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181.
G. Garcia-Belmonte J. Bisquert L. M. Navarro J. R. Jurado F. M. B. Marques 《Ionics》1995,1(5-6):377-383
In ionic conductors, long range-migrating charges are a main cause of polarization processes. This has complicated, up to
date, the study of ionic thermocurrents (ITC) in solid electrolytes. However, the method is appealing, as it probes directly
charge-formation phenomena that are important both from a scientific point of view and for applications.
This work reports on the observation of ITC in solid electrolytes. Under appropriate experimental conditions, the ITC response
of a zirconia sample electroded with platinum is a reproducible one, thus opening the way to a new characterization method
that may complement other well established methods, such as Impedance Spectroscopy and a number of electrochemical techniques.
The general trends of the response, which is composed of two well resolved ITC peaks, is discussed. One of them, taking place
at higher temperatures, conforms to the standard shape of a first order kinetics depolarization process.
Paper presented at the 2nd Euroconference on Solid State Ionics, Funchal, Madeira, Portugal, Sept. 10–16, 1995 相似文献
182.
183.
The micro element content of food is an important quality index due to the action of these elements on human health. In this
article, we discuss how to ensure the reliability of analytical data on micro elements in order to truly represent the condition
of food. Sampling, treatment of the analytical sample, selection of the analytical method, standard solution, and certified
reference material, blank test, calibration of the instrument and equipment, application of the quality control chart, assessment
of the final analytical result, and quality assurance system are briefly described.
Received: 5 July 2001 Accepted: 19 November 2001 相似文献
184.
185.
L. A. Sakhnovich 《Functional Analysis and Its Applications》2002,36(3):205-211
The conjecture according to which the mean energy of an equilibrium system in quantum theory exceeds the mean energy of the corresponding classical system is considered. It is rigorously proved that the conjecture holds for the potential well. The estimates for the mean energy of the potential well at high and low temperatures are of special interest. 相似文献
186.
Robert L. Jerrard Halil Mete Soner 《Calculus of Variations and Partial Differential Equations》2002,14(2):151-191
We study the Ginzburg-Landau functional
for , where U is a bounded, open subset of . We show that if a sequence of functions satisfies , then their Jacobians are precompact in the dual of for every . Moreover, any limiting measure is a sum of point masses. We also characterize the -limit of the functionals , in terms of the function space B2V introduced by the authors in [16,17]: we show that I(u) is finite if and only if , and for is equal to the total variation of the Jacobian measure Ju. When the domain U has dimension greater than two, we prove if then the Jacobians are again precompact in for all , and moreover we show that any limiting measure must be integer multiplicity rectifiable. We also show that the total variation
of the Jacobian measure is a lower bound for the limit of the Ginzburg-Landau functional.
Received: 15 December 2000 / Accepted: 23 January 2001 / Published online: 25 June 2001 相似文献
187.
B. MacMillan M. Halse M. Schneider L. Fardy Y. H. Chui B. J. Balcom 《Applied magnetic resonance》2002,22(2):247-256
Magnetic resonance imaging has rarely been applied to rigid polymeric materials, due primarily to the strong dipolar coupling and short signal lifetimes inherent in these materials. SPRITE (single point ramped imaging withT 1 enhancement) (B. J. Balcom, R. P. MacGregor, S. D. Beyea, D. P. Green, R. L. Armstrong, T. W. Bremner: J. Magn. Reson. A123, 131–134, 1996) is particularly well suited to imaging solid materials. With SPRITE, the only requirement is thatT 2* be long enough so that the signal can be phase-encoded. The minimum phase encoding time is limited by the maximum gradient strength available and by the instrument deadtime. At present this is usually tens of microseconds and will only improve with refinements in technology. We have used the SPRITE sequence in conjunction with raising the sample temperature to obtain images of rigid polymers that have largely frustrated conventional imaging methods. This approach provides a straightforward and reliable method for imaging a class of samples that, up until now, have been very difficult to image. 相似文献
188.
R. Gerbaldo G. Ghigo G. Giunchi L. Gozzelino F. Laviano E. Mezzetti 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):297-300
We present results from an extended magneto-optical (MO) analysis of two samples cut from high-density pellets of MgB2. The first sample was studied in order to show that no matter how large the sample is and despite the bulk granularity, the
material enters into a critical state in a crystal-like fashion. The second sample was chosen for the quantitative analysis.
A numerical approach based on an inverted 2D Biot-Savart model was used to calculate the current paths across the homogeneous
polycrystalline bulk, as well as in the vicinity and across some morphological defects. Local current densities in the homogeneous
part were estimated as a function of the applied magnetic field at different temperatures, in three regimes: below full penetration,
at full penetration and above full penetration, respectively. A hypothesis of interpretation of the apparent absence of magnetic
granularity inside the polycrystalline microstructure is presented. It is related to a critical state likely reached by a
network of strongly coupled Josephson junctions.
Received 31 May 2001 and Received in final form 5 December 2001 相似文献
189.
R. Enberg L. Motyka G. Poludniowski 《The European Physical Journal C - Particles and Fields》2002,26(2):219-228
Diffractive heavy vector meson photoproduction accompanied by proton dissociation is studied for arbitrary momentum transfer.
The process is described by the non-forward BFKL equation, for which a complete analytical solution is found, giving the scattering
amplitude. The impact of non-leading corrections to the BFKL equation is also analysed. Results are compared to the HERA data
on production.
Received: 2 July 2002 / Revised version: 29 August 2002 / Published online: 18 October 2002 相似文献
190.
Ivonin I. V. Krasil'nikova L. M. Lavrent'eva L. G. Porokhovnichenko L. P. 《Russian Physics Journal》2002,45(5):493-497
Experimental proofs of asymmetric trapping of atoms at the growth step in vapor-phase epitaxy of gallium arsenide in the GaAs–AsCl3–H2 system are given. The data obtained confirm the important role of the surface diffusion mass transfer in the growth of epitaxial GaAs layers on vicinals in the neighborhood of (111)A. The effective diffusion length is estimated. 相似文献