4-[(E)-2-(3, 4-二甲氧基苯基)乙烯基]苯氧基乙酸乙酯的合成及其NMR研究

以对硝基甲苯、3, 4-二甲氧基苯甲醛为起始原料,经过缩合,还原,重氮化水解,亲核取代反应,最终合成了新的化合物4-[(E)-2-(3, 4-二甲氧基苯基)乙烯基]苯氧基乙酸乙酯,用¹H 和¹³C NMR及多种二维核磁共振谱确定了该化合物的结构,完成了¹H 和¹³C NMR的归属,给出了分子中各氢,碳原子的准确化学位移.     

S空位调节扶手型二硫化钼纳米带的电子性质

二硫化钼纳米带按边界结构特征可分为锯齿型和扶手型,在制备过程中,不可避免地会存在一定的缺陷,其中硫空位(VS)最为常见,它将改变纳米结构,进而影响其电子性质。本文采用密度泛函理论来研究S空位对扶手型二硫化钼纳米带性质的影响。计算结果表明：纯扶手型二硫化钼纳米带（AMoS2NRs）为非磁性半导体,但其物性受S空位的位置及浓度所调制。当S空位出现在纳米带内部时,其性质不变。但当S空位在纳米带边缘时,AMoS2NRs被调节成半金属;并随着S空位的浓度的增加,其物性从半金属转变为稀磁半导体。这一有趣的发现将使得低维MoS2纳米材料在自旋电子学上有更宽广的应用。     

火焰原子吸收光谱法测定几种清泻去湿药材的微量元素

用硝酸-高氯酸的混合酸对车前草、泽泻、乌元参、茯苓4种药材进行处理,用火焰原子吸收光谱法测定其中Ca、Mg、Fe、Zn、Mn、Co 6种微量元素。样品加标回收率在96.0%—103.5%之间,相对标准偏差（RSD）小于3.2%,该方法测量简便、准确,结果可靠。     

Application of EDXRF Method in Measurement of Fe Content in Aqueous Fe Sample

介绍了能量色散X荧光分析方法在含水Fe样品测量中的应用.用ANTG -2000型海底X荧光探测系统对含Fe为10％～60％的Fe样进行测量,建立水分对Fe元素特征K α射线影响的校正模型.结果表明,通过该模型校正,对含饱和水情况下Fe样品的分析相对误差小于4％,具有良好的分析效果.     

Corannulene derivatives for organic electronics: From molecular engineering to applications

This paper intends to provide an overview for using corannulene derivatives in organic electronics such as organic field-effect transistors (OFETs), organic solar cells (OSCs), and organic light-emitting diodes (OLEDs). We highlight the rational design strategies, tuning molecular orbital energy levels and arrangement in single crystals of corannulenes. The topological structure and properties of corannulene make it a unique candidate for organic electronics.     

Surface solitons supported by one-dimensional composite Bessel optical lattices

We address the existence of surface solitons at an interface in a defocusing cubic medium with an imprinted one-dimensional （1D） composite Bessel optical lattice. This setting is composed of two Bessel lattices with different orders and different modulation depths, separated beside both sides of an interface. Stability analysis and numerical propagation simulations prove that solitons supported by the model are dynamically stable in the entire domain of their existence. The order of lattice determines the shape of soliton, and the amplitude of soliton depends on the lattice modulation depth. The experimental realization of the scheme is also proposed. Our results may provide another effective way of controlling the shapes of surface solitons and thus their evolutions by introducing a new freedom degree.     

色散磁导率对异向介质中的调制不稳定性的影响

基于Drude模型研究了异向介质的色散磁导率对调制不稳定性的影响. 结果表明，在反常色散情形，赝五阶非线性在异向介质的负折射区中增大了调制频谱的范围及增益值，这与常规正折射介质中出现的现象正好相反；自陡峭效应在异向介质中有可能为负值，但无论正负，也无论在正折射区还是负折射区，它都抑制调制不稳定性的产生；二阶非线性色散效应在正、负折射区中分别促进和抑制调制不稳定性的产生. 在正常色散情形，由于二阶非线性色散效应的作用，使本来在常规正折射介质中不可能出现的调制不稳定性现象也能出现，这一特性为在正常色散区形成孤     

圆柱状铁磁体中的偶极-交换自旋波

对于轴向磁化的圆柱状铁磁体,同时考虑偶极作用和交换作用,得到了偶极-交换自旋波的本征方程,给出了频谱的数值结果。当自旋波波矢β较小,即偶极能起主要作用时,相当于静磁模的结果,β较大,即交换能起主要作用时,过渡到宏观自旋波交换模理论的结果。     

Giant extended pi-conjugated dendrimers containing the 10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene chromophore: synthesis, NMR behaviors, optical properties, and electroluminescence

This paper reports the facile synthetic strategy of a series of novel pi-conjugated dendrimers (G0 and G1) based on 10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) in which the benzene cores are generated "in-situ" from acetyl aromatics by the acid-promoted cyclotrimerizations. The unique NMR behaviors, physical properties, and electroluminescence device applications are also presented. Besides the purity, the structure, and the confirmation of the successful formation and isolation of desired compounds by clear assignments of every molecule by (1)H and (13)C and 2D NMR characterizations, several astonishing NMR behaviors have been observed in various solvents. For 1, chemical shift values belonging to H-2' of hexyl substituents move to the most upfield; however, such chemical shift values move from 0.48 to 0.85 ppm when pyridine-d(5) or benzene-d(6) is used as solvent. Our dendrimers as the emissive layers in organic light-emitting diodes gave blue-green light with an external quantum efficiency up to 0.16% both for G0 and for G1 in nitrogen, respectively, which exhibit unique electroluminescence spectra in comparison with their corresponding photoluminescence ones.     

脉冲激光沉积的金属原子团簇的电子状态及生长的研究

 介绍了采用X射线光电子谱(XPS)等技术研究脉冲激光沉积在Ni、Mo、C、NaCl(100)表面的Cu、Au原子团簇的电子状态;结合Cu₂p_3/2 X射线光电子谱峰和Cu L₃M_4,5M_4,5俄歇跃迁分离了电子结合能的初态和终态贡献,得出了它们随Cu表面浓度变化的关系,并对之作出了解释。使用XPS、RBS、TEM三项技术研究了Au在NaCl(100)表面的生长过程,通过计算得出了在不同表面浓度下Au原子团簇的平均高度和表面覆盖率。