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11.
The influence of poly(vinyl alcohol) (PVA), a steric stabilizer, and sodium dodecyl sulfate (SDS), an electrostatic stabilizer, on the stability of styrene dispersion polymerized systems was studied. It was shown that in stabilization by PVA there was pronounced bridging of the submicron emulsion particles to 10-μ dispersion particles and that the emulsion particles could not be washed off. In SDS stabilization, on the other hand, the emulsion formed was easily washed off because bridging with SDS does not occur. The surface tension of the aqueous phase measured during polymerization showed different characteristics for stable and unstable systems. 相似文献
12.
An N2O laser is used to pump the ground vibrational state (8,7) inversion doublet of 14NH3 while simultaneously monitoring other ground state doublets. Time-resolved rotational energy transfer signals are observed in accordance with known selection values. Absolute rates of rotational energy transfer processes are estimated. 相似文献
13.
14.
Cyclic voltammetry and electrolysis studies were carried out in dimethyl sulfoxide, diglyme and liquid ammonia. The depolarizers were diethyl fumarate, ethyl cinnamate, stilbene and anthracene. The reduction reactions were carried out in the presence of organic halides, phenol, acids and water. The rates of the reactions were measured. The main solvent effect was noticed with water which reacts 100 times faster in diglyme than in liquid ammonia or DMSO. The results of electrolytic experiments with two reactants simultaneously were compared with those predicted from the kinetic data. 相似文献
15.
The influence of localized excited (LE) states on the spectroscopy of charge transfer (CT) complexes has been examined for a series of complexes formed between methyl-substituted benzene donors and 1,2,4,5-tetracyanobenzene as acceptor in 1,2-dichloroethane and octanenitrile solvents. A molecular orbital model was used to describe the appearance of multiple CT absorption bands that occur in the spectra of these complexes. The influence of LE states in these CT absorptions was explored using time-resolved linear dichroism spectroscopy where the direction of the CT transition moment vector (TMV) was used to probe the magnitude of intensity borrowing. The TMV directions for each of the observed CT transitions within the absorption spectra were determined for several complexes. In some cases, the observed CT transitions were interpreted as being pure CT transitions; in others the observed transitions are influenced significantly by a LE transition. The correlation between the TMV directions and the transition energy suggests that the magnitude of intensity borrowing is influenced not only by the energy difference between the CT and LE transitions but also by the specific character of the transitions under consideration. 相似文献
16.
17.
Is the ring conformation the most critical parameter in lipase-catalysed acylation of cycloalkanols?
CAL-B catalysed the resolution of several five and six-membered cyclic beta-hydroxy esters efficiently with the exception of the cis-cyclohexanol (+/-)-4. When employing molecular modelling techniques the conformation turned out to be the most important determinant for their reactivity towards O-acetylation. In all cases, the R enantiomers reacted faster than the S enantiomers since the reactive intermediates of the former can adopt more favourable ring conformations and thus experience less steric hindrance in the active site. Furthermore, the minimised structure for the main conformer of R-4 showed that the axial hydrogens in the 3 and 5-positions with respect to the hydroxyl group prevent the enzymatic reaction. 相似文献
18.
Oxidation of 3,6-disubstituted tetrabenzo[5.5]fulvalenes by SbF(5) results in the formation of dications that behave like two antiaromatic fluorenyl cations connected by a single bond. Both fluorenyl systems exhibit the paratropic shifts and nucleus independent chemical shifts (NICS) characteristic of antiaromatic species. Comparison with analogous 2,7-disubstituted tetrabenzo[5.5]fulvalenes reveals that the antiaromaticity of the substituted ring system can be altered substantially by changes in the placement of the substituents, possibly due to changes in the delocalization of charge in the system. Substituents in the 3,6-position decrease the antiaromaticity because of the increase in the benzylic resonance compared to 2,7-substituents. 相似文献
19.
We analyzed the data from a replica exchange molecular dynamics simulation using the weighted histogram analysis method to combine data from all of the temperature replicas (T-WHAM) to obtain the room-temperature potential of mean force of the G-peptide (the C-terminal beta-hairpin of the B1 domain of protein G) in regions of conformational space not sampled at room temperature. We were able to determine the potential of mean force in the transition region between a minor alpha-helical population and the major beta-hairpin population and identify a possible transition path between them along which the peptide retains a significant amount of secondary structure. This observation provides new insights into a possible mechanism of formation of beta-sheet secondary structures in proteins. We developed a novel Bayesian statistical uncertainty estimation method for any quantity derived from WHAM and used it to validate the calculated potential of mean force. The feasibility of estimating regions of the potential of mean force with unfavorable free energy at room temperature by T-WHAM analysis of replica exchange simulations was further tested on a system that can be solved analytically and presented some of the same challenges found in more complex chemical systems. 相似文献
20.
The structures, energies, and natural atomic charges of 2-dimethylaminophenol oxide, 2-Me2N-(O)C6H4OH, and 2-dimethylphosphinylphenol, 2-Me2P(O)C6H4OH, in three different conformations were computed at the ab initio MP2/6-31G* level. Computed natural charges indicate distributions of electron density in amine oxides and phosphine oxides that are quite different from what is normally assumed on the basis of the formal charges in the usual representations of these compounds. The charges on nitrogen and phosphorus in these compounds are typically computed to be approximately zero on nitrogen and +2 on phosphorus, and the oxygen is considerably more negative in the phosphine oxide than in the amino oxide. Electronegativity differences thus play a larger role and formal charges a smaller one in determining atomic charges in these compounds than is generally believed. Despite the more negative oxygen in phosphine oxides, amine oxides are computed to be considerably more basic when participating in hydrogen bonding. Calculations treating the computed natural charges on these six conformations as point charges for classical approximations of the coulombic energies support the idea that the quantum mechanically computed relative energies are largely determined by coulombic interactions. 相似文献