13C?13C spin coupling constants in tetrahydronaphthylene,hexahydrobenzanthracene and benzo[a]pyrene derivatives

The ¹³C? ¹³C spin coupling constants have been determined in substituted [1-¹³C]tetrahydronaphthylenes, [5-¹³C]hexahydrobenzanthracenes and [5-¹³C]benzanthracene. In addition, the ¹³C? ¹³C spin coupling constants for 7-hydroxy[7-¹³C]benzopyrene, trans-7,8-dihydro[7-¹³C]benzopyrene-7,8-diol and trans-7,8-dihydro[10-¹³C]benzopyrene-7,8-diol are reported, together with the one-bond carbon-carbon coupling constants between C-4 and C-5 in selected 4,5-disubstituted benzopyrenes. Values for the directly bonded coupling constants and long-range coupling constants are similar to those reported previously for other aromatic and aliphatic systems. Substituent effects on carbon-carbon coupling are compared for similarly substituted cyclic and acyclic systems.     

Use of precision colorimetry for elemental microanalysis

Spectrophotometric techniques are useful for microdeterminations of many elements in organic compounds and some inorganic compounds. It is possible to determine most metals and some non-metals (Al, Co, F, Fe, Mo, P, Pd, Pt, Si, Sn, Ti...) by applying spectrophotometric techniques described in the literature (most often for trace analysis) and using commercial reagents.     

Luminescence of AgCl excited by u.v. laser light

The spectral distribution and decay of the blue-green luminescence of AgCl has been measured at very low temperatures, using u.v. laser excitation. A structure was observed in the emission band at 77°K. The decay consists of three processes: a) a very fast process which follows the laser pulse (10^–8 sec), b) a fast exponential process which is also observed with low intensity u.v. excitation,(10^–4–10^–5 sec) and, finally, c) a slow exponential process (seconds).     

Numerical experiments on quadratically convergent algorithms for function minimization

The nine quadratically convergent algorithms for function minimization appearing in Ref. 2 are tested through several numerical examples. A quadratic function and four nonquadratic functions are investigated. For the quadratic function, the results show that, if high-precision arithmetic together with high accuracy in the one-dimensional search is employed, all the algorithms behave identically: they all produce the same sequence of points and they all lead to the minimal point in the same number of iterations (this number is equal at most to the number of variables). For the nonquadratic functions, the results show that some of the algorithms behave identically and, therefore, any one of them can be considered to be representative of the entire class. The effect of different restarting conditions on the convergence characteristics of the algorithms is studied. Proper restarting conditions for faster convergence are given.This research, supported by the Office of Scientific Research, Office of Aerospace Research, United States Air Force, Grant No. AF-AFOSR-828-67, is a condensation of the investigation described in Ref. 1.     

Dynamical coulomb blockade of multiple Andreev reflections

We analyze the dynamical Coulomb blockade of multiple Andreev reflections (MAR) in a superconducting quantum point contact coupled to a macroscopic impedance. We find that at very low transmission the blockade scales as n2 with n = Int(2delta/eV), where V is the bias voltage and delta is the superconducting gap, as it would correspond to the occurrence of shots of charge ne. For higher transmission the blockade is reduced because of both the Pauli principle and the elastic renormalization of the MAR probability, and for certain voltage regions it may even become an anti-blockade; i.e., the current is enhanced due to the coupling with the electromagnetic environment.     

Identification of transverse spin currents in noncollinear magnetic structures

In this Letter we construct a spinor transport theory and derive the equations of motion for the distribution functions for currents in noncollinear magnetic multilayers. We find the length scale which characterizes the transverse spin current is of the order of 3 nm for a ferromagnetic 3d transition metal such as Co; this alters one's prediction of the spin torque generated for free magnetic layers less than 3 nm. In the limit of large exchange splitting we reproduce the results previously found for spin currents across noncollinear multilayers inasmuch as there are no transverse spin currents in the layers themselves in this limit.     

Heritability of Stroop and flanker performance in 12-year old children

Background  

There is great interest in appropriate phenotypes that serve as indicator of genetically transmitted frontal (dys)function, such as ADHD. Here we investigate the ability to deal with response conflict, and we ask to what extent performance variation on response interference tasks is caused by genetic variation. We tested a large sample of 12-year old monozygotic and dizygotic twins on two well-known and closely related response interference tasks; the color Stroop task and the Eriksen flanker task. Using structural equation modelling we assessed the heritability of several performance indices derived from those tasks.     

Versatile and facile synthesis of diverse semisynthetic tetracycline derivatives via Pd-catalyzed reactions

A diverse collection of tetracycline derivatives has been synthesized utilizing Heck, Suzuki, and other palladium-coupling reactions via tetracycline arenediazonium and iodoarene salts. Large numbers of tetracyclines are now possible via these reactions, including numerous upper periphery derivatives of doxycycline, minocycline, sancycline, and methacycline modified at positions C7, C9, and C6-C13 on the tetracycline naphthacene ring. Application of palladium-coupling reactions to the tetracyclines has yielded new tetracycline classes with differing structural attributes, greatly increasing the structural diversity of this family of antibiotics, one of the last of the early antibiotic families to be expanded by organic and medicinal chemistry.     

Simultaneous multicolor image formation with a single diffractive optical element

A design for a novel diffractive optical element (DOE) that can reconstruct three different intensity patterns when it is illuminated by three different wavelengths is presented. If the chosen wavelengths are red, green, and blue, full-color reconstruction capability is obtained. Reconstruction is achieved in the near field (Fresnel domain). Computer simulation results as well as experimental evidence are presented, proving the capabilities of this novel DOE design procedure.     

Optimal synthesis of three-dimensional complex amplitude distributions

The synthesis of three-dimensional (3-D) light distributions is important for many applications. For example, in scanning applications it is preferable that the scanning beam preserve its characteristics over a large distance to yield elongated scanning range. It is evident that any 3-D light distribution must satisfy the wave equation or, in second-order approximation, the Fresnel diffraction formula. Thus many desirable 3-D light distributions may not be realizable. We propose a single optical element (OE) that synthesizes a physical beam within a certain 3-D region. The OE provides the optimal physical beam in comparison with a desired one in the sense of minimal mean-square error.