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921.
922.
A E Abdel-Megied P Hansen E B Pedersen C M Nielsen 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(10):1060-1063
The 3'-iodonucleoside 4 and the 3'-O-methylsulfonylthymidine 9 have been synthesized by condensation of silylated uracils 2 with methyl 5-O-tert-butyldiphensilyl-2,3-dideoxy-3-iodo-D-threo-pentofuran oside (3) and methyl 5-O-tert-butyldiphenylsilyl-2-deoxy-3-methylsulfonyl-D-erythro- pentofuranoside (8), respectively. The nucleoside 4 and 9 produced the corresponding 2',3'-didehydro-2',3'-dideoxynucleosides 5 in an elimination reaction on treatment with sodium methoxide. The compounds 5b showed no antiviral activity against HIV-1. 相似文献
923.
A simple High performance liquid chromatographic (HPLC) method for the specific determination of the molecular weight and concentration of hyaluronic acid (HA) in complex mixtures has been developed. Hyaluronate-binding proteins isolated from bovine cartilage labelled by 125I or fluoresceinisothiocyanate were used as specific markers. The specific binding affinities of the markers were compared and were found to have association constants of 1.6 x 10(7) M-1 and 1.2 x 10(7) M-1 respectively. The HA levels and molecular weight distributions can be easily determined in the range 10-500 ng/mL in complex mixtures by the use of markers, molecular sieving HPLC columns and appropriate detectors. It has been demonstrated clearly that the method is useful for the highly specific determination of the parameters in complex biological samples such as serum and synovial fluids and is recommended for clinical applications. 相似文献
924.
We consider applications of elliptic differential operators and their associated spectral functions in quantum field theory problems. The role of zeta functions and traces of heat kernels in the regularization of Casimir energies is emphasized, and the renormalization procedure is discussed with simple examples. 相似文献
925.
Gunter M. Schütz 《Zeitschrift für Physik B Condensed Matter》1997,104(3):583-590
We study diffusion-limited (on-site) pair annihilation A + A → 0 and (on-site) fusion A + A → A which we show to be equivalent for arbitrary space-dependent diffusion and reaction rates. For one-dimensional lattices with nearest neighbour hopping we find that in the limit of infinite reaction rate the time-dependent n-point density correlations for many-particle initial states are determined by the correlation functions of a dual diffusion-limited annihilation process with at most 2n particles initially. Furthermore, by reformulating general properties of annihilating random walks in one dimension in terms of fermionic anticommutation relations we derive an exact representation for these correlation functions in terms of conditional probabilities for a single particle performing a random walk with dual hopping rates. This allows for the exact and explicit calculation of a wide range of universal and non-universal types of behaviour for the decay of the density and density correlations. 相似文献
926.
We engage a study of nonmodal linear logic which takes times ⊗ and the linear conditional ⊸ to be the basic connectives instead
of times and linear negation ()⊥ as in Girard's approach. This difference enables us to obtain a very large subsystem of linear logic (called positive linear
logic) without an involutionary negation (if the law of double negation is removed from linear logic in Girard's formulation,
the resulting subsystem is extremely limited). Our approach enables us to obtain several natural models for various subsystems
of linear logic, including a generic model for the so-called minimal linear logic. In particular, it is seen that these models
arise spontaneously in the transition from set theory to multiset theory. We also construct a model of full (nonmodal) linear
logic that is generic relative to any model of positive linear logic. However, the problem of constructing a generic model
for positive linear logic remains open. Bibliography: 2 titles.
Published inZapiski Nauchnykh Seminarov POMI, Vol. 220, 1995, pp. 23–35. Original 相似文献
927.
928.
Summary. In this paper we are interested in two phase flow problems in porous media. We use a Dual Mesh Method to discretize this
problem with finite volume schemes. In a simplified case (elliptic - hyperbolic system) we prove the convergence of approximate
solutions to the exact solutions. We use the Dual Mesh Method in physically complex problems (heterogeneous cases with non
constant total mobility). We validate numerically the Dual Mesh Method on practical examples by computing error estimates
for different test-cases.
Received March 21, 1997 / Revised version received October 13, 1997 相似文献
929.
IR and Raman spectra of (NH4)3ZnCl5 have been recorded. The observed spectra have been analysed on the basis of the vibrations of ZnCl
4
2−
and NH
4
+
ions. The appearance of multiple Raman bands indicates the presence of two different types of ammonium ions. The effect of
anisotropic crystalline field over the ZnCl4 and NH4 tetrahedra is also discussed. The assignment of internal modes has been verified by the potential energy distribution calculations. 相似文献
930.
L. S. de C. Oliveira M. T. X. Silva A. Vasquez J. A. H. da Jornada 《Hyperfine Interactions》1991,66(1-4):267-270
An exploratory Mössbauer spectroscopy study of the Fe-C system in the C rich region, prepared by high pressure-high temperature treatment near the graphite-diamond stability line, was made. The results obtained for the different processing conditions give no evidence of Fe intercalation in graphite. The presence of some water in the cell produced hydrated Fe complexes, which can explain the deleterious effect of water or hydrogen in the high pressure diamond synthesis. 相似文献