新型双极有机小分子化合物及其Al3+配合物的合成与发光

合成了一种新的具有“双极”(bipolar)性质的有机小分子蓝色发光材料2-(5-(4-(二苯胺基)苯基)-1,3,4-噁二唑-2-)苯酚［2(5-(4-(diphenylamino)phenyl)-1,3,4-oxadiazol-2-yl)phenol, HPOT］, 并以HPOT为配体, 与铝离子配位, 合成了三(2-(5-(4-(二苯胺基)苯基) 1,3,4-噁二唑-2-)苯酚)合铝［tri(2-(5-(4-(diphenylamino)phenyl)-1,3,4-oxadiazol-2-yl)phenonate)aluminum, AlPOT］配合物. 用 1 H NMR、 HRMS和元素分析进行了表征, 并测定了两种化合物的光致发光性质和热稳定性. 结果表明: 两种新化合物的热稳定性好, 光致发光性能优良, 是制作有机电致发光器件的候选材料.     

TRANSIENT PHOTOCHEMISTRY OF NEUTRAL RED

Abstract— Flash photolysis of neutral red between pH 1.3 and pH 11 yields the triplet species ³DH₂⁺²³DH⁺ and ³D. Both ³DH₂⁺² and ³D exhibit first order decay with rate constants of 1.6 ± 0.3 × 10⁴ s^-1 but ³DH⁺ decays within the lifetime of the flash. Over the entire pH range, ascorbic acid quenches the triplet, forming the semireduced radicals DH₃⁺² DH₂⁺ and DH, all of which exhibit second order decay with k = 1.8 ± 0.4 ± 10⁸ M ^-1s^-1 most probably by recombination with semioxidized ascorbic acid. The dependence of the rate of decay of radical neutral red on the identity of reversible reductants supports the back-electron transfer mechanism, as does digital simulation of complex radical disproportionation schemes. In contrast to the efficient reduction of triplet neutral red by ascorbic acid, its reduction by EDTA is quite inefficient.     

PHOTOACTIVITY OF TRANSIENT INTERMEDIATES IN THE PATHWAY FROM THE RED-ABSORBING TO THE FAR-RED-ABSORBING FORM OF Avena PHYTOCHROME AS OBSERVED BY A DOUBLE-FLASH TRANSIENT-SPECTRUM ANALYZER

Abstract— Phototransformation from the red-absorbing form of phytochrome (Pr) to the far-red-absorbing form occurs via at least two reaction stages. We report here on the photoactivity of the intermediates present during these two stages, as detected with 114/118-kdalton Avena phytochrome by a transient spectrum analyzer with two actinic lasers of microsecond duration. Flash activation of intermediates present during the first stage results in their photoconversion back to Pr within the time resolution provided by the analyzer, which is 10 μs. Since these intermediates are present within 60 ns of excitation of Pr (Cordonnier et al. , 1981), a single flash of ms duration as used here should yield a photostationary equilibrium between them and Pr. The proportion of Pr converted to intermediates by a single saturating flash is estimated to be about 30%. Flash activation of intermediates present during the second stage converts them to another transient intermediate stage, which decays thermally to Pr within 2 ms.     

非甾体抗炎药对映体在多糖衍生物手性固定相上的拆分

在共价键合多糖类衍生物的手性固定相(Chiralpak IA,Chiralpak IB,Chiralpak IC)和涂敷型多糖衍生物的手性固定相(Chiralpak AD,Chiralcel OD)上,对非甾体抗炎药物(non-steroidal anti-inflammatory drugs,NSAIDs)进行了对映体拆分.色谱条件:流动相为10%异丙醇/正己烷(V/V)含0.1%三氟乙酸(Chiralpak AD,2%异丙醇/正己烷(V/V)含0.1%三氟乙酸(Chiralpak OD),异丙醇(四氢呋喃、乙酸乙酯、二氯甲烷)/正己烷/0.1%三氟乙酸(Chiralpak IA,Chiralpak IB,Chiralpak IC);流速为1.0 mL/min;紫外检测波长为254 nm.比较了非甾体抗炎药在直链淀粉-三(3,5-二甲基苯基氨基甲酸酯)衍生的手性固定相Chiralpak IA和 Chiralcel AD,纤维素-三(3,5-二甲基苯基氨基甲酸酯)衍生的手性固定相Chiralpak IB和Chiralcel OD上的对映体拆分.结果表明,非甾体抗炎药在Chiralpak IA和Chiralpak IB上的分离效果普遍低于Chiralpak AD和Chiralcel OD.     

铬酸及硝酸混合液处理以增强碳纳米管场发射

为了修饰碳纳米管(CNTs)的表面型态及改变碳纳米管的表面结构, 进一步增强碳纳米管的场发射特性, 使用铬酸及硝酸的混合溶液对碳纳米管进行后处理. 采用SEM、TEM、Raman 和EDS测试手段对样品的形貌、表面成份组成和微观结构特征进行了表征. 场发射(FE)的数据显示, 经过铬酸及硝酸的混合溶液处理20 min的碳纳米管场发射电流比未经任何处理的碳纳米管场发射电流明显增加一个数量级以上, 场发射电流增强的主要原因为样品上的碳纳米管的表面型态的改变, 造成碳纳米管场发射增强因子茁的增大. 与单独使用硝酸溶液后处理比较, 使用铬酸及硝酸的混合溶液对碳纳米管进行后处理可以得到较高的场发射电流及较低的起始电场. 铬酸及硝酸的混合溶液处理方法能经济且有效增强碳纳米管的场发射特性.     

EFFECT OF STRESS-STRAIN CURVE OF MATERIAL ON SOLUTION OF PLANE-STRESS PROBLEMS WITH LARGE PLSTIC DEFORMATION

本文首先将以前所得到的关于两个轴对称塑性平面应力问题(薄圆环和旋转盘)的有关方程和计算结果作了一个简单的叙述.这些计算结果是根据两种不同硬化特性的材料和一种理想塑性材料的应力应变曲线在不同负荷下计算得到的.这些结果指出这三种不同材料的应力应变曲线和负荷对于这两个问题的主应力比值和比例应变的影响很小,而对于比例应力的影响则很大.之后,分析了二维的塑性平面应力问题的方程;这些方程考虑了大应变,但不包括体积力(body force).分析这些方程中的包括材料应力应变曲线项和载荷数项的结果,认为假若在边界上的主应力的比值和比例应变不变,则材料的应力应变曲线和载荷对于主应力比值和比例应变的分布的影响可能不大,而对于比例应力的影响则很大.这种边界条件在实际问题中的普通加减下,满足的可能想是很大的.薄圆环和旋转盘的边界条件及所得的结果和这分析的结果是完全一致的.从这些结果并可提出一个简单而相当准确的近似解,最后并将本文所得的结果和依留辛(Ильюшии)的理论——关于小应变下三维问题形变理论的应用条件——作了比较.     

分层不动点及变分不等式的粘性方法及应用

介绍了处理变分不等式问题的一种分层不动点的粘性方法．这一方法所涉及的映像是非扩张的,而其解是从另一非扩张映像的不动点集中求出．在文末,还把这一结果应用于研究单调变分不等式问题、凸规划问题、分层极小化问题及在不动点集上的二次极小化问题．     

眼镜蛇(Naja naja atra)毒膜毒素MT-Ⅰ的生物学效应研究

从眼镜蛇（Ｎａｊａｎａｊａａｔｒａ）毒中纯化出膜毒素ＭＴ－Ⅰ,该毒素与磷脂酶Ａ２产生协同溶血效应,使小鸡颈二腹肌等标本产生进行性挛缩,对体外Ｈｕｔ－７８细胞有杀伤作用,腹腔注射能引起家猫的心电图异常     

Mg原子3p3/2nd系列自电离分支比的研究

利用多通道量子亏损理论(MQDT),结合已知的K矩阵,研究了受实验条件限制目前无法得到的Mg原子3p3/2nd(J=1,3)系列的自电离分支比,同时对3pnd系列的部分自电离光谱作了计算,并取得了和实验比较吻合的结果。结合分支比研究结果探讨了Mg原子的能级结构特点及粒子数反转的可能性     

CONTROLLING GROUNDWATER QUALITY WITH ENDOGENOUS REGULATORY INSTRUMENTS

ABSTRACT. This research presents a competitive dynamic model that endogenously evaluates the economics of regulatory tax-policy options. This model is then applied to an irrigated corn production area west of Kearney, Nebraska, where the average groundwater contamination level from nitrates is reported to be 8.7 parts per million (ppm). Results indicate that no regulatory policies are necessary for maintaining potable groundwater quality with either a surge-flow irrigation system or a sprinkler irrigation system. In areas where conventional furrow irrigation technology is being used, higher net economic benefits result from the adoption of a variable-tax on nitrogen fertilizer use, followed by a constant-unit tax and a pollution tax.