We study the Cauchy problem for the quasilinear parabolic equation where p > 1 is a parameter and ψ is a smooth, bounded function on (1, ∞) with ? ? sψ′(s)/ψ(s) ? θ for some θ > 0. If 1 < p < 1 + 2/N, there are no global positive solutions, whereas if p > 1 + 2/N, there are global, positive solutions for small initial data. 相似文献
Polyethylene terephthalate(PET)/polycaprolactone(PCL) segmented copolymers with different hard segment contents and a blend of two of them were studied by using DSC, WAXS, TEM and IR techniques and dynamic mechanical, stress-strain and isothermal crystallization measurements. Emphasis was laid on the studies of influence of compositional heterogeneity on the morphology and properties of these segmented copolymers. It was found that the solution cast specimens of the more heterogeneous sample exhibit better segregation of segments, high crystallinity and melting temperature. They have higher thermal stability of mechanical properties at small deformations. However, they are less stable against large deformations and may become softer than the more homogeneous ones. 相似文献
In this study, surface plasmon resonance (SPR) for monitoring 17β-eatradiol (E2) was developed. The small molecule E2 was immobilized on a CM5 sensor chip for an indirect competitive immunoassay to detect E2. The SPR response bahed on the antigen-antibody reaction was measured by injecting the sample solution into the flow system. The limitation of detection was 0.445 μg/L. The developed SPE-SPR system was applied to analyze the seawater samples. Recovery of E2 was 91.6%-93. 1%. Relative standard deviations(RSD) for the E2 assay were between 10.9%-15.1% (n = 3). The range of determination of E2 samples from the sewage in the coastal marine environ-ment was between ND(lower than detection limit) and ca. 11.78 ng/L. 相似文献
Supermolecular compounds of glycine monosubstituted heteropolytungstates isomer with Keggin structure βi-K6-n(HGly)n[SiW11M(H2O)O39]·xH2O (M=Co2+, Ni2+; βi=β2, β3) were synthesized and characterized by means of elementary analysis, IR, UV, TG-DTA, X-ray diffraction, polarography and CV. The results indicate that glycin combines the electrostatic effect with heteropolytungstates isomer. The heteropoly anion still remains its Keggin structure in supermolecular compounds. The electrochemical behavior of the compound in 1 mol·L-1 HAc-NaAc shows that two redox waves correspond to two two-electron processes attributing to the reduction of [SiW11Co(H2O)O39]6-. Steady-state fluorescence spectrum shows two intenser fluorescence emission peaks in 447 nm and 486 nm appeared after the supermolecular compound being excited by the excitation wavelength in 274 nm. 相似文献
One important difference between the results of collinear and of full 3-D dynamical computations arises from the difference in the available volume in phase space (1-D versus 3-D) which can be termed a “dimensionality-bias”. Correction for this phase space factor allows for a more realistic estimate of reaction cross sections, branching ratios and 3-D product energy distributions from collinear calculations. 相似文献
Three new cyclometalated iridium(m) complexes based on ligands of diphenylquinoline with fluorinated subsfituents were prepared, and characterized by elemental analysis (EA), ^1H NMR, and mass spectroscopy (MS). The photophysical and electrophosphorescent properties of the complexes were briefly discussed. 相似文献