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141.
[reactions: see text] A concise synthesis of highly functionalized cyclopentane derivatives via a Brook rearrangement mediated stereoselective linchpin cyclization reaction involving tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides is described. 相似文献
142.
[reactions: see text] [(Ph3P)CuH]6 effectively catalyzes the hydrostannation of activated alkynes with exclusive regioselectivity for alpha-stannation. Syn hydrostannation is observed exclusively for alkynoates. Anti or syn hydrostannation adducts are obtained as products for alkynone substrates. 相似文献
143.
144.
An experimental investigation has been performed to determine the effects of different arrangements of obstacles on the
cooling of simulated electronic package. The considered simulated electronic package consisted of a channel formed by two
parallel plates. The bottom plate is attached with five identical electrically heated square obstacles, which are perpendicular
to the mean airflow and arranged with different side-to-side distances. The experimental results show that the conventional
equi-spaced arrangement might not be the optimum option and should be avoided. A better thermal performance could be obtained
when the side-to-side distances between the obstacles followed a geometric series. For example, at Re=800, the highest temperature
of the optimum arrangement could be reduced by 12% compare to the equi-spaced arrangement and the maximum temperature difference
among the five obstacles is lower than that of equi-spaced arrangement by 32.1%.
Received on 17 December 1999 相似文献
145.
Björn Schwarz Issic K. C. Leung Nils Buchholtz Gabriele Kaiser Gloria Stillman Jill Brown Colleen Vale 《ZDM》2008,40(5):791-811
In this paper, qualitative results of a case study about the professional knowledge in the area of argumentation and proof of future teachers from universities in three countries are described. Based on results of open questionnaires, data about the competencies these future teachers have in the areas of mathematical knowledge and knowledge of mathematics pedagogy are presented. The study shows that the majority of the future teachers at the participating universities situated in Germany, Hong Kong and Australia, were not able to execute formal proofs, requiring only lower secondary mathematical content, in an adequate and mathematically correct way. In contrast, in all samples there was evidence of at least average competencies of pedagogical content reflection about formal and pre-formal proving in mathematics teaching. However, it appears that possessing a mathematical background as mandated for teaching and having a high affinity with proving in mathematics teaching at the lower secondary level are not a sufficient preparation for teaching proof. 相似文献
146.
Toby Cubitt Aram W. Harrow Debbie Leung Ashley Montanaro Andreas Winter 《Communications in Mathematical Physics》2008,284(1):281-290
Complementing recent progress on the additivity conjecture of quantum information theory, showing that the minimum output
p-Rényi entropies of channels are not generally additive for p > 1, we demonstrate here by a careful random selection argument that also at p = 0, and consequently for sufficiently small p, there exist counterexamples.
An explicit construction of two channels from 4 to 3 dimensions is given, which have non-multiplicative minimum output rank;
for this pair of channels, numerics strongly suggest that the p-Rényi entropy is non-additive for all p ≲ 0.11. We conjecture however that violations of additivity exist for all p < 1. 相似文献
147.
We are interested in the problem of scheduling orders for different product types in a facility with a number of machines
in parallel. Each order asks for certain amounts of various different product types which can be produced concurrently. Each
product type can be produced on a subset of the machines. Two extreme cases of machine environments are of interest. In the
first case, each product type can be produced on one and only one machine which is dedicated to that product type. In the
second case, all machines are identical and flexible; each product type can be produced by any one of the machines. Moreover,
when a machine in this case switches over from one product type to another, no setup is required. Each order has a release
date and a weight. Preemptions are not allowed. The objective is minimizing the total weighted completion time of the orders.
Even when all orders are available at time 0, both types of machine environments have been shown to be NP-hard for any fixed
number (≥2) of machines. This paper focuses on the design and analysis of approximation algorithms for these two machine environments.
We also present empirical comparisons of the various algorithms. The conclusions from the empirical analyses provide insights
into the trade-offs with regard to solution quality, speed, and memory space.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users.
This research is supported by the National Science Foundation through grants DMI-0300156 and DMI-0245603. 相似文献
148.
Lamellarin K is a complex pyrrole natural product and member of the lamellarin family – a group of natural products known for their potent biological activities, such as, antiproliferative activity and inhibition of P-gp mediated drug efflux pumps. We herein describe the synthesis of the N-benzyl-des-D ring analogue of lamellarin K using a route that centres on an acyl-Claisen reaction to eventually prepare a highly-functionalised 1-aryl-4-methyl-1,4-diketone. Paal-Knorr pyrrole formation using this diketone undergoes auto-oxidation to give a fully-substituted 5-formyl pyrrole which was converted into the natural lactone B ring. Antiproliferative testing of the N-benzyl-des-D ring analogue gave an IC50 of 2.63 μM against the MDA-MB-231 breast cancer cell line. 相似文献
149.
The multi-technique analytical approach has proved to be a very effective tool for the analysis of artwork, as demonstrated by various studies. In this work, four micro-analysis methods were used to analyze the wall painting fragments in Kaiping Diaolou, a world cultural heritage enlisted in 2007. Field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray micro-analysis (EDX), combined with micro Raman and Fourier transform infrared (FT-IR) spectroscopy, provided a vast amount of information concerning the raw materials present in the pigments, organic binder, plasters and mortars of the wall painting. Four types of pigments (goethite, lazurite, chromium green and calcite) were identified on the surface layer of the wall paintings. The substrate under the pigment layer was found to be composed of cubic-like calcite (CaCO3), micro-rod bundle-shaped syngenite (K2Ca(SO4)2·H2O), gypsum (CaSO4·2H2O) and silica (SiO2). The organic binder can be attributed to animal glue (such as egg) and drying oil by micro FT-IR spectroscopy. These analysis results can provide important information for the conservation and restoration of the Kaiping Diaolou. 相似文献
150.
The first example of a polystyrene bearing two distinct reagent groups has been prepared. This phosphine and amine functionalized material was used in one-pot Wittig reactions with an aldehyde and either an α-halo-ester, -ketone, or -amide. Due to the heterogeneous nature of the polymer, the desired alkene product of these reactions could be isolated in excellent yield in essentially pure form after only filtration and solvent removal. 相似文献