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921.
The prepared amorphous
γ-ZrP\SiO2 composite had a complicated composition,
since a part of γ-ZrP is converted to α-form during the exfoliation
of it. The γ-ZrP\SiO2 composite have specific surface
area of 421 m2g–1.
The acidic P–OH groups of the lamellae species placed on the surface
(it is ≈1.0 meq g–1), do not destroy until
the temperature of 1030 K. During the thermal treatment the total mass loss
of 7.79% was found. This value corresponds to 0.42 mole of H2O
per molecule unit. The water loss process was found very slow, because of
the placing of bilamellar species in the composite. 相似文献
922.
I. P. Dobrovol’skaya M. V. Mokeev Yu. N. Sazanov A. V. Gribanov T. E. Sukhanova 《Russian Journal of Applied Chemistry》2006,79(8):1312-1315
Variation of the supramolecular structure of heat-resistant polymide films in the course of high-temperature treatment was studied by X-ray diffraction analysis and NMR spectroscopy in solids. 相似文献
923.
V. M. Lembrikov V. V. Volkova G. P. Zhavoronkova L. V. Konyakhina 《Russian Journal of Applied Chemistry》2006,79(2):196-200
Data on the equilibrium distribution of phosphoric acid among the aqueous and organic phases in extraction of phosphoric acid with tri-n-butyl phosphate are presented for the system constituted by phosphoric acid produced from the Khibiny concentrate and by the extracting agent from the industrial system for purification of extraction phosphoric acid at 25–50°C. 相似文献
924.
Experimental data on the equilibrium and dynamics of chemisorption of vapors of organic substances on a silica gel modified with color reagents are presented. 相似文献
925.
926.
A one-dimensional nanodusty plasma was modeled by self-consistently coupling a plasma model with nanoparticle growth, charging,
and transport models. As nanoparticles grow from subnanometer to tens of nm in diameter, the numerical results predict a rich
spatiotemporal structure, including four distinct temporal phases: a charge-limited phase, a charge accumulation phase, an
early ion drag phase, and a sheath interaction phase. 相似文献
927.
A theory that predicts the effect of the counterion size on the swelling and collapse of a weakly charged polyelectrolyte gel was developed. In addition to excluded-volume interactions between monomer units of the gel, the theory involves the counterion-monomer unit and counterion-counterion interactions in terms of the virial approximation. The character of interactions between different units in the system varies from repulsion to attraction depending on the type of solvent, counterion, and dielectric permittivity of the solvent. For solvents with a low permittivity, the effect of condensation of counterions resulting in the formation of ion pairs is taken into account. 相似文献
928.
B. D. Kabulov K. A. Akhundzhanov F. U. Yunusov O. A. Shpigun S. S. Negmatov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(3):354-356
The hydrolytic polycondensation of tetraethoxysilane in the presence of various polymers (polyacrylonitrile, polycaproamide, and chitosan) as templates was performed with the use of the sol-gel technology to obtain nanohybrid composite polymer-silica sorbents-nanofractals. 相似文献
929.
930.
E. Baggio Saitovitch F. J. Litterst I. Souza Azevedo R. B. Scorzelli 《Hyperfine Interactions》1989,50(1-4):529-535
The Mössbauer spectra of YBa2(Cu1?x Fe x )3O7 at room temperature show several doublets attributed to Fe in Cu(1) sites with different oxygen configurations. Here we present a systematic study performed at 4.2 K forx=0.005, 0.01, 0.03, 0.05, 0.10, 0.15. To obtain information about the magnetic ordered state two samples, withx=0.005 andx=0.15, have been studied at 4.2 K underB ext=5 T. The Mössbauer spectra indicate that the iron moments are polarized forx=0.005, while in the ordered state (x=0.15) they have an antiferromagnetic or spin-glass-like arrangement with high anisotropy. 相似文献