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71.
Kuan Fang Ren Grard Gouesbet Grad Ghan Denis Lebrun Cafer
zkul Alain Kleitz 《Particle & Particle Systems Characterization》1996,13(2):156-164
Imaging techniques in particle sizing have always been important. Nevertheless, owing to the progress in CCD cameras, these techniques have found new potential which strongly depends on the capability to describe the image formation. Based on a combination of the generalized Lorenz-Mie theory and the diffraction theory, the image characteristics are described, taking into account the beam size, particle location, direction of observation and collecting optics characteristics. In the case of forward detection, a finite coherence is introduced and the results are compared with those obtained by a convolution approach, with the point spread function assumed to be Gaussian. Then some experimental results are displayed which underline the improvement achieved in particle size measurement. 相似文献
72.
A. Possoz Ph. Deschepper L. Grenacs P. Lebrun J. Lehmann L. Palffy A. De Moura Gonçalves C. Samour V.L. Telegdi 《Physics letters. [Part B]》1977,70(2):265-268
The helicity, h?, of μ? in π-decay has been determined as positive (h??+0.90) from the average polarization, Pav≡〈JB·sμ〉, of 12B produced in the reaction. We obtain also dynamical information on μ-capture: (i) the weak magnetism form factor, μ=4.5±1.1, and (ii) the sum of the induced pseudoscalar (gp) and the 2nd class induced tensor (gT) couplings versus gA, (. The latter result, adopting the “canonical” value of , leads to which is compatible with zero and in strong contradiction with the value ?—6 recently advocated by Kubodera, Delorme and Rho. 相似文献
73.
M H Lebrun F Gaudemer M Boutar L Nicolas A Gaudemer 《Journal of chromatography. A》1989,464(2):307-322
The ion-pair, ligand-exchange and anion-exchange chromatography of the fungal metabolic tenuazonic acid (TA) and its related 3-acetyl 5-substituted pyrrolidine-2,4-diones were studied. Ion-pair chromatography was performed on a C18 column with a mobile phase composed of cetrimide, phosphate buffer in water-methanol and a metal complexant (ethylenediamine) to improve the peak sharpness. Addition of the same metal complexant to the mobile phase of the anion-exchange chromatographic system also improved its efficiency. TA and its 5-substituted analogues derived from valine and leucine were separated with the ion-pair and anion-exchange chromatographic systems. With ligand-exchange chromatography, TA could only be separated from its valine analogue. These chromatographic systems were used for the detection of TA in the culture filtrates of the fungus Pyricularia oryzae and in infected rice leaves. Deproteinated culture filtrates could be rapidly analysed for their TA content by anion-exchange chromatography. However, this system was not suitable for the detection of TA in the infected rice leaf as interfering compounds were coeluted with TA. Ion-pair and ligand-exchange chromatographic systems allowed the efficient quantification of TA in infected leaves. 相似文献
74.
New mu-oxo-diferric complexes have been designed for hydrolysis of phosphodiesters. To mimic the diiron active site of purple acid phosphatase, a combinatorial method has been used to select complexes containing two distinct iron coordination spheres. The introduction of a bidentate ligand, a substituted phenanthroline (L) into complex 1, [Fe2O(bipy)4(OH2)2](NO3)4, generates in solution the complex [Fe2O(bipy)3(L)(OH2)2](NO3)4 as shown by ESI/MS and 1H NMR studies. The latter complex was found to be 20-fold more active than complex 1. On the basis of kinetic studies, we demonstrated that the complex [Fe2O(bipy)3(L)(OH)(OH2)](NO3)3 was the active species and the reaction proceeded through the formation of a ternary complex in which one iron binds a hydroxide and the second, the substrate. At nonsaturating concentrations of the substrate, the increased activity with increased methyl substituents in L was due to an increased affinity of the complex for the substrate. The activity of [Fe2O(bipy)3(33'44'Me2-Phen)(OH2)2](NO3)4 [33'44'Me2Phen = 3,3',4,4'-dimethyl-1,10-phenanthroline] was found to be comparable to that reported for Co(III) or Ce(IV) complexes. 相似文献
75.
Cren-Olivé C Déprez S Lebrun S Coddeville B Rolando C 《Rapid communications in mass spectrometry : RCM》2000,14(23):2312-2319
Liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) was used for the structural characterization and differentiation of four isomeric O-monomethylated catechins (on phenolic positions) by the analysis of the fragmentation behaviour of catechin. The catechin fragmentation routes were rationalized and it is shown that several diagnostic ions such as (1,3)A(+), (1,2)B(+), and (1,4)B(+) allow the unambiguous identification of the methylated ring. The precise position of the methyl group on each ring is determined by the difference in the relative intensities of the diagnostic ions. Isomeric O-methylepicatechins were also differentiated using this methodology. 相似文献
76.
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78.
A novel complexing membrane was used for the removal of heavy metal ions such as Pb(II), Cd(II) and Cu(II) from aqueous solutions. The membrane consists in a semi-interpenetrating polymer network of crosslinked poly(vinyl alcohol) as the matrix and poly(ethyleneimine) as the complexing polymer. The absorption reactions followed pseudo-first-order kinetics with similar rate constants for the three cations. A model is proposed for the absorption–desorption process in order to rationalize the data obtained for the retention ratio and the retention efficiency ratio. The corresponding equilibrium constants were determined for the three metal ions, showing that the affinity order of the membrane is Pb > Cu > Cd. This sequence is consistent with the order of maximum uptake of the ions per gram of membrane: 0.59, 0.47 and 0.33 mmol g−1, respectively. On the other hand, the uptake order is different on a mass basis: 123, 30 and 37 mg g−1, respectively. Regeneration of the membrane and metal recovery were studied with HCl and HNO3 at different concentrations. Filtration of solutions of each metal ion showed large elimination ratios (96–99.5%) with a retention sequence Cd > Cu > Pb. The membrane remained efficient until complete saturation of its sites. Moreover, Cu retention is larger than expected, indicating possible additional chelation by the PVA matrix. Better retention ratios were observed when the concentration of the feed solution was kept constant. Filtration of a mixture of the three cations (all at 100 ppm concentration) resulted in the same retention sequence, but the elimination ratios were smaller and Pb was eventually displaced by Cu and Cd that were present in larger molar concentrations. 相似文献
79.
Akerlof C Areti H Binkley M Conetti S Cox B Enagonio J Mao H Hojvat C Judd D Katsanevas S Kephart RD Kourkoumelis C Kraushaar P Lebrun P Malhotra PK Markou A Mazur PO Nitz D Resvanis LK Ryan D Ryan T Schappert W Stairs DG Thun R Turkot F Tzamarias S Voulgaris G Wagner RL Wagoner DE Yang W Zhang Nai-jian 《Physical review D: Particles and fields》1993,48(11):5067-5080
80.