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The experiments have been performed with a semi-continuous batch reactor to investigate the degradation efficiency of nitrobenzene in aqueous solution by ultrasound with the different orthogonal dual frequencies catalytic ozonation. The introduction of ultrasound can enhance the degradation efficiency of nitrobenzene compared to the results obtained from the processes of ozonation alone and ultrasound alone. The degradation of nitrobenzene is found to be zero-order in the two systems of ultrasound alone, and the reactions follow the pseudo-first-order kinetic model in the processes of ozone alone and ozone/ultrasound. The investigation confirms that the degradation of nitrobenzene follows the mechanism of hydroxyl radical (•OH) oxidation, and the enhancement function is even more pronounced in the presence of ultrasound with the greater difference between the orthogonal dual frequencies due to the obvious synergetic effect between ozone and ultrasound, which increases the utilization efficiency of ozone, and accelerates the initiation of •OH and the formation of H2O2, resulting in the rapid formation of an increasing diversity of byproducts and the advancement degree of mineralization of total organic carbon (TOC). The oxidative byproducts have been, respectively identified in the different processes selected, including o, p, m-nitrophenols, phenol, malonic acid, 4-nitrocatechol, nitrate ion, maleic acid, oxalic acid, hydroquinone, p-quinone, 1,2,3-trihydroxy-5-nitrobenzene and acetic acid. 相似文献
24.
In this paper, we propose a sinusoidal phase modulating (SPM) interferometer that is insensitive to external disturbances, and its measuring principle is analyzed theoretically. In the SPM interferometer, the interference signal is detected by a high-speed image sensor based on a low-speed CCD and a signal processing circuit is used to obtain the phase of each point on the surface. Therefore, the surface profile can be measured real-time. The experiments measuring the surface profile of a wedge-shaped optical flat show that the measurement time of the SPM interferometer is less than 10 ms, the repetitive measurement accuracy is 4.2 nm. The results show that the impacts of nonlinear distortion of the piezoelectric transducer (PZT) and part external disturbance are removed. 相似文献
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The DNA primary sequence is translated into “structure graph” based on classification of its four bases. Then the invariants, such as topological indices, are extracted from those graphic representations of DNA primary sequences, and used to calculate the similarities among the eleven species. From these similarities/dissimilarities the homologies can be revealed that they are in agreement with evolutionary relation satisfactorily. 相似文献
27.
Disk-ring multiferroic heterostructures composed of Terfenol-D and Pb(Zr,Ti)O3 (PZT) were prepared and characterized, for which the ferromagnetic and ferroelectric phases were coupled through normal stresses
instead of the shear stresses that acted in most of the previous multiferroic heterostructures. High low-frequency magnetoelectric
coefficients of 0.10–0.75 V cm−1 Oe−1 were attained for the disk-ring heterostructures, which indicated the strong magnetoelectric coupling. Moreover, a symmetrical
resonant peak was observed for dE
3/dH
3 in the frequency range of 1–200 kHz, while another weak peak with asymmetrical shape also existed at a lower frequency for
dE
3/dH
1, which was due to the combination of two vibration modes. 相似文献
28.
Jiahui Fu Wan Chen Changfei Zhou Lei Zhu Qun Wu 《Applied Physics A: Materials Science & Processing》2014,116(1):327-332
In this paper, a circular polarized electronically-controlled scanning microstrip antenna array is designed, which is based on composite right left-handed transmission line (CRLH TL) and is realized by varactor diodes. Proposed electronically-controlled antenna arrays till now are always linear-polarized as the axial ratio (AR) may be spoiled by the DC feed line, especially in the CRLH TL based case. A more separated CRLH TL integrated with active lumped elements is utilized to solve the problem. The antenna array is composed of the CRLH microstrip transmission line structure and circular polarized microstrip antenna. The direction of the main lobe varies from ?1° to ?20 ° by continuously modifying the varactor diodes bias voltages from 0 to 20 V with 5 V as a step. The AR remains below 3 dB in the scanning range. The simulation and experimental results show a good consistence. 相似文献
29.
Lei Shi Songnan Chu Jiyin Zhao Yang Wang Yuqiao Guo Cailin Wang 《Applied Physics A: Materials Science & Processing》2014,114(3):833-838
In antiperovskite intermetallics ZnCNi3?x Mn x , the negative slope coefficient (NSC) dρ/dT of resistivity–temperature curves is observed when x=1.15,1.25,1.4,1.5. The sample with x=1.25 shows a semiconductor-like behavior in the whole temperature range of 15–290 K. By study of the magnetization, magnetoresistance, and low-temperature X-ray diffraction, it is found that Mn dopant significantly affects the physical properties of ZnCNi3?x Mn x by changing both the carrier density and the magnetism. The origin of the NSC dρ/dT can be ascribed to the change of hole-like carrier density, which is adjusted by Mn content. The existence of hole-like carriers can be understood rationally by the two-band model. The change of sign of magnetoresistance from positive to negative has been observed in ZnCNi3?x Mn x with the change of Mn content, which could be ascribed to the competition between the contribution from field-induced suppression of the thermally excited ferromagnetic spin fluctuations and the Lorentz contribution. When Mn content is low, the Lorentz contribution dominates the sign of magnetoresistance. On the other hand, when Mn content is high, the contribution from field-induced suppression of the thermally excited ferromagnetic spin fluctuations dominates the sign of magnetoresistance. 相似文献
30.