Acyclovir terminated thiophosphate dendrimers

An efficient synthesis of antiviral dendritic prodrug candidates, water-soluble, polyanionic conjugates of 1st and 2nd generation thiophosphate dendrimers with acyclovir, is described.     

Searching for new conditions for fermion N-representability

New elements of the dual cone of the set of fermion N-representable 2-density operators are proposed. So far, the explicit form of the corresponding necessary conditions for N-representability is obtained for N = 3. In this case the new condition is stronger than the known B- and C-conditions for 3-representability. The results provide evidence that in the spectral decomposition of the N-representable 2-density operator there exists an intrinsic relation between the eigenvalue and the corresponding eigenfunction.     

Thermal Analysis in Examination of Reduction of Blast Furnace Pellets

This paper presents applications of thermal analysis to observe the course of reduction of acidic pellets, metallurgical substances whose reducibility and strength are basic parameters of use in blast furnace processes. Both parameters depend on the mineral composition of the samples. The investigations included determination of the chemical and phase compositions of the initial samples and reduction products. Research was conducted on acidic pellets from Połtawa (Poland), applied in the T. Sendzimir Steelworks (Poland), in comparison with pellets from Brazil, Canada and Lebedyn (Russia). This revised version was published online in August 2006 with corrections to the Cover Date.     

On mechano-chemical Calcium waves

The influence of mechano-chemical coupling on calcium concentration waves is considered. The propagation of calcium waves is described by a reaction–diffusion equation with the reaction term dependent on the mechanical stress responsible for the release of calcium. Similarly the balance of mechanical forces is influenced by the calcium concentration through the so-called traction force.     

Hausdorff Measures versus Equilibrium States of Conformal Infinite Iterated Function Systems

Dealing with infinite iterated function systems we introduce and develop the ergodic theory of Hölder systems of functions similarly as in [HU] and [HMU]. In the context of conformal infinite iterated function systems we prove the volume lemma for the Hausdorff dimension of the projection onto the limit set of a shift invariant measure. This can be considered as a Billingsley type result. Our cenral goal is to demonstrate the appearance of the "singularity-absolute continuity" dichotomy for equilibrium states of Hölder systems of functions which has been observed in [PUZ,I] and [PUZ,II] (see also [DU1] and [DU2]) in the setting of rational functions of the Riemann sphere.     

Activity of TiO2 deposited by the CVD method on ammoxidized surface of a carbonaceous material in hydrogenation of styrene

Hydrogenation of styrene has been applied as a test reaction to study the catalytic activity of TiO₂ deposited by the CVD (chemical vapour deposition) method on the surface of a carbonaceous material enriched in nitrogen (C_N).     

The effect of fluorine-based plasma treatment on morphology and chemical surface composition of biocompatible silicone elastomer

X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) have been used to investigate the effect of reactive ion etching (RIE) on poly(methylhydrogensiloxane-co-dimethylsiloxane) surface in fluorine-based plasmas. Polysiloxane layers supported on the standard silicon wafers were etched using SF₆ + O₂ or CF₄ + O₂ plasmas. SEM studies show that the polysiloxane morphology depends on plasma chemical composition strongly. Presence of a columnar layer likely covered with a fluorine rich compound was found on the elastomer surface after the CF₄ + O₂ plasma exposure. After the SF₆ + O₂ or CF₄ + O₂ plasma treatment the polysiloxane surface enriches with fluorine or with fluorine and aluminum, respectively. Different morphologies and surface chemical compositions of the silicone elastomer etched in both plasmas indicate different etching mechanisms.     

Mechanical properties of metallic ribbons investigated by depth sensing indentation technique

The paper presents mechanical properties of two kinds of Co-based and one Fe-based metallic ribbons by the depth sensing indentation (DSI) technique. Investigations were carried out on two kinds ternary alloy Co₇₇Si_11,5B_11,5 and Fe₇₈Si₁₃B₉ and multicomponent Co₆₈Fe₄Mo₁Si_13,5B_13,5, which are so-called “zero-magnetostriction” materials. Metallic ribbons were investigated in amorphous state and partially crystallized state after annealing in 400°C in argon atmosphere. Heating of ribbons obtained by melt spinning technique was performed to check its effect on changes of mechanical properties.