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51.
Highly Curved Bowl‐Shaped Fragments of Fullerenes: Synthesis,Structural Analysis,and Physical Properties
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Min‐Kuan Chen Hsin‐Ju Hsin Dr. Tsun‐Cheng Wu Bo‐Yan Kang Yen‐Wei Lee Prof. Ming‐Yu Kuo Prof. Yao‐Ting Wu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(2):598-608
Highly curved buckybowls 3 , 4 , and 5 were synthesized from planar precursors, fluoranthenes 8 , benzo[k]fluoranthenes 10 and naphtho[1,2‐k]‐cyclopenta[cd]fluoranthenes 12 , respectively, using straightforward palladium‐catalyzed cyclization reactions. These fluoranthene‐based starting materials were easily prepared from 1,8‐bis(arylethynyl)naphthalenes 6 . Both buckybowls 3 and 4 are fragments of C60, whereas 5 is a unique subunit of C70. The curved structures were identified by X‐ray crystallography, and they are deep bowls. The maximum π‐orbital axis vector (POAV) pyramidalization angle in both 3 and 4 is 12.8°. Such a high curvature is very rarely obtained. Buckybowls 5 are less curved than the others because they have a lower density of five‐membered rings, analogous to the tube portion of C70. Cyclopentaannulation increases the bowl depths of 3 and 4 , but not the maximum POAV pyramidalization angle. Among the eight buckybowls studied herein, five form polar crystals. The bowl‐to‐bowl inversion dynamics of these buckybowls can be classified into two types; one has a planar transition structure, whereas the other has an S‐shaped transition structure. A larger longitudinal length of these buckybowls corresponds to a stronger preference for the latter. The photophysical properties of these buckybowls were examined and compared with those of C60 and C70. Buckybowls 5 have absorption bands at wavelengths greater than 450 nm, which are similar to those of C70. The chiral resolution of the mono‐substituted buckybowl 4 ac was also studied by using HPLC with a chiral column. 相似文献
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53.
Cheng-Li Wang Weng-Sing Hwang Hsueh-Liang Chu Feng-Lin Yen Chi-Yuen Hwang Chi-Shiung Hsi Huey-Er Lee Moo-Chin Wang 《Journal of Sol-Gel Science and Technology》2014,70(3):428-440
The phase transformation and crystalline growth of 4 mol% yttria partially stabilized zirconia (4Y-PSZ) precursor powders have been investigated using the coprecipitation route, using zirconium oxide chloride octahydrate (ZrOCl2·8H2O) and yttrium nitrate (Y(NO3)3·6H2O) as the initial materials. Differential thermal analysis (DTA), X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), nano beam electron diffraction (NBED), and high resolution TEM (HRTEM) were utilized to characterize the behavior of phase transformation and crystalline growth of the 4Y-PSZ precursor powders after calcined. Tetragonal ZrO2 crystallization occurred at about 718.2 K. The activation energy of tetragonal ZrO2 crystallization was 227.0 ± 17.4 kJ/mol, obtained by a non-isothermal method. The growth morphology parameter (n) and growth mechanism index were close to 2.0, showing that tetragonal ZrO2 had a plate-like morphology. The crystalline size of tetragonal ZrO2 increased from 7.9 to 27.6 nm when the calcination temperature was increased from 973 to 1,273 K. The activation energies of tetragonal ZrO2 growth were 14.97 ± 0.33 and 84.46 ± 6.65 kJ/mol when precursor powders after calcined from 723–973 and 973–1,273 K, respectively. 相似文献
54.
Dr. Hsin-Yung Yen Dr. Idlir Liko Joseph Gault Dr. Di Wu Dr. Weston B. Struwe Prof. Carol V. Robinson 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(36):15690-15694
The immune scavenger protein DC-SIGN interacts with glycosylated proteins and has a putative role in facilitating viral infection. How these recognition events take place with different viruses is not clear and the effects of glycosylation on the folding and stability of DC-SIGN have not been reported. Herein, we report the development and application of a mass-spectrometry-based approach to both uncover and characterise the effects of O-glycans on the stability of DC-SIGN. We first quantify the Core 1 and 2 O-glycan structures on the carbohydrate recognition and extracellular domains of the protein using sequential exoglycosidase sequencing. Using ion mobility mass spectrometry, we show how specific O-glycans, and/or single monosaccharide substitutions, alter both the overall collision cross section and the gas-phase stability of the DC-SIGN isoforms. We find that rather than the mass or length of glycoprotein modifications, the stability of DC-SIGN is better correlated with the number of glycosylation sites. 相似文献
55.
Ruixiang Qu Xiangyu Li Yanan Liu Huajun Zhai Shuaiheng Zhao Lin Feng Yen Wei 《Angewandte Chemie (International ed. in English)》2020,59(32):13437-13443
Superwetting membranes with responsive properties have attracted heightened attention because of their fine‐tunable surface wettability. However, their functional diversity is severely limited by the “black‐or‐white” wettability transition. Herein, we describe a coating strategy to fabricate multifunctional responsive superwetting membranes with SiO2/octadecylamine patterns. The adjustable patterns in the responsive region are the key factor for functional diversity. Specifically, the coated part of the membrane displayed a superhydrophobicity/superhydrophilicity transition at different pH values, whereas the uncoated part exhibited invariant superhydrophilicity. On the basis of this anisotropy/isotropy transition, the membranes can serve as either responsive permeable membranes or signal‐expression membranes, thus enabling the responsive separation and permeation of liquids with satisfactory separation efficiency (>99.90 %) and flux (ca. 60 L m?2 h), as well as real‐time liquid signal expression with alterable signals. 相似文献
56.
Lithium–sulfur batteries have great potential as next-generation energy-storage devices because of their high theoretical charge-storage capacity and the low cost of the sulfur cathode. To accelerate the development of lithium–sulfur technology, it is necessary to address the intrinsic material and extrinsic technological challenges brought about by the insulating active solid-state materials and the soluble active liquid-state materials. Herein, we report a systematic investigation of module-designed carbon-coated separators, where the carbon coating layer on the polypropylene membrane decreases the irreversible loss of dissolved polysulfides and increases the reaction kinetics of the high-loading sulfur cathode. Eight different conductive carbon coatings were considered to investigate how the materials’ characteristics contribute to the lithium–sulfur cell’s cathode performance. The cell with a nonporous-carbon-coated separator delivered an optimized peak capacity of 1112 mA∙h g−1 at a cycling rate of C/10 and retained a high reversible capacity of 710 mA∙h g−1 after 200 cycles under lean-electrolyte conditions. Moreover, we demonstrate the practical high specific capacity of the cathode and its commercial potential, achieving high sulfur loading and content of 4.0 mg cm−2 and 70 wt%, respectively, and attaining high areal and gravimetric capacities of 4.45 mA∙h cm−2 and 778 mA∙h g−1, respectively. 相似文献
57.
58.
Yupeng Wu Yangchun Tao Kuan Cai Siwei Liu Yi Zhang Zhenguo Chi Jiarui Xu Yen Wei 《中国化学》2015,33(12):1338-1346
Two triblock polymers, tetraaniline‐block‐poly(N‐isopropyl acrylamide)‐block‐poly(hydroxyethyl acrylate) (TA‐b‐PNIPAM‐b‐PHEA) and TA‐b‐PHEA‐b‐PNIPAM, were synthesized with unambiguous structure by a two step method. The difference of these two diblock polymers is the connection order of carboxyl group to block, e.g., carboxyl group to PNIPAM block for PNIPAM‐b‐PHEA and to PHEA block for PHEA‐b‐PNIPAM. Secondly, block tetraaniline was linked to the diblock polymer through amidation to yield the corresponding triblock copolymer. Both of them have almost the identical chemical compositions. The only difference is the connection order of each block in the triblock polymers. When they were self‐assembled at 45°C in a suitable solution, both of their aggregates have spherical shape with slight defects on their surface with the average diameter of about 400 nm. However, when their aggregate dispersion was cooled down to 20°C, only TA‐b‐PHEA‐b‐PNIPAM's morphology changed, forming worm‐like aggregates with the diameter of about 100–200 nm transformed from spherical aggregates. Both amphiphilic property and position of each block in this triblock copolymer are very essential for this morphology transformation. Since the worm‐like aggregates presented here by our group have hollow structure inside, its controlled release properties for doxorubicin were evaluated. Drug release experiment indicated that along with the temperature changes, the rearrangement of the intermediate layer structure caused morphology change in aggregate, thus accelerating the speed of drug release. 相似文献
59.
Dr. Gábor London Kuang‐Yen Chen Dr. Gregory T. Carroll Prof. Dr. Ben L. Feringa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(32):10690-10697
We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were introduced to the rotor part of the motors. Molecular motors were attached to quartz surfaces by using interfacial 1,3‐dipolar cycloadditions. To test the effect of the functional groups on the rotary motion, photochemical and thermal isomerization studies of the motors were performed both in solution and when attached to the surface. We found that the substituents have no significant effect on the thermal and photochemical processes, and the functionalized motors preserved their rotary function both in solution and on a quartz surface. Preliminary results on the influence of the functional groups on surface wettability are also described. 相似文献
60.
Yi-Jung Liu Chih-Hung Yen Chia-Hao Hsu Kuo-Hui Yu Li-Yang Chen Tsung-Han Tsai Wen-Chau Liu 《Optical Review》2009,16(6):575-577
An interesting GaN-based light emitting diode (LED) using a 50 nm indium oxide (In2O3)/250 nm indium-tin oxide (ITO) mixed structure to replace the commonly used ITO (250 nm) current spreading layer is fabricated
and studied. Use of the In2O3 layer could reduce the contact resistance of p-GaN in LEDs. In addition, this highly-resistive In2O3 layer, below the ITO layer could improve the current spreading performance. Experimentally, at room temperature, using this
mixed structure, the luminous and EL intensities are enhanced by 17.7 and 17.1%, respectively. 相似文献