全文获取类型
收费全文 | 557篇 |
免费 | 7篇 |
国内免费 | 1篇 |
专业分类
化学 | 328篇 |
晶体学 | 2篇 |
力学 | 7篇 |
数学 | 102篇 |
物理学 | 126篇 |
出版年
2022年 | 6篇 |
2020年 | 9篇 |
2019年 | 6篇 |
2017年 | 7篇 |
2016年 | 8篇 |
2015年 | 8篇 |
2013年 | 23篇 |
2012年 | 11篇 |
2011年 | 9篇 |
2010年 | 13篇 |
2009年 | 10篇 |
2008年 | 13篇 |
2007年 | 20篇 |
2006年 | 16篇 |
2005年 | 11篇 |
2004年 | 16篇 |
2003年 | 12篇 |
2002年 | 6篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 7篇 |
1996年 | 6篇 |
1995年 | 7篇 |
1994年 | 14篇 |
1993年 | 11篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 11篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 13篇 |
1981年 | 7篇 |
1980年 | 6篇 |
1979年 | 11篇 |
1978年 | 7篇 |
1977年 | 8篇 |
1976年 | 5篇 |
1975年 | 7篇 |
1974年 | 7篇 |
1973年 | 6篇 |
1963年 | 5篇 |
1962年 | 5篇 |
1958年 | 5篇 |
1895年 | 5篇 |
1890年 | 6篇 |
1886年 | 10篇 |
1882年 | 9篇 |
排序方式: 共有565条查询结果,搜索用时 15 毫秒
21.
Kenneth Gonsalves Lin Zhan-Ru Robert W. Lenz Marvin D. Rausch 《Journal of polymer science. Part A, Polymer chemistry》1985,23(6):1707-1722
Three types of isopropenylmetallocene monomers were synthesized and subjected to polymerization and copolymerization by cationic initiators; (1) isopropenylferrocene (IF); (2) (η5-isopropenylcyclopentadienyl)dicarbonylnitrosylmolybdenum (IDM); and (3) 1,1′-diisopropenylcyclopentadienylstannocene (DIS), and related derivatives of each. IF was synthesized by a three-step procedure involving the acetylation of ferrocene, conversion of the latter to 2-ferrocenyl-2-propanol, and dehydration of the carbinol. IF was homopolymerized under various cationic initiation conditions, but only low molecular weight homopolymers were obtained. Copolymerization of IF with styrene and with p-methoxy-α-methylstyrene also gave only low molecular weight products. The formation of only low molecular weight polymers in all polymerization reactions is believed to result from the effect of the unusually high stability of ferrocenyl carbenium ions on its propagation reaction. The observed polymerization behavior of α-trifluoromethylvinylferrocene is in accord with this conclusion. IDM and DIS did not form polymeric products under cationic conditions, although copolymers could be obtained for each of these monomers and styrene with a free radical polymerization initiator (AIBN). 相似文献
22.
Robert w. Lenz 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(6):945-959
Alkyl α-chloroacrylates and p-substituted α-methylstyrenes were investigated for the effect of polymerization conditions on tacticity, molecular weight, and distribution, and for the relationship between tacticity, glass temperature, and crystalline properties. 相似文献
23.
24.
Elisabeth Siebert Marius Horch Yvonne Rippers Johannes Fritsch Stefan Frielingsdorf Oliver Lenz Francisco VelazquezEscobar Friedrich Siebert Lars Paasche Uwe Kuhlmann Friedhelm Lendzian Maria‐Andrea Mroginski Ingo Zebger Peter Hildebrandt 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2013,125(19):5267-5270
25.
Clostridium botulinum type E is a cold-tolerant, neurotoxigenic, endospore-forming organism, primarily associated with aquatic environments. High pressure thermal (HPT) processing presents a promising tool to enhance food safety and stability. The effect of fat on HPT inactivation of C. botulinum type E spores was investigated using an emulsion model system. The distribution of spores in oil-in-water (O/W) emulsions and their HPT (300–750?MPa, 45–75?°C, 10?min) inactivation was determined as a function of emulsion fat content (30–70% (v/v) soybean oil in buffer). Approximately 26% and 74% of the spores were located at the oil–buffer interface and the continuous phase, respectively. Spore inactivation in emulsion systems decreased with increasing oil contents, which suggests that the fat content of food plays an important role in the protection of C. botulinum type E endospores against HPT treatments. These results can be helpful for future safety considerations. 相似文献
26.
A series of thermotropic aromatic polyesters based on a triad ester mesogenic unit containing an arylsulfonyl substituted hydroquinone group and a decamethylene spacer group was prepared. The large arylsulfonyl substituent was substituted in the para-position with either electron donating or accepting groups to study the effect of steric and polar interactions on the thermal transitions of these polymers and on the thermodynamic parameters of their isotropization transitions. All polymers formed nematic melts, and a regular decrease in T1, ΔH1 and ΔS1 was observed with increasing molecular radius of the substituted hydroquinone group. However, a polarity or polarizability effect was superimposed on these relationships. Model compounds containing the same aromatic ester triad were prepared and their thermotropic properties were compared to those of the polymers. Essentially identical effects were observed for both. 相似文献
27.
Optically pure methyl, ethyl, isopropyl, and benzyl (R)-malolactonate were prepared from (S)-(-)-malic acid and were polymerized in the bulk with tetraethylammonium benzoate as the initiator to yield high-molecular-weight, crystalline polymers. The optical purity of methyl and benzyl malolactonate was determined by 1H NMR spectroscopy of the β-lactone complexed with a chiral europium shift reagent. Enantiomeric excesses of 100% were found (the experimental error was 3%). Optically active poly(β-malic acid) was obtained from optically active poly[benzyl (S)-malate] by catalytic hydrogenolysis of the pendent benzyl esters. Ethyl and benzyl (R)-malolactonate were also copolymerized, and the benzyl esters of the resulting copolymer were converted into carboxylic acid units by hydrogenolysis. 相似文献
28.
29.
A. Lau M. Pfeiffer W. Werncke H.-J. Weigmann K. Lenz 《Journal of Raman spectroscopy : JRS》1988,19(5):353-357
Resonance CARS line-shape analysis has been applied to determine the parameters of the excited electronic state potential curves of a cyanine dye and its short-lived photoisomers during the process of photoisomerization. For this very complicated situation other methods for the estimation of these values would fail. The origin shift parameters determined are very small and the homogeneous line width is smaller than the line width of the absorption band. 相似文献
30.
MaxwellD. Cummings Jimmy Lindberg Tse‐I Lin Herman deKock Oliver Lenz Elisabet Lilja Sara Fellnder Vera Baraznenok Susanne Nystrm Magnus Nilsson Lotta Vrang Michael Edlund sa Rosenquist Bertil Samuelsson Pierre Raboisson Kenneth Simmen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2010,122(9):1552-1552