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151.
The fluorescence dynamics parameters of the fluorescent transient flavin-luciferase species from the typesVibrio fischeri andPhotobacterium leiognathi are presented. The fluorescence anisotropy decay is a single exponential function for both types. The correlation time is 70 ns for theP. leiognathi fluorescent transient intermediate (2°C, aqueous buffer, pH 7.0), consistent with the rotational correlation time of the luciferase macromolecule (77 kD) to which the flavin fluorophore is rigidly attached. In contrast, for theV. fischeri species the observed correlation time for the anisotropy decay function is 133 ns. This suggests that protein self-association occurs in theV. fischeri case and this is confirmed by filtration, where the fluorescent transient fromV. fischeri does not pass through a 100,000 molecular weight cutoff membrane, whereas theP. leiognathi species does. The filtration method also demonstrates self-association in the luciferase peroxyflavin and photoflavin fromV. fischeri. A monomer-dimer equilibrium also explains the previously reported high correlation times for theV. harveyi luciferase-flavin species. It is proposed that the self-association competes with the lumazine protein interaction in the bioluminescence reaction. 相似文献
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154.
We study the Bloch oscillations of two-component Bose-Einstein condensates trapped in spin-dependent optical lattices. The influence of the intercomponent atom interaction on the system is discussed in detail Accelerated breakdown of the Bloch oscillations and revival phenomena are found respectively for the repulsive and attractive case. For both the cases, the system will finally be set in a quantum self-trapping state due to dynamical instability. 相似文献
155.
Mi Jung Lee 《Tetrahedron letters》2006,47(8):1355-1358
A new and regioselective [4+2] benzannulation protocol toward polysubstituted benzenes was developed. Nitroalkane derivative, which was prepared from Baylis-Hillman adduct, served as the four-carbon unit and Michael acceptor as a two-carbon unit. 相似文献
156.
157.
Crack initiation and stable crack growth under monotonic loading in steels has been studied using an elastic-plastic finite element analysis. The fracture criterion used for crack initiation and stable crack growth was the critical strain energy density. In addition the shift core method for the analysis of crack extension was used. In the shift core modelling method, crack advance is simulated by moving the coordinates of the core region which surrounds the crack tip, to obtain the stiffness reduction. Simultaneously the core itself geometrically undergoes a simple rigid-body motion or translation during the crack extension. The analytically calculated and experimentally measured load for crack initiation and the subsequent stable crack growth agreed well. 相似文献
158.
159.
Thermotropic copolyester fibers of oxynaphthoate and oxybenzoate have been subjected to conditions that promote solid-state polymerization as well as annealing. The annealing process causes the crystals to perfect with a simultaneous increase in heat of fusion and melting temperature. Solid-state polymerization, a reaction rate-controlled process, causes the polymer viscosity average molecular weight to increase by chain extension from about 14,000 g/mole to more than 87,000 g/mole with a simultaneous impressive increase in tenacity from about 10 g/d (1.2 GPa) to almost 30 g/d (3.7 GPa). To understand the changes in mechanical properties, we have modeled the fiber structure as short rod-like molecules poorly bonded to a continuous matrix of parallel molecules. Lengthening of the reinforcing molecules facilitates better transfer of load from matrix to molecules, resulting in higher tenacity fibers. © 1994 John Wiley & Sons, Inc. 相似文献
160.
beta-Glucosidase and beta-glucuronidase of human and rat fecal bacteria were induced by cultivation in alkaline media although their growths were not affected. When a bacterium isolated from human feces producing each enzyme was cultured in a medium at pH 5 for 12-15 h and then adjusted to pH 8, beta-glucosidase and beta-glucuronidase were induced 9.2-fold and 11.5-fold, respectively. 相似文献