Fracture of brittle metallic glasses: brittleness or plasticity

We report a brittle Mg-based bulk metallic glass which approaches the ideal brittle behavior. However, a dimple structure is observed at the fracture surface by high resolution scanning electron microscopy, indicating some type of "ductile" fracture mechanism in this very brittle glass. We also show, from the available data, a clear correlation between the fracture toughness and plastic process zone size for various glasses. The results indicate that the fracture in brittle metallic glassy materials might also proceed through the local softening mechanism but at different length scales.     

Thermally excited multiplet states in macerals separated from bituminous coal

Electron paramagnetic resonance searches of thermally excited multiplet states in macerals, exinite, vitrinite, and inertinite of Polish medium-rank coal (85.6 wt% C), were performed. Numerical analysis of lineshape indicates a multicomponent structure of the EPR spectra of macerals heated at 300 degrees and 650 degrees C. EPR spectra of exinite and vitrinite are a superposition of broad Gauss, broad Lorentz (Lorentz 1), and narrow Lorentz (Lorentz 3) lines. Two narrow Lorentz (Lorentz 2 and Lorentz 3) lines were observed in the resonance absorption curves of inertinite. The influence of the measuring temperature (100-300 K) on the EPR lines of the macerals was also studied. The experimentally obtained temperature dependence of the EPR line intensities were fitted by the theoretical functions characteristic for paramagnetic centers with ground doublet state (S = 12) and paramagnetic centers with thermally excited triplet (S = 1) and quadruplet (S = 32) states. Thermally excited multiplet states were found in exinite and vitrinite. Both paramagnetic centers with doublet ground state (S = 12) and paramagnetic centers with thermally excited states, probably quadruplet states (S = 32), exist in the group of paramagnetic centers of exinite and vitrinite with the broad Lorentz 1 lines. Intensities (I) of the broad Gauss and the narrow Lorentz 3 lines of exinite and vitrinite changes with temperature according to the Curie law (I = C/T). The existence of thermally excited multiplet states was not stated for inertinite. The two groups of paramagnetic centers of inertinite with Lorentz 2 and Lorentz 3 lines obey the Curie law. Copyright 2000 Academic Press.     

Quantitative Bestimmung heterocyclischer Verbindungen mittels Ionenaustauscherpapier

Zusammenfassung Es wird darauf hingewiesen, daß einfache heterocyclische Verbindungen ähnlich wie Alkaloide mittels Ionenaustauscherpapier quantitativ bestimmt werden können. Kleine Mengen (im Bereich von Mikrogrammen) dieser Verbindungen werden als Lösungen in die Streifen des Austauscherpapiers eingesogen. Die entstehenden Zonen werden mit Dragendorffs Reagens sichtbar gemacht und planimetriert. Der Vergleich mit Standardzonen ermöglicht eine quantitative Auswertung des Zonenflächen.     

Buchbesprechungen

Ohne Zusammenfassung     

Das Quadrupolmoment des 2,3 MeV-Zustandes in120Sn

Time differentialγγ-angular correlation measurements have been performed to determine the electric interaction of the 2.3 MeVI=5^? state of¹²⁰Sn in different polycristalline antimony compounds. A calibration of the field gradient was achieved by Mößbauerexperiments with the 23.8 keVI=3/2⁺ state in¹¹⁹Sn using identical sources. From the ratio of the measured electric interactions the ratio of the quadrupole moments is deduced as: $$\left| {\frac{{Q(2.3{\mathbf{ }}MeV level,{\mathbf{ }}I = 5^ - ,^{120} Sn)}}{{Q(2.8{\mathbf{ }}keV level,{\mathbf{ }}I = {3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}^ + ,^{119} Sn)}}} \right| = 2.86(15)$$ . Using 0.06 (2) b for the quadrupole moment of the 23.8 keV level in¹¹⁹Sn one gets for the quadrupole moment of the 2.3 MeV level in¹²⁰Sn ¦Q(2.3 MeV level,I=5^?,¹²⁰Sn)¦=0.021 (8) b.     

Bound on the ratio of decay amplitudes for -B0-->J/psiK*0 and B0-->J/psiK*0

We have measured the time-dependent decay rate for the process B-->J/psiK(*0) (892) in a sample of about 88x10(6) Upsilon(4S)-->B(-)B decays collected with the BABAR detector at the PEP-II asymmetric-energy B factory at SLAC. In this sample we study flavor-tagged events in which one neutral B meson is reconstructed in the J/psiK(*0) or J/psi(-)K(*0) final state. We measure the coefficients of the cosine and sine terms in the time-dependent asymmetries for J/psiK(*0) and J/psi(-)K(*0), find them to be consistent with the standard model expectations, and set upper limits at 90% confidence level (C.L.) on the decay amplitude ratios |A((-)B(0)-->J/psiK(*0))|/|A(B0-->J/psiK(*0))|<0.26 and |A(B0-->J/psi(-)K(*0))|/|A((-)B(0)-->J/psi(-)K(*0))|<0.32. For a single ratio of wrong-flavor to favored amplitudes for B0 and (-)B(0) combined, we obtain an upper limit of 0.25 at 90% C.L.     

Search for B0 decays to invisible final states and to nunugamma

We establish upper limits on branching fractions for B0 decays to final states where the decay products are purely invisible (i.e., no observable final state particles) and for B0 decays to nunugamma. Within the standard model, these decays have branching fractions that are below current experimental sensitivity, but various models of physics beyond the standard model predict significant contributions from these channels. Using 88.5 x 10(6) BB pairs collected at the Upsilon(4S) resonance by the BABAR experiment at the PEP-II e(+)e- storage ring at the Stanford Linear Accelerator Center, we establish upper limits at the 90% confidence level of 22 x 10(-5) for the branching fraction of B0-->invisible and 4.7 x 10(-5) for the branching fraction of B0-->nunugamma.     

Measurement of the direct CP asymmetry in b-->s gamma Decays

We describe a measurement of the direct CP asymmetry between inclusive b-->s gamma and b-->s gamma decays. This asymmetry is expected to be less than 0.01 in the standard model, but could be enhanced up to about 0.10 by new physics contributions. We use a sample of 89 x 10(6) BB pairs recorded with the BABAR detector at SLAC PEP-II, from which we reconstruct a set of 12 exclusive b-->s gamma final states containing one charged or neutral kaon and one to three pions. We measure an asymmetry of A(CP)(b-->s gamma)=0.025+/-0.050(stat)+/-0.015(syst), corresponding to an allowed range of -0.06s gamma)<+0.11 at 90% confidence level.     

Heteronuclear proton assisted recoupling

We describe a theoretical framework for understanding the heteronuclear version of the third spin assisted recoupling polarization transfer mechanism and demonstrate its potential for detecting long-distance intramolecular and intermolecular (15)N-(13)C contacts in biomolecular systems. The pulse sequence, proton assisted insensitive nuclei cross polarization (PAIN-CP) relies on a cross term between (1)H-(15)N and (1)H-(13)C dipolar couplings to mediate zero- and∕or double-quantum (15)N-(13)C recoupling. In particular, using average Hamiltonian theory we derive effective Hamiltonians for PAIN-CP and show that the transfer is mediated by trilinear terms of the form N(±)C(?)H(z) (ZQ) or N(±)C(±)H(z) (DQ) depending on the rf field strengths employed. We use analytical and numerical simulations to explain the structure of the PAIN-CP optimization maps and to delineate the appropriate matching conditions. We also detail the dependence of the PAIN-CP polarization transfer with respect to local molecular geometry and explain the observed reduction in dipolar truncation. In addition, we demonstrate the utility of PAIN-CP in structural studies with (15)N-(13)C spectra of two uniformly (13)C,(15)N labeled model microcrystalline proteins-GB1, a 56 amino acid peptide, and Crh, a 85 amino acid domain swapped dimer (MW=2×10.4 kDa). The spectra acquired at high magic angle spinning frequencies (ω(r)∕2π>20 kHz) and magnetic fields (ω(0H)∕2π=700-900 MHz) using moderate rf fields, yield multiple long-distance intramonomer and intermonomer (15)N-(13)C contacts. We use these distance restraints, in combination with the available x-ray structure as a homology model, to perform a calculation of the monomer subunit of the Crh protein.