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1.IntroductionAbsolutedistancemeasurementisfarfromanewtopic.However,itisstillafieldstimulatinggreatinterestsnowadaysduetoitSimportantroleinmanufacturingandassembly['J.SincethegreatsuccessachievedbyMichelsonandBenoitwhentheyfirstdevelopedaninterferometertodeterminethestandardmeterintermsofthemonochromaticredcadmiumline,theopticinterferometerhasbeenprovedtobeoneofthemostpreciseandefficientwayindisplacementmeasurementbecauseofitshighdiscriminationandsimplestructure.However,thetraditionalinterfe…  相似文献   
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周耐根  周浪  杜丹旭 《物理学报》2006,55(1):372-377
用分子动力学方法对5%负失配条件下面心立方晶体铝薄膜的原子沉积外延生长进行了三维模拟.铝原子间的相互作用采用嵌入原子法(EAM)多体势计算.模拟结果再现了失配位错的形成现象.分析表明,失配位错在形成之初即呈现为Shockley扩展位错,即由两个伯格斯矢量为〈211〉/6的部分位错和其间的堆垛层错组成,两个部分位错的间距、即层错宽度为1.8 nm,与理论计算结果一致;外延晶体薄膜沉积生长中,位错对会发生滑移,但其间距保持稳定.进一步观察发现,该扩展位错产生于一种类似于“局部熔融-重结晶”的表层局部无序紊乱- 关键词: 失配位错 外延生长 薄膜 分子动力学 铝  相似文献   
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We succeeded in developing the acyl chloride‐facilitated condensation polymerization method for the synthesis of new poly(anhydride‐ester)s with aromatic side groups, which cannot be polymerized by the classic melt condensation polymerization method. Using chlorinated and acylated carboxylic acids as the intermediates, the polymerization was carried out at low temperatures of 120 or 135 °C to yield pure poly(anhydride‐ester)s of molecular weights as high as 1.55 × 105 with minimal side‐reactions. A homogeneous route of preparation was developed and optimized, using butyric anhydride as the acylating reagent and oxalyl chloride as the chlorinating reagent. A comparison of the mechanisms of the classic method and the new method indicates that the effects of transacylation—cyclization and oligomer formation—were greatly reduced due to the high reactivity of carboxylic acid chloride and the steric effect of bulky acyl groups. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5899–5915, 2007  相似文献   
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In this article we use classical formulas involving the K–Bessel function in two variables to express the Poisson kernel on a Riemannian manifold in terms of the heat kernel. We then use the small time asymptotics of the heat kernel on certain Riemannian manifolds to obtain a meromorphic continuation of the associated Poisson kernel to all values of complex time with identifiable singularities. This result reproves in a different setting by different means a well–known theorem due to Duistermaat and Guillemin [DG 75]. Also, we develop analytic expressions for the heat kernel beyond asymptotic expansions. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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Asymmetric alkylation of butyl glycinate-benzophenone Schiff base proceeded smoothly on clays and alumina at room temperature to afford alkylated products in high yields and good enantioselectivities.  相似文献   
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We present data showing hyperfine transitions in an atomic deuterium beam induced by the (476 MHz) radio-frequency field of a 704 MeV electron beam in a storage ring. A polarized deuterium beam, produced in an atomic beam source, was crossed with a stored electron beam and analyzed with a Breit--Rabi polarimeter. Electron-beam induced transitions were singled out by injecting different combinations of hyperfine states. Transition probabilities as high as 70% were measured at large currents (~ 100 mA). All possible deuterium transitions for a radio-frequency of 476 MHz were observed. In addition, a 1--6 transition resulting from the first harmonic (952 MHz) was observed. The effects of these transitions are of general importance for the polarized internal target technique applied in nuclear and particle physics experiments. The data are reasonably described by numerical estimates. The observed mechanism can be exploited to create nuclear polarized atoms when injecting electron polarized atoms with no net nuclear polarization into a storage cell. However, when nuclear polarized atoms are injected, care should be taken to avoid this mechanism, since it would result in depolarization of the atoms. The studies enabled us to choose the magnetic guide field during our spin-dependent electron--deuteron scattering experiments, such that electron-beam induced depolarizing effects were avoided. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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Bi2O3/SrTiO3 composite powders have been prepared and their photocatalytic activities were investigated by photooxidation of methanol. These powders were characterized by UV-Visible diffuse reflectance spectra, SEM and X-ray diffraction (XRD). The results revealed that all the Bi2O3/SrTiO3 composite powders exhibited higher photocatalytic activity than pure SrTiO3, Bi2O3 and TiO2 (P25) under visible light irradiation (λ>440 nm). The effects of the Bi2O3 contents on the photocatalytic activities of the composite powders were examined, the photocatalytic activities increased with the content of Bi2O3 increasing to a maximum of 83% and then decreased under visible light irradiation. The effects of the calcination temperatures on the photocatalytic activities of the composite powders were also investigated.  相似文献   
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本文主要论证了在不完全市场条件下带风险指数的金融均衡的存在性,并揭示其均衡结构的特征.本文中建立的模型是一、二期货币投入产出金融经济且具有可微的资产结构,这一模型包括了许多具有特殊资产结构的均衡模型,如实资产结构、虚资产结构、恒秩资产结构的均衡模型.因此本文的这一模型具有广泛的应用前景和实用价值.接着给出了本文的金融均衡的存在性定理,再借助微分拓扑给出它的证明过程,这一证明过程较之以前证明均衡存在性的经典方法(如Duffie,D&W.Shfer(1985)的方法)要简便得多.同时也应注意到本文的这一结论既适用于资产市场下会随机风险因素的情形,也适用于商品空间为无限维的情形,除此之外,还给出了怎样判别资产结构是否属于T类的判别法,为检验均衡存在性提供了更为便利的途径.最后,本文论证了在金融市场里,尽管由于稀缺性的存在,从而导致均衡分配的多样化,然而均衡分配集却形成了一光滑子流,但该流形的维数与稀缺性有关.换句话说,尽管市场是不完全的,但均市分配不确定性的反却是可比的.如此使得人们对均衡资产结构的认识更进一步.  相似文献   
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