Tensor force effect on proton shell structure in neutron-rich Ca isotopes

In the framework of the Skyrme-Hartree-Fock approach with 36 sets of the TI J parameterizations,the tensor force effect on the evolution of the single-proton states in the calcium isotopes is systematically investigated.It is shown that the single-proton states with higher angular momenta are influenced significantly by the tensor force and the trend in the evolution of somesingle-particle energy differences with the mass number of the isotopes depends sensitively on a parameter βT associated with the intensity of the tensor force.To understand this phenomenon,we analyze the spin-orbit potentials and the radial wave functions of relevant single-proton orbits in detail.In addition,it is found that some TI J interactions could cause the 2s1/21d3/2 energy level inversion in 48Ca.     

Application of wavelet transform in-ray spectra analysis

The frequency distribution of different ingredients in-ray spectra,e.g.,photo-peak,fluctuations of counts and Compton region,is separately analyzed.After wavelet transform of-ray spectra,the wavelet coefficients of a photo-peak increase with transforming scales and these coefficients show direct proportion with intensity of peak at determinate scale.A novel algorithm based on wavelet transform is proposed and studied.The results indicate that most of the photo-peaks in multi-spectra can be determined accurately,the-rays energy and intensity of the peak can also be determined.This method has the prospect of being applied in on-line multi-spectra analysis in such fields as radioprotection and nuclear safety monitoring.     

ISOVALEROYL OXOKADSURANE,A NOVEL DIBENZOCYCLOOCTADIENE LIGNAN POSSESSING A SPIROBENZOPURANOID SKELETON

Isovaleroyl oxokadsurane, a novel dibenzocyclooctadiene lignan pos-sessing a spirobenzofuranoid skeleton was isolated from the stems of Kadsura coccinea.Its structure and relative configuration were determined by X-ray diffraction analysis.     

CuNaY分子筛的制备及其催化甲醇氧化羰基化

采用多种铜盐溶液与NaY分子筛离子交换制备了CuNaY催化剂,通过加入氨水提高溶液pH值以及高温活化,显著提高了该催化剂对甲醇氧化羰基化合成碳酸二甲酯的反应活性。不同的铜盐水溶液交换制备的CuNaY催化剂催化活性不同,添加氨水将溶液pH值调节为11后,离子交换制备的CuNaY催化剂的催化活性和DMC选择性明显升高且趋于一致。经元素分析、XRD、XPS和H₂-TPR表征可知,加入氨水可促进Cu²⁺离子交换的进行,提高CuNaY催化剂中Cu的交换量,催化剂中约75%的Cu²⁺定位于分子筛的超笼中。     

Synthesis and Properties of Novel Luminescent Compounds Containing Triphenylamine and Bipyridine Units

Blue luminescent compounds T1-T4 containing triphenylamine donors,bipyridine acceptors and olefinic linkers were synthesized and characterized by 1H NMR,13C NMR and high resolution mass spectrometry(HR...     

非晶态合金Ni64B36结构的计算机模拟(Ⅰ)——合金中的化学短程序

我们用两种不同直径球的无规密堆计算机模型模拟了Ni₆₄B₃₆金属玻璃的结构,计算了模型的简约部分径向分布函数、角分布函数及均匀度,对结构的化学短程序进行了讨论,我们的计算结果表明,在过渡金属-类金属型(TM-M)的非晶态合金中,类金属原子的相对分布是结构中化学短程序的重要特征,这一特征可以用M-M原子的部分径向分布函数中第二峰的第一个分裂次峰的位置r_c来表征。 关键词：     

α-AlPO4晶体弹性温度特性的研究

研究了用缓慢升温法生长的α-AlPO₄晶体的弹性温度特性。测量采用传输法,测温范围为-30—150℃;用最小二乘法拟合弹性-温度曲线;用电子计算机处理数据。给出了弹性常数c_ij和s_ij(i,j=1,2,…,6)的温度特性方程以及T₀=25℃时的一级、二级和三级温度系数。 关键词：     

非晶态合金Ni64B36结构的计算机模拟(Ⅱ)——边界条件对模型结构的影响

本文用计算机制作的模拟Ni₆₄B₃₆非晶态合金的结构模型作为初始位形,分别在自由边界、固定边界、周期边界和准动态平衡边界条件下,用不同于以往的松弛方法进行了能量极小化计算。通过分析和对比松弛前后各模型的各种结构参数的变化,讨论了各类边界条件对松弛模型结构的影响。 关键词：     

面内磁场对硬磁泡形成的影响

实验研究了面内磁场对一次脉冲偏磁场作用下外延石榴石薄膜中硬磁泡形成的影响,发现存在一个使硬磁泡不再形成的临界面内磁场H_in⁰,它与材料参量有关,通过实验,运用面内磁场对条状畴的作用和枝状畴的形成,定性解释了软硬磁泡形成的分界场H_[b]随面内磁场增大、快降以及缓降这三个物理过程。 关键词：     

由隧道电子谱微分电导极大值确定超导体能隙的新方法

本文给出一种确定超导体能隙的新方法,由隧道理论计算出V_max/kT与Δ/kT的关系曲线,微分电导极大值电压V_max由隧道电子谱测定,由V_max/kT值及上述曲线很容易计算出能隙Δ值。这种方法很简单,而准确度几乎接近于曲线拟合法。 关键词：