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71.
Zusammenfassung Die Indikatorbase 4-Methoxyphenylazo--naphthylamin wird von p-Nitrobenzoylperoxid in neutralem oder saurem Medium ohne, von p-Nitrobenzopersäure unter Erwärmen oxydiert, gar nicht aber von p-Nitroäthylbenzol--hydroperoxid. Auf der Grundlage dieses Verhaltens können die drei Verbindungen unterschieden und p-Nitrobenzoylperoxid nachgewiesen werden. Die Indikatorsäure 4-Nitrophenylazo-2-amino-5-nitrobenzol wird von p-Nitroäthylbenzol--hydroperoxid oxydiert, nicht aber von p-Nitrobenzoylperoxid und p-Nitrobenzopersäure. Mit dieser Farbreaktion kann p-Nitroäthylbenzol--hydroperoxid nachgewiesen werden. p-Nitrobenzopersäure kann neben p-Nitroäthylbenzolhydroperoxid mit einer Farbreaktion von p- + m-Phenylendiamin nachgewiesen werden. Auch p-Nitrobenzoylperoxid gibt die Reaktion, aber p-Nitroäthylbenzol--hydroperoxid setzt sich nicht um.
Detection of peroxides, hydroperoxides, and peracids
Summary The indicator base 4-methoxyphenylazo--naphthylamine is oxidized in neutral medium without warming byp-nitrobenzoyl peroxide, and byp-nitrobenzoperacid with warming, but it is not oxidized at all byp-nitroethylbenzene--hydroperoxide. The three compounds may be differentiated on the basis of these behaviors and furthermore it is thus possible to detect and identifyp-nitrobenzoyl peroxide. The indicator acid 4-nitrophenylazo-2-amino-5-nitrobenzene is oxidized byp-nitroethylbenzene--hydroperoxide but not byp-nitrobenzoyl peroxide andp-nitrobenzoperacid.p-Nitroethylbenzene--hydroperoxide may be detected through this color reaction.p-Nitrobenzoperacid can be detected in the presence ofp-nitroethylbenzene--hydroperoxide by a color reaction withp + m-phenylenediamine but no reaction is given byp-nitroethylbenzene--hydroperoxide.相似文献
72.
A convenient route to new 3-quinolinonyl-pyrazoles and isoxazoles is described through cyclization of 3-[(E)-3-(dimethylamino)-2-propenoyl]-4-hydroxy-1-methyl-2(1H)-quinolinone. The phototoxicity as well as the cytotoxic activities of the title compounds are evaluated against leukemia- and adenocarcinoma-derived cell lines in comparison to the normal human keratinocytes. 相似文献
73.
74.
Carlo Bruno Eleonora Ussano Gianni Barucca Davide Vanossi Giovanni Valenti Edward A. Jackson Andrea Goldoni Lucio Litti Simona Fermani Luca Pasquali Moreno Meneghetti Claudio Fontanesi Lawrence T. Scott Francesco Paolucci Massimo Marcaccio 《Chemical science》2021,12(23):8048
The presence of non-hexagonal rings in the honeycomb carbon arrangement of graphene produces rippled graphene layers with valuable chemical and physical properties. In principle, a bottom-up approach to introducing distortion from planarity of a graphene sheet can be achieved by careful insertion of curved polyaromatic hydrocarbons during the growth of the lattice. Corannulene, the archetype of such non-planar polyaromatic hydrocarbons, can act as an ideal wrinkling motif in 2D carbon nanostructures. Herein we report an electrochemical bottom-up method to obtain egg-box shaped nanographene structures through a polycondensation of corannulene that produces a new conducting layered material. Characterization of this new polymeric material by electrochemistry, spectroscopy, electron microscopy (SEM and TEM), scanning probe microscopy, and laser desorption-ionization time of flight mass spectrometry provides strong evidence that the anodic polymerization of corannulene, combined with electrochemically induced oxidative cyclodehydrogenations (Scholl reactions), leads to polycorannulene with a wavy graphene-like structure.A bottom-up synthesis of wavy graphene structures obtained through an anodic polymerization process, combined with an electrochemically triggered oxidative cyclodehydrogenation, of the bowl-shaped polyaromatic hydrocarbon corannulene. 相似文献
75.
Giovannelli Tommaso Liuzzi Giampaolo Lucidi Stefano Rinaldi Francesco 《Computational Optimization and Applications》2022,82(2):293-327
Computational Optimization and Applications - In this paper, mixed-integer nonsmooth constrained optimization problems are considered, where objective/constraint functions are available only as the... 相似文献
76.
Castaing Charles Godet-Thobie C. Saïdi Soumia 《Set-Valued and Variational Analysis》2022,30(2):621-656
Set-Valued and Variational Analysis - The paper deals with second-order evolution problems driven by time and state dependent maximal monotone operators with non-Lipschitz perturbations. Systems... 相似文献
77.
Francesco Cubadda 《Russian Chemical Bulletin》1995,44(2):388-390
Information Congresses, Conferences, Symposia, Workshops, and Seminars in the Field of Chemical Sciences held with Participation of the Russian Academy of Sciences
The XXXV International IUPAC Symposium on macromolecular chemistry (MACROACRON-94) 相似文献78.
Summary We consider a (possibly) vector-valued function u: RN, Rn, minimizing the integral
, 2-2/(n*1)<p<2, whereD
i
u=u/x
i
or some more general functional retaining the same behaviour, we prove higher integrability for Du: D1 u,..., Dn–1 u Lp/(p-1) and Dnu L2; this result allows us to get existence of second weak derivatives: D(D1 u),...,D(Dn–1u)L2 and D(Dn u) L
p.This work has been supported by MURST and GNAFA-CNR. 相似文献
79.
80.