熔石英相位共轭镜无损工作状态分析

基于非线性光学耦合波方程组建立了聚焦泵浦条件下熔石英玻璃材料中SBS过程的物理模型并编制了相应的数值求解程序,研究了SBS介质内激光场的时空发展特征,从而试图揭示SBS介质的内在破坏机制并寻求相应的加固措施.通过数值模拟程序研究了焦点处激光功率密度以及SBS反射率与激光能量的依赖关系,发现SBS对介质内的激光场具有"限幅"作用,即在注入能量大幅度提升的情况下,内部的激光场强度只有较小的增加,这种机制使大能量的固体介质PCM成为可能.分析激光脉宽以及耦合透镜焦距等参数对SBS过程的影响发现,精细选择系统参数,在熔石英玻璃材料中有可能无损伤地实现高效的SBS过程.     

Inside or outside a ligand cleft? Synthetic, structural, and kinetic inertness studies of zinc, cadmium, and mercury complexes of cross-bridged cyclam and cyclen

Ethylene cross-bridging of the popular tetraazamacrocyclic ligand cyclam has led to metal complexes with enhanced kinetic inertness. The synthesis and spectral characterization of zinc(II), cadmium(II), and mercury(II) complexes of cross-bridged cyclam (L1) as well as cross-bridged cyclen (L2) are reported along with the details of our synthetic route to L2. X-ray structural studies revealed that all Zn(II) and Cd(II) cations are fully kappa(4)N-coordinated inside the respective ligand's molecular cleft with L1 providing the better fit for Zn(II). While Hg(II) is similarly coordinated to L2, it has been found to complex L1 outside the ligand cleft in a novel exo-kappa(2)N-mode. Solution NMR data of the kappa(4)N complexes are consistent with the presence of only a single cis-folded isomer in each case. Ligand (1)H and (13)C coupling to both (111,113)Cd and (199)Hg in their complexes can be clearly discerned. The relative kinetic inertness of representative cross-bridged complexes in acidic aqueous solution has been assessed and found to be in the following order: Zn(II) > Cd(II)[dbl greater-than] Hg(II). The data also reaffirm that cross-bridged cyclam ligand L1 forms a substantially more inert complex with zinc(II) than either the smaller cyclen analogue L2 or the unbridged 1,4,8,11-tetramethyl-cyclam L3.     

Investigation of all-solid photonic bandgap fiber with low losses in low-order bandgaps

We report synoptically an investigation of design, fabrication and characterization of a new all-solid photonic bandgap fiber. By introducing an index depressed layer around a high index core in every unit cell of photonic crystal cladding, a novel all-solid bandgap fiber is predicted to obtain low confinement and bend losses within low-order bandgaps. After optimizing the structure parameters, we fabricate a batch of rods used for cladding cells, select a pure-silica rod for core cell and an inner-hexagonal jacket tube. We demonstrate an all-solid bandgap fiber with the transmission loss as low as 2 dB/km at 1,310 nm and a bandwidth of over 700 nm within the first bandgap. The guiding properties are also measured, respectively, such as transmission spectrum, attenuation spectrum, bend loss, mode field intensity profile, and chromatic dispersion.     

三维各向异性耦合谐振子哈密顿量的对角化

根据物理量的可测实在性,应用二次型理论,一般地解决了3个质量与3个频率均不相同、坐标和动量各自具有全耦合谐振子系统的哈密顿量的可对角化问题,并具体给出了哈密顿量对角化的标准形.     

定时截尾场合双参数威布尔分布的贝叶斯推断

给出了定时截尾下,双参数威布尔分布中参数及可靠性指标的Bayes估计,并且给出了未来观测值的贝叶斯预测问题.     

多星测控调度问题任务优先级研究

在对多星测控调度问题工程需求进行分析的基础上,提出了多星测控问题中影响测控任务优先级的10个影响因素,并对各项因素对测控任务优先级的影响方式与影响程度进行了分析.利用功效系数法给出了设定优先级的算法,最后给出了一个算例.     

碘原子共振多光子电离光谱研究

用可调谐的染料激光(4600～5000(?)),共振(3+2)和(4+1)多光子电离探测了I(5p~2P_(3/2)~0)和1~#(5p~2P_(1/2)~0).碘原子是由碘分子(I_2)经激光解离而产生的.在上述激光波段中共观察到12个原子跃迁,其中,(4+1)多光子电离跃迁是首次观察到的.     

Palladium-catalyzed regiocontrolled internal heteroarylation of electron-rich olefins with heteroaryl halides

A highly efficient palladium-catalyzed Heck coupling reaction of heteroaryl halides with electron-rich vinyl ether and hydroxyalkyl vinyl ethers is described. It was found that the choice of solvent, ligand, and reaction temperature had a fundamental influence on the regioselectivity and reactivity of the reaction, and the combination of Pd(OAc)₂ and DPPF in ethylene glycol led to the most effective catalytic system. Under these conditions, a variety of heteroaryl halides reacted very quickly with electron-rich olefins to afford exclusively the branched products in good to excellent yields without employing triflates, halide scavengers, or ionic liquids.     

低阈值飞秒钛宝石激光器的理论研究

利用数值求解的方法，从理论上系统分析了决定钛宝石激光器锁模阈值的几个关键因素. 定 量分析了腔模对克尔效应的主导作用，并将光孤子模型引入低阈值锁模理论，分析了色散与 阈值的关系. 根据理论指导在实验上完成了一台阈值低至390 mW自启动飞秒掺钛蓝宝石激光 器. 关键词： 低阈值 掺钛蓝宝石激光器 克尔透镜锁模 光孤子