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51.
We give a characterization, in one variable case, of those multipliers F such that the division problem is solvable in . For these functions we even prove that the multiplication operator has a continuous linear right inverse on , in contrast to what happens in the several variables case, as was shown by Langenbruch. 相似文献
52.
53.
Daniel Sabanés Bové Leonhard Held Göran Kauermann 《Journal of computational and graphical statistics》2013,22(2):394-415
We propose an objective Bayesian approach to the selection of covariates and their penalized splines transformations in generalized additive models. The methodology is based on a combination of continuous mixtures of g-priors for model parameters and a multiplicity-correction prior for the models themselves. We introduce our approach in the normal model and extend it to nonnormal exponential families. A simulation study and an application with binary outcome is provided. An efficient implementation is available in the R package hypergsplines. Supplementary materials for this article are available online. 相似文献
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C. Kippenberger G. Freyss und Leonhard Manslock 《Fresenius' Journal of Analytical Chemistry》1904,43(10):636-637
Ohne Zusammenfassung 相似文献
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Leonhard Birkofer 《欧洲无机化学杂志》1943,76(8):769-773
58.
Clifford S. Leonhard 《Fresenius' Journal of Analytical Chemistry》1926,69(3):137-138
Ohne Zusammenfassung 相似文献
59.
Radha G. Bhuin Leonhard Winter Matthias Lexow Florian Maier Hans‐Peter Steinrück 《Angewandte Chemie (International ed. in English)》2020,59(34):14429-14433
The impact of a reactant from the gas phase on the surface of a liquid and its transfer through this gas/liquid interface are crucial for various concepts applying ionic liquids (ILs) in catalysis. We investigated the first step of the adsorption dynamics of n‐butane on a series of 1‐alkyl‐3‐methylimidazolium bis(trifluoromethanesulfonyl)imide ILs ([CnC1Im][Tf2N]; n=1, 2, 3, 8). Using a supersonic molecular beam in ultra‐high vacuum, the trapping of n‐butane on the frozen ILs was determined as a function of surface temperature, between 90 and 125 K. On the C8‐ and C3‐ILs, n‐butane adsorbs at 90 K with an initial trapping probability of ≈0.89. The adsorption energy increases with increasing length of the IL alkyl chain, whereas the ionic headgroups seem to interact only weakly with n‐butane. The absence of adsorption on the C1‐ and C2‐ILs is attributed to a too short residence time on the IL surface to form nuclei for condensation even at 90 K. 相似文献
60.
Dr. Joseph F. DeJesus Lindy M. Sherman Darius J. Yohannan Jeffrey C. Becca Shelby L. Strausser Leonhard F. P. Karger Dr. Lasse Jensen Dr. David M. Jenkins Dr. Jon P. Camden 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(19):7655-7660
The remarkable resilience of N-heterocyclic carbene (NHC) gold bonds has quickly made NHCs the ligand of choice when functionalizing gold surfaces. Despite rapid progress using deposition from free or CO2-protected NHCs, synthetic challenges hinder the functionalization of NHC surfaces with protic functional groups, such as alcohols and amines, particularly on larger nanoparticles. Here, we synthesize NHC-functionalized gold surfaces from gold(I) NHC complexes and aqueous nanoparticles without the need for additional reagents, enabling otherwise difficult functional groups to be appended to the carbene. The resilience of the NHC−Au bond allows for multi-step post-synthetic modification. Beginning with the nitro-NHC, we form an amine-NHC terminated surface, which further undergoes amide coupling with carboxylic acids. The simplicity of this approach, its compatibility with aqueous nanoparticle solutions, and its ability to yield protic functionality, greatly expands the potential of NHC-functionalized noble metal surfaces. 相似文献