Mg2Ru2Cl10O·16H2O

Mg₂Ru₂Cl₁₀O·16H₂O {dimagnesium μ‐oxo‐bis­[penta­chloro­ruthenate(IV)] hexa­deca­hydrate} crystallizes in the monoclinic system (space group P2₁/c). The structure consists of layers of [Ru₂Cl₁₀O]⁴⁻ anions, [Mg(H₂O)₆]²⁺ cations and water mol­ecules stacked along the a axis. Only the O atom bonded to Ru occupies the 2a site with symmetry. All the other atoms occupy general 4e sites. The crystal structure is stabilized by O—H⋯O and O—H⋯Cl inter­actions.     

Synthesis and spectroscopic characterization of piperidine/chloranil and piperidine/7,7′,8,8′-tetracyanoquinodimethane charge transfer complexes: X-ray crystal structure of a 7,7-dicyano-8,8-di-piperidinoquinodimethane adduct

Charge transfer reactions of piperidine with p-chloranil (CHL) and 7,7′,8,8′-tetracyanoquinodimethane (TCNQ) in chloroform have produced stable complexes with the general formula [(Pip)₂(acceptor)] with a 1:2 acceptor:donor molar ratio. Elemental analysis (CHN), electronic spectra, photometric titration, mid infrared spectra, ¹H NMR spectra and thermogravimetric analysis (TGA/DTG) were used to predict the position of the charge transfer interaction between the donating and accepting sites. The crystal structure of the Pip/TCNQ system was determined by single crystal X-ray diffraction.     

Proton-proton elastic scattering via the Trojan horse method

We address a successful indirect technique, the Trojan horse method, which allows one to measure the bare nucleus cross section for rearrangement reactions down to astrophysical energies. In particular, we consider here the application of the method to the p-p elastic scattering. This represents an important test of the main feature of the method, namely the suppression of Coulomb effects in the entrance channel due to off-energy-shell effects. In contrast to the on-energy-shell case, the extracted p-p cross section does not exhibit the Coulomb-nuclear interference minimum, as predicted by the half-off-energy shell calculations. This hypothesis is strengthened by the agreement between the Trojan horse p-p data and the calculated on-energy-shell n-n, n-p and nuclear p-p cross sections.     

On the magnitude of the Li + He → B + n reaction cross section at the Big-Bang temperature

The ⁸Li + ⁴He → ¹¹B + n reaction at Ecm<2 MeV$E_{\mathrm{cm}}<2\text{MeV}$ is a process of relevant astrophysical interest for which a remarkable experimental discrepancy between inclusive and exclusive cross-section measurements exists. In this Letter, a new inclusive neutron measurement at Ecm=1.05±0.16 MeV$E_{\mathrm{cm}}=1.05\pm 0.16\text{MeV}$ is given. The radioactive ⁸Li beam was delivered by the EXCYT facility. The cross section was determined by a low-background measurement of the time correlation between the ⁸Li projectile arrival to the target and the following neutron capture in a threshold-less 4π thermalization counter. This new data strengthens the reliability of the previous inclusive reaction cross-section data and altogether are consistent with a significant population of ¹¹B levels at high excitation energy.     

Phytochemical Compositions of Some Red Sea Halophyte Plants with Antioxidant and Anticancer Potentials

The aim of this study was to determine the compositions of carbohydrates, phenolic compounds, fatty acids (FAs), and amino acids (AAs) of four Rea Sea halophytes: Anabasis ehrenbergii, Suaeda aegyptiaca, Suaeda monoica, and Zygophyllum album. The results showed that S. aegyptiaca and S. monoica were rich in gallic acid with 41.72 and 47.48 mg/g, respectively, while A. ehrenbergii was rich in naringenin with 11.88 mg/g. The polysaccharides of the four species were mainly composed of galactose (54.74%) in A. ehrenbergii, mannose (44.15%) in S. aegyptiaca, glucose and ribose (33 and 26%, respectively) in S. monoica, and arabinose and glucose (36.67 and 31.52%, respectively) in Z. album. Glutamic acid and aspartic acid were the major AAs in all halophyte species with 50–63% and 10–22% of the total AAs, respectively. The proportion of unsaturated fatty acids (UFA) of the four species was 42.18–55.33%, comprised mainly of linolenic acid (15.54–28.63%) and oleic acid (5.68–22.05%), while palmitic acid (23.94–49.49%) was the most abundant saturated fatty acid (SFA). Phytol and 9,19-cyclolanost-24-en-3β–ol represented the major unsaponifiable matter (USM) constituents of S. monoica and A. ehrenbergii with proportions 42.44 and 44.11%, respectively. The phenolic fraction of S. aegyptiaca and S. monoica demonstrated noteworthy antioxidant activity with IC₅₀ values of 9.0 and 8.0 μg/mL, respectively, while the FAs fraction of Z. album exhibited potent cytotoxic activity against Huh-7, A-549, and Caco-2 cancer cell lines with IC₅₀ values of 7.4, 10.8, and 11.8 μg/mL, respectively. Our results indicate that these plants may be considered a source of naturally occurring compounds with antioxidant and anticancer effects that could be suitable for future applications.     

On the phase behavior of blends of polymers and nematic liquid crystals

The phase behavior of mixtures of polymers and nematic liquid crystals (LC) is investigated. Two types of systems are examined. The first one deals with blends in which the polymer is made of linear chains. In this case, a systematic study of the effects of various parameters on the phase diagrams is performed. In particular, it is shown how increasing the polymer size and/or the LC molecule size increases the miscibility gap of the mixture. It also reduces the region where a single nematic phase is observed in the presence of a tiny amount of polymer. Likewise, the relative effects of the isotropic and the nematic interaction parameters on the phase diagrams are examined. The second part of this investigation deals with blends involving crosslinked polymers. Here, substantial differences are observed as compared to the case where the polymer components are made of linear chains. These differences are illustrated by showing the phase diagrams in similar conditions for both blends. Unlike the case of a linear polymer matrix, it is observed that the single nematic phase and the nematic-isotropic spinodal branches are absent from the phase diagram of crosslinked polymers. This results into significant distortions of the phase diagram. In order to highlight all these effects, examples representing hypothetical blends are considered. These examples are chosen for illustration of the results in which the choice of numerical parameters is made consistently with the existing values in the literature which makes comparison with published data possible.     

Synthesis of 2-Amino-4-(2-hydroxynaphthyl)-4H-chromene-3-carbonitriles by Michael Addition and Their Transformation into New Pentacyclic Compounds

2-Amino-4-(2-hydroxynaphthyl)-4H-chromene-3-carbonitriles were synthesized by Michael addition of various 3-cyanoiminocoumarins and β-naphthol in good yield. The heterocyclization of these materials in an acidic medium leads new heterocyclic compounds, which have not previously been described, in moderate to good yields and good selectivity. The synthesized compounds were characterized by infrared, ¹H NMR, ¹³C NMR, two-dimensional NMR, and elemental analysis.     

Recent Results for the Effects of Distortion in the Inter-Cluster Motion in Light Nuclei and Application to Nuclear Astrophysics

Deuteron induced quasi-free scattering and reactions have been extensively investigated in the past few decades. This was done not only for the study of the nuclear structure and processes but also for the important astrophysical implication (Trojan Horse Method, THM). In particular the width of the neutron momentum distribution in deuteron will be studied as a function of the transferred momentum. THM applications will also be discussed because the momentum distribution of the spectator particle inside the Trojan horse nucleus is a necessary input for this method. The impact of the width variation on the extraction of the astrophysical S(E)-factor is discussed as well as the relevance of the s and d wave component in the deuteron wave function.     

New Advances in the Trojan Horse Method as an Indirect Approach to Nuclear Astrophysics

With the introduction of the Trojan Horse Method, nuclear cross sections between charged particles at astrophysical energies can now be measured. Here the basic features of the method are recalled together with recent results relevant for Nuclear Astrophysics. New applications in connection with plasma physics and industrial energy production are discussed.     

试用特洛伊木马方法研究天体核反应9Be(p,α)6Li

为克服低能带电粒子核反应截面直接测量中所遇到的库仑位垒和电子屏蔽效应带来的困难，试用基于准自由反应机制的特洛伊木马方法，在意大利南部国家核物理实验室的15MV串列加速器上，通过^2H（^9Be，α^6Li）n核反应对^9Be（p，α）^6Li在低能区（Ecm=0-1000kev）的裸核反应截面做了间接测量，并将测量结果与直接测量数据进行了比较。