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191.
探讨了有机金属催化剂的组成及其对二氧化碳同环氧丙烷交替共聚产物结构的影响,发现二乙基锌—助剂体系的催化活性按如次顺序递降:二乙基锌—连苯三酚>二乙基锌—间苯二酚>二乙基锌—对苯二胺>二乙基锌—亚乙基脲。若用三异丁基铝代替二乙基锌同连苯三酚构成催化剂,则失去对二氧化碳同环氧丙烷交替共聚反应的活性同时,著者发现二乙基锌—二元芳胺催化体系与二乙基锌—二元酚催化体系的催化活性规律完全不同。 相似文献
192.
The design and synthesis of a porphyrin-appended terpyridine, 5-(4-([2,2′:6′,2″]-terpyridin-4-yl-carboxyamidyl)phenyl)-10,15,20-triphenylporphyrin (H2TPPTPy) and its application as potential fluoroionophore for recognition of metal ions are reported. For preparation of the fluoroionophore, a novel simple strategy with improved total yield has been applied for the synthesis of 2,2′:6′,2″-terpyridine-4′-carboxylic acid as a ligand. H2TPPTPy shows chelation-enhanced fluorescence effect with cadmium ion via the interruption of photoinduced electron transfer (PET) process, which has been utilized as the basis of the fabrication of the Cd(II)-sensitive fluorescent chemosensor. The analytical performance characteristics of the proposed Cd(II)-sensitive chemosensor were investigated. It shows a linear response toward Cd(II) in the concentration range of 3.2 × 10−6 to 3.2 × 10−4 M with a limit of detection of 1.2 × 10−6 M. The chemosensor shows good selectivity for Cd(II) over a large number of cations, such as alkali, alkali earth and transitional metal ions except Cu(II) and Zn(II). The sensor has been used for determination of Cd(II) in water samples with satisfactory recoveries. 相似文献
193.
表面活性剂对纤维素接枝共聚物溶液粘度性质的影响 总被引:1,自引:0,他引:1
研究了阴离子十二烷基硫酸钠(SDS)、阳离子十六烷基三甲基溴化铵(CTAB)和非离子聚乙二醇辛基苯基醚(OP)等三种不同类型的表面活性剂对疏水化水溶性两性纤维素接枝共聚物(CGAO)溶液粘度性质的影响.结果表明,在SDS和OP的临界胶束浓度(cmc)附近,CGAO溶液粘度最大,SDS引起CGAO粘度的变化大于OP;即使在CTAB的cmc附近,随着CTAB浓度的增加,CGAO的粘度一直呈下降趋势;非疏水改性的纤维素接枝共聚物的溶液粘度随SDS或CTAB浓度的增加而下降,但几乎不随OP浓度的增大而变化.此外,通过凝胶渗透色谱法测得的保留时间证实了SDS、CTAB和OP与CGAO之间的疏水缔合作用. 相似文献
194.
Li N Luo H Liu S Chen G 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(3):501-507
The interaction of procaine hydrochloride and beta-cyclodextrin in aqueous solution was studied using resonance Rayleigh scattering technology. The molar ratio of the inclusion complex was 1:1 established by spectrophotometry. The resonance Rayleigh scattering technology was first applied in the determination of the beta-cyclodextrin inclusion constant. The inclusion constant of procaine hydrochloride beta-cyclodextrin complex Kf is 1.23 x 10(2) and 1.27 x 10(2) l mol(-1) for method I and 1.15 x 10(2) and 1.21 x 10(2) l mol(-1) for method II. These determination results were in correspondence with the results of the spectrophotometric and fluorescence methods. Therefore, the resonance Rayleigh scattering method can be used as a new technology for the determination of the inclusion constant. 相似文献
195.
Dielectric properties and frequency response of self-assembled monolayers of alkanethiols 总被引:1,自引:0,他引:1
Wang B Luo J Wang X Wang H Hou JG 《Langmuir : the ACS journal of surfaces and colloids》2004,20(12):5007-5012
This paper presents dielectric properties of alkanethiol self-assembled monolayers (SAMs) under an ac electric field. Using a Hg-SAM/SAM-Hg junction, we measured the ac impedance of alkanethiol SAMs using a sinusoidal perturbation of 30 mV (peak-to-peak) with frequency ranging from 1 Hz to 1 MHz at zero bias. Semicircles at higher frequencies and at middle frequencies along with Warburg lines at lower frequencies were observed in complex plane impedance plots, that is, Nyquist plots. The frequency response of SAMs was analyzed by modeling the junction using an equivalent circuit and fitting the Nyquist plots. The semicircles at higher frequencies are attributed to the effect of the SAM/SAM interfaces, and the ones at middle frequencies are attributed to the effect of alkanethiol SAMs. The comparison in the plots of the imaginary part of the impedance Z against frequency for the bare Hg electrodes (in pure ethanal) and the SAM-covered Hg electrodes (in alkanethiol solution) supports the analysis. The Warburg lines are attributed to a certain ionic impurity. The dielectric loss spectra are further analyzed. Chain-length-dependent peaks, which correspond to different relaxation mechanisms, at higher frequencies and middle frequencies were observed in the spectra of the dissipation factor (tan delta vs frequency). The peaks move to small frequency with the increase of chain length of alkanethiols. Using a correlation of peak position with the chain length, we then derived active energies of 39-99 meV for alkanethiol SAMs of C7-C18 under an ac electric field. 相似文献
196.
197.
Electrodeposition of nanocrystalline zinc from acidic sulfate solutions containing thiourea and benzalacetone as additives 总被引:1,自引:0,他引:1
Mou Cheng Li Li Li Jiang Wen Qi Zhang Yu Hai Qian Su Zhen Luo Jia Nian Shen 《Journal of Solid State Electrochemistry》2007,11(4):549-553
Nanocrystalline zinc coatings were produced by pulse electrodeposition in acid sulfate bath containing thiourea and benzalacetone
additives and characterized by X-ray diffraction and scanning electron microscopy techniques. The influence of benzalacetone
concentration and pulse peak current density on the grain size and crystallographic orientation of zinc deposits was investigated.
Zinc electrodeposited from additive-free solutions or with one of the two additives is not composed of nanosized crystals.
The mixture additives of thiourea and benzalacetone give rise to the formation of particle-like nanocrystalline zinc with
a (10ī1) random orientation. A change in peak current density from 2 to 1 A/cm2 only increases the grain size from 60 to 62 nm. 相似文献
198.
Polystyrene-supported recyclable palladacycle catalyst for Heck, Suzuki and Sonogashira reactions 总被引:1,自引:0,他引:1
Chih-An LinFen-Tair Luo 《Tetrahedron letters》2003,44(41):7565-7568
A new type of soluble polystyrene-supported palladium complex as an excellent and recyclable palladacycle catalyst was discovered for carboncarbon bond formation in Heck, Suzuki and Sonogashira reactions. Precipitation and filtration process for recycling the catalyst was also achieved. 相似文献
199.
新型糠醛加氢制糠醇催化剂研究 总被引:8,自引:0,他引:8
新型糠醛加氢制糠醇催化剂研究林培滋,黄世煜,周焕文,赵彤彤,刘崇早,罗洪原,梁东白(中国科学院大连化学物理研究所,大连116023)关键词铜催化剂,糠醛,加氢,糠醇糠醇是重要的化工原料,糖醇树脂是耐酸、碱腐蚀的材料,在工业发达的国家中,铸造工业广泛采... 相似文献
200.