Thermal and rheological properties of a family of botryosphaerans produced by Botryosphaeria rhodina MAMB-05

Differential scanning calorimetry (DSC), thermogravimetry (TG) and Fourier-transform infra-red spectroscopy (FT-IR) analyses were performed to investigate changes in the physico-chemical properties of botryosphaerans, a family of exopolysaccharides (EPS) produced by the fungus Botryosphaeria rhodina MAMB-05 grown on glucose (EPS(GLC)), sucrose (EPS(SUC)) and fructose (EPS(FRU)). A slight endothermic transition and small mass loss attributable to the removal of water of hydration were observed in the DSC and TG analyses, respectively, for the three EPS samples. The FT-IR spectra confirmed no structural changes occurred during thermal treatment. Viscometry was utilized to obtain information on the rheological behaviour of the EPS in aqueous solutions. The Power Law and Cross Equations determined the natural pseudoplastic characteristics of the EPS. Comparatively, results obtained for EPS produced when B. rhodina MAMB-05 was grown on each of the three carbohydrate sources demonstrated similar apparent viscosity values for EPS(GLC) and EPS(SUC), while EPS(FRU) displayed the lowest apparent viscosity of the three botryosphaerans, suggesting a higher degree of ramification and lower Mw. EPS(GLC) and EPS(SUC) possessed similar degrees of ramification. The slight differences found in their viscosities can be explained by the differences in the type of branching among the three botryosphaerans, thus varying the strength of intermolecular interactions and consequently, consistency and viscosity. The physico-chemical studies of botryosphaerans represent the originality of this work, and the knowledge of these properties is an important criterion for potential applications.     

Designing robust liner shipping schedules: Optimizing recovery actions and buffer times

It is important for liner shipping companies to maintain cost efficient and robust liner shipping networks. Regularly, they set up pro-forma schedules, yet it is difficult to stay on time. We consider the problem of managing the delays. Therefore, we need to determine an optimal recovery policy and buffer time allocation to the ship route in order to minimize the total costs associated with delays and recovery actions, such as increasing sailing speed. We introduce a general framework consisting of a mixed integer programming formulation to solve discrete stochastic decision problems with short and long term decisions and apply this framework to the above described problem. Furthermore, we propose and test four heuristics for this problem. We compared the results of our method with an existing liner shipping route schedule and found a cost decrease of 28.9% after optimizing the buffer time distribution compared to the cost of sailing the current route schedule at constant speed.     

Tunneling in suspended carbon nanotubes assisted by longitudinal phonons

Current-voltage characteristics of suspended single-wall carbon nanotube quantum dots show a series of steps equally spaced in voltage. The energy scale of this harmonic, low-energy excitation spectrum is consistent with that of the longitudinal low-k phonon mode (stretching mode) in the nanotube. Agreement is found with a Franck-Condon-based model in which the phonon-assisted tunneling process is modeled as a coupling of electronic levels to underdamped quantum harmonic oscillators. A comparison with this model indicates a rather strong electron-phonon coupling factor of order unity.