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291.
The spin-dependent electron transport is numerically studied in a nonmagnetic nanostructure in the presence of both Dresselhaus and Rashba spin-orbit interactions. It is shown that the large spin polarization can be achieved in such a structure mainly due to the Rashba spin-orbit term induced splitting of the resonant level. It is also shown that the spin polarization strongly depends on the well width and the thickness of the middle barrier as well as the height of the middle barrier. 相似文献
292.
利用发射光谱技术在大气压下测量了空气中多针对板负直流电晕放电和正电晕流光放电产生的O(3p5 P→3s 5 S02777.4nm)活性原子发射光谱。在负电晕放电中,研究了放电功率、电极间距、N2含量和相对湿度等因素对O活性原子产生过程的影响;在正电晕流光放电阶段,研究了O活性原子相对密度在放电反应空间的分布特点。结果表明:O活性原子产量随放电功率的增加而增大,随电极间距增大而减少,随相对湿度和氮气含量的增加,其产量先增大后减少;O活性原子相对密度沿针尖轴向呈先增大后减小的趋势。 相似文献
293.
This paper is concerned with development of improvement schemes for road networks under future travel demand uncertainty. Three optimization models, sensitivity-based, scenario-based and min–max, are proposed for determining robust optimal improvement schemes that make system performance insensitive to realizations of uncertain demands or allow the system to perform better against the worst-case demand scenario. Numerical examples and simulation tests are presented to demonstrate and validate the proposed models. 相似文献
294.
In this paper, we completely characterize the graphs with third largest distance eigenvalue at most \(-1\) and smallest distance eigenvalue at least \(-3\). In particular, we determine all graphs whose distance matrices have exactly two eigenvalues (counting multiplicity) different from \(-1\) and \(-3\). It turns out that such graphs consist of three infinite classes, and all of them are determined by their distance spectra. We also show that the friendship graph is determined by its distance spectrum. 相似文献
295.
Xue‐qin Zhao Sheng Guo Hui Yan You‐yuan Lu Fang Zhang Da‐wei Qian Han‐qing Wang Jin‐ao Duan 《Biomedical chromatography : BMC》2019,33(8)
The leaves of Lycium barbarum (LLB) have been utilized as crude drugs and functional tea for human health in China and Southeast Asia for thousands of years. To control its quality, a rapid and sensitive ultra‐high‐performance liquid chromatography coupled with triple quadrupole tandem mass spectrometry method was established and validated for the first time for simultaneous determination of 10 phenolic acids and flavonoids (including neochlorogenic acid , protocatechuic aldehyde, p‐hydroxybenzoic acid, chlorogenic acid, cryptochlorogenic acid, caffeic acid, p‐coumaric acid, ferulic acid, rutin and kaempferol‐3‐O‐rutinoside) in LLB. The separation was performed on an Acquity UPLC C18 chromatographic column (100 × 2.1 mm internal diameter, 1.7 μm particle size) with 0.1% formic acid in water (A)–acetonitrile (B) as the mobile phase under gradient elution. Multiple reaction monitoring mode was adopted to simultaneously monitor the target components. The developed method was fully validated in terms of linearity (r2 ≥ 0.9860), precision (RSD ≤ 6.58%), repeatability (RSD ≤ 6.60%), stability (RSD ≤ 6.17%), recovery (95.56–108.06%, RSD ≤ 4.64%) and limit of detection (0.021–0.664 ng/mL) and limit of quantitation (0.069–2.210 ng/mL), and then successfully applied to evaluate the quality of 64 batches of LLB collected from 41 producing areas in four different provinces of China. The results showed that the LLB, especially collected from Inner Mongolia regions, were rich in the phenolic acids and flavonoids. Rutin, kaempferol‐3‐O‐rutinoside and chlorogenic acid are the predominant compounds contained in LLB. The above findings will provide helpful information for the effective utilization of LLB. 相似文献
296.
本文研究了在二碘化衫作用下S-S键的断裂,并与二硫化碳及卤代烃的反应,合成了三硫代碳酸酯. 相似文献
297.
The intracellular delivery of metal-organic frameworks(MOFs)encapsulated with functional biomolecules represents a promising av-enue in the field of biomedicine... 相似文献
298.
1.INTRODUCTIONDyewastewaterisakindofseriouspollutionsource.InthetraditionaltreatmentmethodsfordyewastewatergenerallytherearefourapproachesincludingelectricchargeneutraliZationofgelparticles,complexation(chelatation),redoxreaction,andbiochemicalcoagulationII~31.Recently,dyewastewaterhasbecomemoreconcentrated,moredifficulttodegradedbiochemically,andmorepoisonous,whichbringsaboutagreatchallengeforwatertreatment.AlthoughtheCOD(chemicaloxygendemand)mayfitthequalitystandardofwastewaterdischar… 相似文献
299.
Yitao Song Yewang Peng Shuang Yao Peng Zhang Yujie Wang Jianmin Gu Tongbu Lu Zhiming Zhang 《中国化学快报》2022,33(2):1047-1050
A simple and effective method for constructing highly efficient oxygen reduction catalysts with trace amount of isolated cobalt was firstly developed by the pyrolysis of Co-centered polyoxometalate@metalorganic framework (Co-POM@MOF).The Co-centered polyoxometalate ([Co W12O40]6-) was confined in the well-defined void space of ZIF-8 to achieve homogeneous dispersion of polyoxoanions,where the isolated Co centers were well surrounded by the W-O shell and ZIF-8 fra... 相似文献
300.
Xiaowan Zhang Yixin Yang Peige Qin Lizhen Han Wenli Zhu Shaofeng Duan Minghua Lu Zongwei Cai 《中国化学快报》2022,33(2):903-906
In this work,the nano-g-C3N4/Ui O-66-NH2composite was prepared by one-step solvothermal method.The as-prepared composite was characterized by scanning electron microscopy,Brunner-Emmet-Teller measurement,energy dispersive spectrometer,X-ray diffraction,and Fourier transform infrared spectroscopy.By using nano-g-C3N4/Ui O-66-NH2composite as sorbent,a dispersive solid-phase extraction coupled with high-performance liquid chromatogra... 相似文献