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31.
P. R. Latthe P. S. Shinge Bharati V. Badami P. B. Patil S. N. Holihosur 《Journal of Chemical Sciences》2006,118(3):249-256
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been
found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e). 相似文献
32.
A homologous series of azomesogens, 2″-[4-(4′-n-alkoxybenzoyloxy)-2-chlorophenylazo] naphthalenes, with lateral chloro groups was synthesised. All the homologues synthesized
exhibit enantiotropic nematic mesophase. The mesomorphic properties of the present series are compared with other structurally
related series to evaluate the effect of lateral chloro group and its position on mesomorphism
This paper was presented at the 10th National Conference on Liquid Crystals held at Bangalore, India during 9–11 October 2003. 相似文献
33.
We show that, in dimensions equal or greater than three, classical strings do not join or split. This is part of a no-interaction theorem that is also proved. The quantum theory is considered. 相似文献
34.
Summary The available laboratory data of turbulent boundary layer flow over two-dimensional obstacles have been examined in order
to identify the parameters (such as the aspect ratio or the surface roughness) driving the onset of separation. A comparison
with some linearized models suitable for atmospheric applications is also made. It results that i) the model response can
be highly sensitive to the detailed shape of the obstacle; ii) the ratio between obstacle length and boundary layer thickness
is relevant in determining the pressure perturbation near the surface; iii) the surface shear stress is poorly described in
most cases and in particular in the obstacle wake.
Riassunto I dati di laboratorio disponibili, relativi a strati limite turbolenti su ostacoli bidimensionali, sono stati esaminati al fine di identificare i parametri guida della separazione (quali la pendenza o la rugosità della superficie). Inoltre è stato fatto un confronto con i risultati di alcuni modelli linearizzati adatti per applicazioni atmosferiche. Ne risulta che i) la risposta del modello è molto sensibile alla forma dettagliata dell’ostacolo; ii) il rapporto fra la lunghezza dell’ostacolo e lo spessore dello strato limite turbolento incidente è importante nel determinare la perturbazione della pressione vicino alla superficie; iii) lo ?shear stress? superficiale non è riprodotto con accuratezza nella maggioranza dei casi, in particolare nella scia dell’ostacolo.
Резюме Анализируются имеющиеся лабораторные данные по турбулентному течению в пограничном слое над двумерными препятствиями, чтобы идентифицировать параметры (такие как аспектное отношение или шероховатость поверхности), определяющие возникновение отрыва. Проводится сравнение с некоторыми линеаризованными моделями, удобными для атмосферных приложений. Получены следующие результаты: 1) модельный отклик может быть очень чувствительным к детальной форме препятствия; 2) отношение между длиной препятствия и толщиной поверхностного слоя является существенным при определении возмущения давления вблизи поверхности; 3) напряжение поверхностного сдвига плохо описывается в большинстве случаев и, в частности, в спутной струе.相似文献
35.
Summary Using a saturated non-boiling hydrocarbon mixture, the influence of two parameters on the results of field ionization mass spectrometry (FI-MS) measurements was studied: (a) the potential difference between the FI emitter and the counterelectrode; (b) the emitter temperature.Variation of the potential difference had only a minor effect on the average molecular mass measured and had no evident effect on the relative ring number distribution in the sample. In contrast, when the emitter temperature was increased, higher average molecular masses were recorded. Moreover, the average molecular masses shifted to higher ring numbers. In order to control the relationship between the described influences during mixture analysis, measuring instructions have been developed that enable the quantitative analysis of unknown saturated samples. However, average molecular mass of the mixture must be known.
Entwicklung einer quantitativen FI-MS-Methode zur Charakterisierung von gesättigten hoch- und nichtsiedenden Kohlenwasserstoffgemischen相似文献
36.
Zuo LIU Zhen De WU 《数学学报(英文版)》2005,21(5):997-1000
Let κ be non-negative integer. The unoriented bordism classes, which can be represented as [RP(ξ^κ)] where ξ^κ is a k-plane bundle, form an ideal of the unoriented bordism ring MO.. A group of generators of this ideal expressed by a base of MO. and a necessary and sufficient condition for a bordism class to belong to this ideal are given. 相似文献
37.
Inspired by the recent work [HHM03], we prove two stability results for compact Riemannian manifolds with nonzero parallel spinors. Our first result says that Ricci flat metrics which also admit nonzero parallel spinors are stable (in the direction of changes in conformal structures) as the critical points of the total scalar curvature functional. Our second result, which is a local version of the first one, shows that any metric of positive scalar curvature cannot lie too close to a metric with nonzero parallel spinor. We also prove a rigidity result for special holonomy metrics. In the case of SU(m) holonomy, the rigidity result implies that scalar flat deformations of Calabi-Yau metric must be Calabi-Yau. Finally we explore the connection with a positive mass theorem of [D03], which presents another approach to proving these stability and rigidity results. Dedicated to Jeff Cheeger for his sixtieth birthday 相似文献
38.
K. C. Kumara Swamy E. Balaraman M. Phani Pavan N. N. Bhuvan Kumar K. Praveen Kumar N. Satish Kumar 《Journal of Chemical Sciences》2006,118(6):495-501
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated
acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature
of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction. 相似文献
39.
Kristian Hougaard Frederik D. Nielsen 《Journal of Optical and Fiber Communications Reports》2004,1(1):63-83
In this paper we will present an overview of the use
of photonic crystal fibers as fiber amplifiers. We
will describe the basic concepts of optical
amplification, and how to do numerical modelling of
such components. We will then identify advantages
and disadvantages of amplifiers based on PCF
technology compared to conventional fibers, and then
go into greater detail on some of these specific
applications, such as low pump power amplifiers, and
high-power double-clad amplifiers and lasers. 相似文献
40.
In the ever fusion experiments in SWIP, pellet forming process was carried out through adjusting relative devices by staff member in site, which will make every pellet-forming process slight distinction and will result in pellet difference in shape, size and intensity. In the intervals of HL-2A discharges, staff member have to go site to accomplish the pellet-forming process, this wastes human power and increase the potential danger. So it is necessary to develop a remote control system to perform the pellet-forming process. The control system needs have the features of real-time, reliability and be easy to operate and maintain. 相似文献