations using the moment‐of‐fluid method 下载免费PDF全文
Guibo Li Yongsheng Lian Yisen Guo Matthew Jemison Mark Sussman Trevor Helms Marco Arienti 《国际流体数值方法杂志》2015,79(9):456-490
A moment‐of‐fluid method is presented for computing solutions to incompressible multiphase flows in which the number of materials can be greater than two. In this work, the multimaterial moment‐of‐fluid interface representation technique is applied to simulating surface tension effects at points where three materials meet. The advection terms are solved using a directionally split cell integrated semi‐Lagrangian algorithm, and the projection method is used to evaluate the pressure gradient force term. The underlying computational grid is a dynamic block‐structured adaptive grid. The new method is applied to multiphase problems illustrating contact‐line dynamics, triple junctions, and encapsulation in order to demonstrate its capabilities. Examples are given in two‐dimensional, three‐dimensional axisymmetric (R–Z), and three‐dimensional (X–Y–Z) coordinate systems. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献