胆固醇修饰富勒烯/γ-环糊精包结复合物的生物活性

采用Bingel-Hirsch反应合成了胆固醇修饰的富勒烯(CHL-C60), 通过核磁共振(NMR)、质谱(MS)、元素分析对CHL-C60的化学结构进行了表征. γ-环糊精(γ-CD)对甾环具有较强的包结能力, 能够与CHL-C60形成包结复合物(CHL-C60/γ-CD), 从而有效提高CHL-C60的水溶性. 紫外-可见吸收光谱和荧光光谱研究结果表明, CHL-C60能够从γ-CD的疏水空腔中解离出来, 与人血清白蛋白(HSA)及牛血清白蛋白(BSA)形成稳定的复合体, 其结合常数分别为5.73×104和7.05×104 L·moL-1. 无氧条件下, CHL-C60/γ-CD通过光诱导电子转移作用断裂pBR322质粒脱氧核糖核酸(DNA), 其效率可达60.5%.     

带极性侧链的环[6]芳酰胺的球形自组装

环芳酰胺是一类基于三中心氢键促进,经寡聚前体一步大环合成法得到的刚性大环分子.通过紫外-可见(UV-Vis)光谱、动态光散射(DLS)、扫描电镜(SEM)、透射电镜(TEM)和原子力显微镜(AFM)等实验手段,详细考察了侧链为三甘醇单甲基醚链,由六个苯环单元组成的环[6]芳酰胺的自组装行为.实验结果表明,该大环在1,2-二氯乙烷中发生自组装,其组装聚集体随温度升高产生从聚集体到单分子的解聚变化,至70℃时几乎完全解聚;在由良溶剂(二氯甲烷)和不良溶剂(芳烃类)组成的混合溶剂中,带有三甘醇醚链的环[6]芳酰胺化合物1自组装成微球,结合热稳定性实验和TEM证实是实心微球而非囊泡.进一步发现微球形成和形貌依赖于混合溶剂中不良溶剂的极性和种类,芳烃类溶剂有利于微球形成,而烷烃和极性溶剂则不利,后者更倾向于形成膜的结构.     

Syntheses,Structural Characterization and Thermoanalysis of Transition-Metal Compounds Derived from 3,5-Dinitropyridone

Abstract  

Nine metal compounds of Mn(II), Zn(II) and Cd(II) derived from dinitropyridone ligands (3,5-dinitropyrid-2-one, 2HDNP; 3,5-dinitropyrid-4-one, 4HDNP and 3,5-dinitropyrid-4-one-N- hydroxide, 4HDNPO) were characterized by elemental analysis, FT-IR and partly by TG-DSC. Three of which were further structurally characterized by X-ray single-crystal diffraction analysis. The structures of the three compounds, Mn(4DNP)₂(H₂O)₄, 4, Zn(4DNPO)₂(H₂O)₄, 8, and Cd(4DNPO)₂(H₂O)₄, 9, crystallize in the monoclinic space group P2(1)/n and Z = 2, with a = 8.9281(9), b = 9.1053(9), c = 10.6881(11) Å, β = 97.9840(10)° for 4; a = 8.4154(7), b = 9.9806(8), c = 10.5695(8) Å, β = 97.3500(10)° for 8; a = 8.5072(7), b = 10.2254(8), c = 10.5075(8) Å, β = 96.6500(10)° for 9. All three complexes are octahedral consisting of four equatorial water molecules, and two nitrogen or oxygen donor ligands (DNP or DNPO). The abundant hydrogen-bonding and π-π stacking interactions seem to contribute to stabilization of the crystal structures of the compounds. The TG-DTG results revealed that the complexes showed a weight loss sequence corresponding to all coordinated water molecules, nitro groups, the breaking of the pyridine rings and finally the formation of metal oxides.     

Storage of Maximal Wigner-Yanase Skew Information of Two-Qubit System Using Nonlinear Interactions with Decay

The decay mechanism is considered in some nonlinear interaction models for two-qubit system. Exact expression of the final states of two-qubit are given for different model. We find that the maximal Wigner-Yanase skew information can be modulated and stored via using decay mechanism and nonlinear interaction. Due to the maximal Wigner-Yanase skew information being equivalent to the concurrence, the conditions of generating the maximally entangled state (i.e., the Bell state) are obtained.     

Structures and luminescence properties of Yb3＋ in the double perovskites Ba2YB＇O6 （B＇=Ta5＋, Nb5＋） phosphors

The Yb³⁺ doped Ba₂YB'O₆ (B'=Ta⁵⁺, Nb⁵⁺) were prepared by high temperature solid-state reaction method, their structures were determined by x-ray diffraction and refined by Rietveld method. The diffuse reflection absorption, excitation and emission spectra of Yb³⁺:Ba₂YB'O₆ (B'=,Ta⁵⁺, Nb⁵⁺) were measured at room temperature. Under the excitation of ultraviolet light, these phosphors exhibit broad charge transfer band emissions of TaO₆ or NbO₆ centre with large Stokes shift. The Yb³⁺ doped into these hosts are situated at Y³⁺ sites of cubic symmetry (O_h). The experimental energy levels of Yb³⁺ in Ba₂YTaO₆ and Ba₂YNbO₆ were determined by photoluminescence and diffuse reflection absorption spectra. Their wavefunctions and theoretical energy levels were obtained by diagonalising the Hamiltonian matrix. The experimental energy levels were fitted by Levenberg--Marquardt iteration algorithm to determine crystal field parameters. Then, the magnetic-pole transition line strengths of Yb³⁺:Ba₂YB'O₆(B'=Ta⁵⁺, Nb⁵⁺) from (²F_5/2)Γ₈^- to the low-energy states were calculated.     

一类奇摄动薄板弯曲问题的匹配渐近解

研究了一类薄板弯曲问题. 对四阶奇摄动边值问题, 引入伸长变量, 构造边界附近的内层解, 然后与外部解匹配. 最后用合成展开式理论, 得到了原问题的的渐近解. 关键词： 薄板弯曲 挠度 渐近解     

基于桥域理论的Cu单晶纳米切削跨尺度仿真研究

桥域方法是一种典型的跨尺度仿真研究方法.基于桥域理论,本文分析了原子和连续介质耦合区域的处理问题,即在耦合区采用不同的权重计算系统的能量,通过Lagrange乘子法对原子和连续介质位移进行约束.采用桥域方法,建立了单晶Cu米纳切削的跨尺度仿真模型,获得了单晶Cu纳米切削的材料变形机理.同时,研究了不同切削速度对纳米切削过程和原子受力分布的影响,仿真结果表明:随着切削速度的提高,切削区原子所受的力值增大,切屑变形系数减小,已加工表面变质层厚度增加.本文基于桥域理论,实现了Cu单晶纳米切削跨尺度的建模和仿真, 关键词： 桥域法 纳米切削 单晶Cu 切削速度     

CS2团簇增强的激光多价电离现象的质谱研究

利用脉宽为25ns的脉冲Nd:YAG 532 nm的激光,在8×1010W/cm2的强度下,用飞行时间质谱对CS2的激光电离过程进行了研究.观察到了较强的C2+和S2+高价离子信号,这些高价离子C2+,S2+的最可几平动能高达144eV,112 eV.不同进样方式,激光延迟以及束源压力的实验结果表明,这些高价离子可能来源于CS2团簇的库仑爆炸过程.多光子电离引发,逆韧致吸收加热-电子碰撞电离模型可能是高价离子产生的机理.     

Synthesis and Crystal Structure of a Novel 3D Magnesium(II) Coordination Polymer Constructed by Flexible Benzene-1,4-dioxyacetate

1 INTRODUCTION The coordination chemistry of the alkaline-earth metals has remained a largely underdeveloped area[1, 2]to date. Also calcium(II) and magnesium(II) ions are the essentially biological elements and play an im- portant role in DNA and protein syntheses. Although the transition metal carboxylates have been widely in- vestigated[3, 4], the reports on magnesium complexes with carboxylate ligands are very rare[5]. The flexible phenylenedioxydiacetic acids (BDOAH2), especial…