A novel one-dimensional coordination polymer, {[Cd(PAc)2(4,4-bipy)(H2O)]·4H2O}n (HPAc=phenyl acetic acid, 4,4′-bipy=4,4′-bipyridine) was synthesized and characterized by element analysis, IR, TG and X-ray single diffraction crystal structure determination. It crystallizes in the monoclinic space group C2/c with a=2.088 5(4) nm, b=0.839 05(17) nm, c=1.683 5(3) nm, β=105.45(3)° and V=2.843 5(10) nm3, Z=4, Mr=628.94, F(000)=1 288, μ=0.820 mm-1, R=0.019 9, wR=0.056 5. Each cadmium(Ⅱ) atom is seven-coordinated by four oxygen atoms from two different phenyl acetate groups and two nitrogen atoms from two 4,4′-pyridine ligands and one water molecule, forming a distorted pentagonal bipyramid coordination geometry. Adjacent cadmium(Ⅱ) atoms are bridged by 4,4′-pyridine ligand, constructing a infinite chain along the diagonal direction of ac plane. The Cd…Cd separation within the polymer is 1.164 6(4) nm. The three-dimensional supramolecular structures of the title complexes are constructed by hydrogen bonding interactions and π-π stacking interactions between the benzene rings of HPAc and 4,4′-bipy. CCDC: 616697. 相似文献
A two-dimensional coordination polymer, [Cu(PAc)2(μ-3-PyOH)2]n(HPAc=phenyl acetic acid, 3-PyOH=3-hydroxypyridine) was synthesized and characterized by the element analysis, IR, TG and X-ray diffraction single crystal structure determination. The title complex crystallizes in the monoclinic system with space group P21/c, a=1.228 7(3) nm, b=0.967 05(19) nm, c=1.076 4(2) nm, β=109.93(3)° and V=1.202 4(5) nm3, Z=2, Mr=524.01, F(000)=542, μ=0.953 mm-1, R=0.030 9, wR=0.080 7. Each copper(Ⅱ) ion displays an elongated octahedron with two nitrogen atoms from two different 3-PyOH ligands and two oxygen atoms from two different terminal phenyl acetate groups occupying the basal positions and two oxygen atoms of two different 3-PyOH ligands from the neighbouring molecules occupying the axial positions. Each four identical mononuclear Cu(Ⅱ) unit in the two-dimensional layer is joined by four 3-PyOH ligands, related by inversion centers with a Cu…Cu separation of 0.723 5(10) nm across the 3-PyOH-N,O bridge in bc plane. CCDC: 664483. 相似文献
Magnetically separated and N, S co-doped mesoporous carbon microspheres (N/S-MCMs/Fe3O4) are fabricated by encapsulating SiO2 nanoparticles within N, S-containing polymer microspheres which were prepared using resorcinol/formaldehyde as the carbon source and cysteine as the nitrogen and sulfur co-precursors, followed by the carbonization process, silica template removal, and the introduction of Fe3O4 into the carbon mesopores. N/S-MCMs/Fe3O4 exhibits an enhanced Hg2+ adsorption capacity of 74.5 mg/g, and the adsorbent can be conveniently and rapidly separated from wastewater using an externalmagnetic field. This study opens up new opportunities to synthesize welldeveloped, carbon-based materials as an adsorbent for potential applications in the removal of mercury ions from wastewater. 相似文献
采用EDTA-柠檬酸盐法制备了(Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ(PLNCG),并与Ce0.9Gd0.1O2-δ(CGO)形成复合阴极PLNCG-CGO。XRD和SEM分析结果表明PLNCG与CGO在1 000℃具有较好的化学相容性。电化学阻抗测试结果表明PLNCG-30%CGO复合阴极在700℃的极化电阻为0.092Ω·cm2;过电位为39.3 m V时,电流密度达到113.3 m A·cm-2。氧分压分析表明电极反应的速率控制步骤为电荷转移过程。阳极支撑单电池(Ni-CGO/CGO/PLNCG-30%CGO)在700℃的最大输出功率密度达到569 m W·cm-2,开路电压(OCV)为0.76 V。 相似文献
It is estimated that at least 10% of orally administered drugs can form inclusion complexes with CDs and nearly half of them can be improved in the aspects of their physical and chemical properties. CDs have been used in drugs either for complexes or as auxiliary additives such as solubilizers, diluents or tablet ingredients to improve the solubility, stability and bioavailability of drugs, deodorize and detoxicate drugs,and control release of drugs. 相似文献
Since 1975 when Abu-samra first reported the use of microwave as a heat source for wet digestion methods, sample preparation techniques have ushered in a new era. Using this technique, not only has the sample matrix been decomposed completely, but also digestion times have been dramatically reduced with other benefits such as little contamination, less reagent and sample usage, reduction in loss of volatile species and low blank values. In this paper, some developments in microwave-assisted digestion (MAD) are presented. 相似文献
We propose a scheme for the generation of entangled coherent states for the center-of-mass and relative vibrational modes of two trapped ions. In the scheme the ions are simultaneously illuminated by a single standing-wave laser tuned to the carrier. The scheme allows the production of an entangled coherent states with a considerably high speed as long as a laser field of sufficiently high intensity is available. 相似文献
In this paper we consider the situation that four identical two-level atoms are separately trapped in four single-mode optical cavities, which are placed at the vertices of a tetrahedron and coupled by six fibers. Each atom resonantly interacts with cavity via a one-photon hopping. The evolution of the state vector of the system is given by solving the schrödinger equation when the total excitation number of the system equals one. The geometrical quantum discords between atoms and between cavities are investigated. The effects of cavity-fiber coupling coefficient on the geometrical quantum discords between atoms and between cavities are discussed. The results obtained using the numerical method indicate that the geometrical quantum discords between atoms and between cavities are all weakened with increase of cavity-fiber coupling coefficient.
Nonreciprocal devices are indispensable for building quantum networks and ubiquitous in modern communication technology. Here, we study perfect optical nonreciprocity in a three-mode optomechanical system with mechanical driving.The scheme relies on the interference between optomechanical interaction and mechanical driving. We find perfect optical nonreciprocity can be achieved even though nonreciprocal phase difference is zero if we drive the system by a mechanical driving with a nonzero phase. We obtain the essential conditions for perfectoptical nonreciprocity and analyze properties of the optical nonreciprocal transmission. These results can be used to control optical transmission in quantum information processing. 相似文献