Millimeter-Wave Spectra and Global Torsion-Rotation Analysis for the CH(3)OD Isotopomer of Methanol

New millimeter-wave and microwave measurements for CH(3)OD have been combined with previous literature data and with an extended body of Fourier transform far-infrared observations in a full global analysis of the first two torsional states (v(t) = 0 and 1) of the ground vibrational state. The fitted CH(3)OD data set contained 564 microwave and millimeter-wave lines and 4664 far-infrared lines, representing the most recent available information in the quantum number ranges J 相似文献   

Rotation-torsion-vibration term-value mapping for CH3OH: Torsion-mediated doorways and corridors for intermode population transfer

Fourier transform infrared spectra of CH₃OH from 930-1650 cm⁻¹ have been analyzed to reveal details of the rotation-torsion-vibration energy manifold of the CO-stretching, CH₃-rocking, OH-bending and CH₃-deformation modes and their torsional combination states. Mapping of the upper-state term values as a function of the rotational quantum number J has shown the locations of numerous substate crossing resonances that give rise to J-localized spectral perturbations and substate mixing and thereby create “doorways” for collision-induced population transfer among the different modes. Other near-degenerate substates are more globally mixed over a wide range of J, corresponding to “corridors” of doorways. Where both partner substates in a doorway resonance have been identified, the perturbations have been analyzed to find estimates of the interaction matrix elements and the degree of mixing between the coupled states. Many of the resonances are between substates of differing torsional quantum number, highlighting the importance of torsion in generating the doorway channels and enhancing intermode vibrational population transfer.     

Observation of B0-->omega K0, B+-->eta pi+, and B+-->eta K+ and study of related decays

We present measurements of branching fractions and charge asymmetries for seven B-meson decays with an eta, eta', or omega meson in the final state. The data sample corresponds to 89x10(6) BB pairs produced from e(+)e(-) annihilation at the Upsilon(4S) resonance. We measure the following branching fractions in units of 10(-6): B(B+-->eta pi(+))=5.3+/-1.0+/-0.3, B(B+-->eta K+)=3.4+/-0.8+/-0.2, B(B0-->eta K0)=2.9+/-1.0+/-0.2 (<5.2, 90% C.L.), B(B+-->eta(')pi(+))=2.7+/-1.2+/-0.3 (<4.5, 90% C.L.), B(B+-->omega pi(+))=5.5+/-0.9+/-0.5, B(B+-->omega K+)=4.8+/-0.8+/-0.4, and B(B0-->omega K0)=5.9(+1.6)(-1.3)+/-0.5. The charge asymmetries are A(ch)(B+-->eta pi(+))=-0.44+/-0.18+/-0.01, A(ch)(B+-->eta K+)=-0.52+/-0.24+/-0.01, A(ch)(B+-->omega pi(+))=0.03+/-0.16+/-0.01, and A(ch)(B+-->omega K+)=-0.09+/-0.17+/-0.01.     

Production and decay of Omegac0

We present an analysis of inclusive Omega(c)(0) baryon production and decays in 230.5 fb(-1) of data recorded with the BABAR detector. Omega(c)(0) baryons are reconstructed in four final states (Omega(-)pi(+), Omega(-)pi(+)pi(0), Omega(-)pi(+)pi(+)pi(-), Xi(-)K(-)pi(+)pi(+)) and the corresponding ratios of branching fractions are measured. We also measure the momentum spectrum in the e(+)e(-) center-of-mass frame. From the spectrum, we observe Omega(c)(0) production from B decays and in cc events, and extract the two rates of production.     

Evidence for B(0) --> rho(0)rho(0) decays and implications for the Cabibbo-Kobayashi-Maskawa angle alpha

We search for the decays B(0) --> rho(0)rho(0), B(0) --> rho(0)f(0)(980), and B(0) --> f(0)(980)f(0)(980) in a sample of about 384 x 10(6) Upsilon(4S) --> BB[over] decays collected with the BABAR detector at the PEP-II asymmetric-energy e(+)e(-) collider at Stanford Linear Accelerator Center. We find evidence for B(0) --> rho(0)rho(0) with 3.5 sigma significance and measure the branching fraction B = (1.07 +/- 0.33 +/- 0.19) x 10(-6) and longitudinal polarization fraction f(L) = 0.87 +/- 0.13 +/- 0.04, where the first uncertainty is statistical, and the second is systematic. The uncertainty on the Cabibbo-Kobayashi-Maskawa quark-mixing matrix unitarity angle alpha due to penguin contributions in B --> rho rho decays is 18 degrees at the 1 sigma level. We also set upper limits on the B(0) --> rho(0)f(0)(980) and B(0) --> f(0)(980)f(0)(980) decay rates.     

Vector-tensor and vector-vector decay amplitude analysis of B0-->phiK*0

We perform an amplitude analysis of the decays B(0)-->phiK*(2)(1430)(0), phiK*(892)(0), and phi(Kpi)(0)(S-wave) with a sample of about 384x10(6) BB[over ] pairs recorded with the BABAR detector. The fractions of longitudinal polarization f(L) of the vector-tensor and vector-vector decay modes are measured to be 0.853(-0.069+0.061)+/-0.036 and 0.506+/-0.040+/-0.015, respectively. Overall, twelve parameters are measured for the vector-vector decay and seven parameters for the vector-tensor decay, including the branching fractions and parameters sensitive to CP violation.     

Evidence for D0-D0 mixing

We observe evidence for D(0)-D(0) mixing by measuring the difference in the apparent lifetime when a D(0) meson decays to the CP eigenstates K(+)K(-) and pi(+)pi(-) and when it decays to the final state K(-)pi(+). We find the relative difference of the lifetimes y(CP) to be [1.31+/-0.32(stat)+/-0.25(syst)]%, 3.2 standard deviations from zero. We also search for a CP asymmetry between D(0) and D(0) decays; no evidence for CP violation is found. These results are based on 540 fb(-1) of data recorded by the Belle detector at the KEKB e(+)e(-) collider.     

Improved limits on the lepton-flavor violating decays tau{-}-->l{-}l{+}l{-}

A search for the neutrinoless, lepton-flavor violating decay of the tau lepton into three charged leptons has been performed using 376 fb{-1} of data collected at an e{+}e{-} center-of-mass energy around 10.58 GeV with the BABAR detector at the SLAC PEP-II storage rings. In all six decay modes considered, the numbers of events found in data are compatible with the background expectations. Upper limits on the branching fractions are set in the range (4-8)x10{-8} at 90% confidence level.     

Evolving window zone selection method followed by independent component analysis as useful chemometric tools to discriminate between grapefruit juice, orange juice and blends

This study investigates the use of high resolution ¹H NMR as a suitable alternative to the standard chromatographic method for the determination of adulteration of orange juice (Citrus sinensis) with grapefruit juice (Citrus paradisi) based on flavonoid glycoside content. Fifty-nine orange juices (OJ), 23 grapefruit juices (GJ) and 10 blends (OG), obtained from local retail outlets were used to assess the performance of the ¹H NMR method. The work presented here introduces the Evolving Window Zone Selection (EWZS) function that holds promise for the automatic detection of spectral regions tailored to discriminate predefined groups. This technique was applied on the pre-processed ¹H NMR spectra of the 92 juices. Independent Component Analysis (ICA) is a good alternative to Principal Component Analysis (PCA) for recovering linearly-mixed unobserved multidimensional independent signals and has been used in this study to build supervised models that classify the samples into three categories, OJ, GJ, OG. The regions containing the known flavonoid glycoside markers were selected as well as another zone containing the signals of sucrose, α-glucose and other components that were tentatively attributed. ICA was applied on three different groups of selected variables and showed good results for both discrimination and interpretation of the signals. Up to 97.8% of the juices were correctly attributed. This method gave better results than the commonly used PCA method. In addition, the time required to carry out the ¹H NMR analysis was less than half the time of the standard chromatographic method.     

A Control Volume Radial Basis Function Techniques for the Numerical Simulation of Saturated Flows in Semi-confined Aquifer

In this work, a Control Volume Radial Basis Function technique (CV-RBF) is adapted to solve ground water flow in the saturated zone of the semi-confined aquifer. The CV-RBF method differs from classical CV methods in the way that the flux at the cell surfaces is computed. A local RBF interpolation of the field variable is performed at the centres of the cell being integrated and its neighbours. This interpolation is then used to reconstruct the solution and its gradient in the integration points which support the flux computation. In addition, it is required that such interpolation satisfies the governing equation in a certain number of points placed around the cell centres. In this way, the local interpolations become equivalent to local boundary-value problems. The CV-RBF method is combined with a local remeshing technique in order to track the phreatic surface, where the gradients required to satisfy the kinematic condition are computed by the same local RBF interpolations used for the flux computation. The proposed numerical approach is validated in a series of three-dimensional groundwater flow problems where the operations of recharging and extracting water from a semi-confined aquifer are modelled.