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81.
82.
Yun‐Sheng Ye Ying‐Chieh Yen Wen‐Yi Chen Chih‐Chia Cheng Feng‐Chih Chang 《Journal of polymer science. Part A, Polymer chemistry》2008,46(18):6296-6304
This article describes a new and simple method for preparing polyimide nanocomposites that have very low dielectric constants and good thermal properties: simply through blending the polyimide precursor with a fluorinated polyhedral oligomeric silsesquioxane derivative, octakis(dimethylsiloxyhexafluoropropyl) silsesquioxane (OF). The low polarizability of OF is compatible with polyimide matrices, such that it can improve the dispersion and free volume of the resulting composites. Together, the higher free volume and lower polarizability of OF are responsible for the lower dielectric constants of the PI‐OF nanocomposites. This simple method for enhancing the properties of polyimides might have potential applicability in the electronics industry. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6296–6304, 2008 相似文献
83.
H. G. Miller Yiharn Tzeng G. D. Yen N. Canosa R. Rossignoli A. Plastino 《Zeitschrift für Physik A Hadrons and Nuclei》1986,356(2):141-144
Unphysical behavior in the QR algorithm based least squares determination of the expansion coefficients of the charge density obtained from limited information about the charge form factor occurs when the spread of the singular values in the matrix relating these quantities becomes too large. Setting the smallest singular values equal to zero in the singular value decomposition used in the minimum norm method yields a much more reasonable determination of the charge density. Increasing the size of the basis without increasing the range of the prior information about the charge form factor leads to ambiguities in the determination of the charge density. Numerical results in an analytic model are presented. 相似文献
84.
Ying‐Da Luo I‐Chen Chou Wen‐Yen Chiu Chia‐Fen Lee 《Journal of polymer science. Part A, Polymer chemistry》2009,47(17):4435-4445
In this research, poly(methyl methacrylate)‐b‐poly(butyl acrylate) (PMMA‐b‐PBA) block copolymers were prepared by 1,1‐diphenylethene (DPE) controlled radical polymerization in homogeneous and miniemulsion systems. First, monomer methyl methacrylate (MMA), initiator 2,2′‐azobisisobutyronitrile (AIBN) and a control agent DPE were bulk polymerized to form the DPE‐containing PMMA macroinitiator. Then the DPE‐containing PMMA was heated in the presence of a second monomer BA, the block copolymer was synthesized successfully. The effects of solvent and polymerization methods (homogeneous polymerization or miniemulsion polymerization) on the reaction rate, controlled living character, molecular weight (Mn) and molecular weight distribution (PDI) of polymers throughout the polymerization were studied and discussed. The results showed that, increasing the amounts of solvent reduced the reaction rate and viscosity of the polymerization system. It allowed more activation–deactivation cycles to occur at a given conversion thus better controlled living character and narrower molecular weight distribution of polymers were demonstrated throughout the polymerization. Furthermore, the polymerization carried out in miniemulsion system exhibited higher reaction rate and better controlled living character than those in homogeneous system. It was attributed to the compartmentalization of growing radicals and the enhanced deactivation reaction of DPE controlled radical polymerization in miniemulsified droplets. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4435–4445, 2009 相似文献
85.
86.
Kun‐Heng Chiang Shi‐Han Lu Wan‐Ping Yen Naoto Uramaru Wei‐Siou Tseng Te‐Wei Chang Fung Fuh Wong 《Heteroatom Chemistry》2016,27(4):235-242
A convenient synthetic method for N‐arylformamide derivatives was successfully developed by reacting α‐iodo‐N‐arylacetamides with formamide. This method was applicable to α‐iodo‐N‐arylacetamide substrates bearing electron‐donating or electron‐withdrawing groups, N‐(benzo[d][1,3]dioxol‐5‐yl)‐2‐iodoacetamide, 2‐iodo‐N‐(pyridin‐2‐yl)acetamide, and 2‐iodo‐N‐(naphthalen‐4‐yl)acetamide to give the corresponding N‐arylformamides in moderate to excellent yields (65–94%). A plausible mechanism was proposed to account for the new transformation. 相似文献
87.
Sharpless KE Lindstrom RM Nelson BC Phinney KW Rimmer CA Sander LC Schantz MM Spatz RO Thomas JB Turk GC Wise SA Wood LJ Yen JH 《Journal of AOAC International》2010,93(4):1262-1274
Standard Reference Material (SRM) 1849 Infant/Adult Nutritional Formula has been issued by the National Institute of Standards and Technology (NIST) as a replacement for SRM 1846 Infant Formula, issued in 1996. Extraction characteristics of SRM 1846 have changed over time, as have NIST's analytical capabilities. While certified mass fraction values were provided for five constituents in SRM 1846 (four vitamins plus iodine), certified mass fraction values for 43 constituents are provided in SRM 1849 (fatty acids, elements, and vitamins) and reference mass fraction values are provided for an additional 43 constituents including amino acids and nucleotides, making it the most extensively characterized food-matrix SRM available from NIST. 相似文献
88.
Zhi‐Chang Liu Dr. Chih‐Hsien Chen Dr. Hsian‐Wen Wang Yen‐Chin Huang Ming‐Jui Kao Tsong‐Shin Lim Prof. Tien‐Yau Luh Prof. 《化学:亚洲杂志》2010,5(6):1425-1438
Polynorbornenes appended with porphyrins containing a range of different linkers are synthesized. The use of bisamidic chiral alanine linkers between the pending porphyrins and the polymeric backbone has been shown to bring the adjacent porphyrin chromophores to more suitable orientation for exciton coupling owing to hydrogen bonding between the adjacent linkers. The hydrogen bonding between the adjacent pendants in these polymers may induce a cooperative effect and therefore render single‐handed helical structures for these polymers. Such a cooperative effect is reflected in the enhancement of FRET efficiencies between zinc–porphyrin and free base porphyrin in random copolymers. 相似文献
89.
In order to improve the lateral resolution and extend the field of view of a previously reported 48 element 30 MHz ultrasound linear array and 16-channel digital imaging system, the development of a 256 element 30 MHz linear array and an ultrasound imaging system with increased channel count has been undertaken. This paper reports the design and testing of a 64 channel digital imaging system which consists of an analog front-end pulser/receiver, 64 channels of Time-Gain Compensation (TGC), 64 channels of high-speed digitizer as well as a beamformer. A Personal Computer (PC) is used as the user interface to display real-time images. This system is designed as a platform for the purpose of testing the performance of high frequency linear arrays that have been developed in house. Therefore conventional approaches were taken it its implementation. Flexibility and ease of use are of primary concern whereas consideration of cost-effectiveness and novelty in design are only secondary. Even so, there are many issues at higher frequencies but do not exist at lower frequencies need to be solved. The system provides 64 channels of excitation pulsers while receiving simultaneously at a 20–120 MHz sampling rate to 12-bits. The digitized data from all channels are first fed through Field Programmable Gate Arrays (FPGAs), and then stored in memories. These raw data are accessed by the beamforming processor to re-build the image or to be downloaded to the PC for further processing. The beamformer that applies delays to the echoes of each channel is implemented with the strategy that combines coarse (8.3 ns) and fine delays (2 ns). The coarse delays are integer multiples of the sampling clock rate and are achieved by controlling the write enable pin of the First-In-First-Out (FIFO) memory to obtain valid beamforming data. The fine delays are accomplished with interpolation filters. This system is capable of achieving a maximum frame rate of 50 frames per second. Wire phantom images acquired with this system show a spatial resolution of 146 μm (lateral) and 54 μm (axial). Images with excised rabbit and pig eyeball as well as mouse embryo were also acquired to demonstrate its imaging capability. 相似文献
90.
Lee Ming-Kwei Yen Chih-Feng Chiu Shih-Chen 《Applied Physics A: Materials Science & Processing》2011,104(4):1175-1180
The electrical characteristics of thin TiO2 films prepared by metal–organic chemical vapor deposition grown on a p-type InP substrate were studied. For a TiO2 film of 4.7 nm on InP without and with ammonium sulfide treatment, the leakage currents are 8.8×10−2 and 1.1×10−4 A/cm2 at +2 V bias and 1.6×10−1 and 8.3×10−4 A/cm2 at −2 V bias. The lower leakage currents of TiO2 with ammonium sulfide treatment arise from the improvement of interface quality. The dielectric constant and effective oxide
charge number density are 33 and 2.5×1013 cm2, respectively. The lowest mid-gap interface state density is around 7.6×1011 cm−2 eV−1. The equivalent oxide thickness is 0.52 nm. The breakdown electric field increases with decreasing thickness in the range
of 2.5 to 7.6 nm and reaches 9.3 MV/cm at 2.5 nm. 相似文献