基于光纤叠栅的全光纤声光可调谐滤波器的特性分析

本文提出了一种基于光纤叠栅的全光纤声光可调谐滤波器, 与普通光纤布拉格光栅型全光纤声光可调谐滤波器相比, 该滤波器能够对光纤叠栅的两个中心波长进行同步调制. 理论分析了声波频率和声致应变幅度对基于光纤叠栅的全光纤声光可调谐滤波器的传输光谱的影响, 结果表明, 各阶次反射峰分别以两个主反射峰为中心呈对称关系, 且主反射峰与其所调制出的次反射峰之间的波长间隔与声波频率成正比, 而两个主反射峰所调制出的同阶次反射峰之间的波长间隔与声波频率无关; 声致应变幅度主要影响主反射峰及次反射峰的反射率的变化. 实验中, 分别测试声波频率为390 kHz和710 kHz的基于光纤叠栅的全光纤声光可调谐滤波器的传输光谱, 实验结果的变化趋势与仿真分析结果相一致.     

Raman investigation on carbonization process of metal–organic frameworks

Under inert gas flow and high temperature, carbonization of aluminum‐based metal–organic frameworks (MOFs) was carried out. The formation rate of carbonized MOFs (CMOFs) was monitored by the variation of the Raman D band to G band intensity ratio with heat treatment duration. Powder x‐ray diffraction (PXRD) and scanning electron microscope (SEM) techniques were used to confirm the formation of CMOFs. The activation energy was extracted from the temperature‐dependent rate constants using the Arrhenius equation and correlated with the structural properties of precursor MOFs such as pore size and the number of carbon atoms per ligand. A reaction mechanism is proposed and discussed for the formation of CMOFs based on Raman observation. Copyright © 2016 John Wiley & Sons, Ltd.     

Space-frequency analysis in higher dimensions and applications

Annali di Matematica Pura ed Applicata (1923 -) - In the Clifford algebra setting of Euclidean spaces, monogenic signals are naturally defined as the boundary limit functions of the associated...     

可数对一映射及相关问题

本文研究了■0-sn-度量空间与度量空间之间的关系.利用特殊映射,获得了在序列空间中下述命题等价:(1)空间X是■0-sn-度量空间;(2)存在从度量空间M到X可数对一、序列商、σ映射f;(3)存在从度量空间M到X可数对一、序列商、σ映射f使得对每一个x∈X,■f-1(x)是σ-紧.推广了参考文献[3,4]中的一些结果.     

Neural-Network Quantum States for Spin-1 Systems: Spin-Basis and Parameterization Effects on Compactness of Representations

Neural network quantum states (NQS) have been widely applied to spin-1/2 systems, where they have proven to be highly effective. The application to systems with larger on-site dimension, such as spin-1 or bosonic systems, has been explored less and predominantly using spin-1/2 Restricted Boltzmann Machines (RBMs) with a one-hot/unary encoding. Here, we propose a more direct generalization of RBMs for spin-1 that retains the key properties of the standard spin-1/2 RBM, specifically trivial product states representations, labeling freedom for the visible variables and gauge equivalence to the tensor network formulation. To test this new approach, we present variational Monte Carlo (VMC) calculations for the spin-1 anti-ferromagnetic Heisenberg (AFH) model and benchmark it against the one-hot/unary encoded RBM demonstrating that it achieves the same accuracy with substantially fewer variational parameters. Furthermore, we investigate how the hidden unit complexity of NQS depend on the local single-spin basis used. Exploiting the tensor network version of our RBM we construct an analytic NQS representation of the Affleck-Kennedy-Lieb-Tasaki (AKLT) state in the xyz spin-1 basis using only M=2N hidden units, compared to M∼O(N2) required in the Sz basis. Additional VMC calculations provide strong evidence that the AKLT state in fact possesses an exact compact NQS representation in the xyz basis with only M=N hidden units. These insights help to further unravel how to most effectively adapt the NQS framework for more complex quantum systems.     

Small-amplitude limit cycles of polynomial Liénard systems

In this paper,we study the number of limit cycles appeared in Hopf bifurcations of a Linard system with multiple parameters.As an application to some polynomial Li’enard systems of the form x=y,y=gm(x)-fn(x)y,we obtain a new lower bound of maximal number of limit cycles which appear in Hopf bifurcation for arbitrary degrees m and n.     

Large‐scale synthesis of submicron gallium oxide hydrate rods and their optical and electrochemical properties

Large‐scale submicron gallium oxide hydrate (GaOOH) rods have been synthesized by a simple hydrothermal process and their optical, electrochemical properties have been analyzed. The diameter of the GaOOH nanorods with good single crystalline structure is 80‐800 nm and length of less than 4 μm. The tips of the GaOOH structures are composed of nanorods with the diameter of less than 10 nm and length of more than 100 nm. Hydrothermal temperature, time and the Ga‐contained starting materials have important roles on the formation and growth of submicron GaOOH rods. The submicron GaOOH rods exhibit good UV‐vis absorption ability. The electrochemical analysis shows that the submicron GaOOH rods have good detecting ability for ascorbic acid and cysteine in PBS and NaCl solution exhibiting promising potential for electrochemical sensing application. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

光动力疗法用糖基光敏剂的研究进展

作为光动力疗法中至关重要的决定性因素,光敏剂的研究受到越来越多的重视.而糖基的引入,可以大大提高光敏剂母体的膜透过性和特异吸收性.从糖基光敏剂的母体结构、糖基光敏剂分子的构效关系、糖基的作用机理以及糖基光敏剂的药物动力学和代谢产物这四个方面对近年来糖基光敏剂的研究现状进行了综述,对其发展趋势进行了展望.     

反相高效液相色谱负峰测定法研究以及酮类的测定

研究了反相液相色谱中负峰现象及产生的原理,应用计量置换作用原理解释了样品在色谱柱中的计量置换保留行为;应用负峰法测试了甲基脂肪酮各组分的含量.本研究采用Agilent C18色谱柱(150 mm×4.6 mm, 5 μm), 流动相为V(甲醇)∶ V(水, 含0.01 mmol/L磺基水杨酸)=60∶ 40, 紫外检测器(λsig=310 nm, λref=275 nm). 本方法简便,线性相关系数r均大于0.9993; 甲基酮的定量下限为0.041 μg; 相对标准偏差为0.52%～0.80%.     

Electrochemical Determination of Cu(II) Ions in Chloride‐Rich Environment Using Polyviologen‐Modified Glassy Carbon Electrodes

Polyviologen was formed on glassy carbon electrodes using potentiostatic electropolymerization in pH 4.2 Britton‐Robinson buffer solution. The polyviologen‐modified glassy carbon electrode (PVGCE) was employed to determine Cu(II) in chloride‐rich solutions in order to demonstrate the electroanalytical application of polyviologen. The PVGCE was found capable of enhancing the detection limit of Cu(II) in chloride‐rich environment because of the anion‐exchange feature of the polymer film. Cathodic stripping square‐wave voltammetry (CSSWV) was employed to determine Cu(II). The dependence of the cathodic stripping current on the concentration of Cu(II) was linear from 0.06 ppm to 9.53 ppm with a regression coefficient of 0.999. The detection limit is 0.02 ppm (σ = 3). Regeneration of the PVGCE can be achieved by simply immersing the electrode in a stirred 0.5 M NaCl solution.