全文获取类型
收费全文 | 717247篇 |
免费 | 6436篇 |
国内免费 | 2573篇 |
专业分类
化学 | 357617篇 |
晶体学 | 10058篇 |
力学 | 36622篇 |
综合类 | 89篇 |
数学 | 103990篇 |
物理学 | 217880篇 |
出版年
2021年 | 5982篇 |
2020年 | 6569篇 |
2019年 | 7320篇 |
2018年 | 13806篇 |
2017年 | 14163篇 |
2016年 | 15936篇 |
2015年 | 8256篇 |
2014年 | 12835篇 |
2013年 | 29666篇 |
2012年 | 25611篇 |
2011年 | 34176篇 |
2010年 | 24298篇 |
2009年 | 24150篇 |
2008年 | 31560篇 |
2007年 | 33284篇 |
2006年 | 24263篇 |
2005年 | 24393篇 |
2004年 | 21198篇 |
2003年 | 19418篇 |
2002年 | 18356篇 |
2001年 | 18751篇 |
2000年 | 14742篇 |
1999年 | 11148篇 |
1998年 | 9644篇 |
1997年 | 9454篇 |
1996年 | 9007篇 |
1995年 | 8029篇 |
1994年 | 8078篇 |
1993年 | 7729篇 |
1992年 | 8273篇 |
1991年 | 8680篇 |
1990年 | 8239篇 |
1989年 | 8130篇 |
1988年 | 7922篇 |
1987年 | 7627篇 |
1986年 | 7395篇 |
1985年 | 9575篇 |
1984年 | 9946篇 |
1983年 | 8364篇 |
1982年 | 8777篇 |
1981年 | 8205篇 |
1980年 | 7784篇 |
1979年 | 8335篇 |
1978年 | 8710篇 |
1977年 | 8542篇 |
1976年 | 8563篇 |
1975年 | 8111篇 |
1974年 | 8027篇 |
1973年 | 8386篇 |
1972年 | 6190篇 |
排序方式: 共有10000条查询结果,搜索用时 20 毫秒
991.
Chalcones have been synthesized under sonochemical irradiation by Claisen-Schmidt condensation between benzaldehyde and acetophenone. Two basic activated carbons (Na and Cs-Norit) have been used as catalysts. The effect of the ultrasound activation has been studied. A substantial enhancing effect in the yield was observed when the carbon catalyst was activated under ultrasonic waves. This “green” method (combination of alkaline-doped carbon catalyst and ultrasound waves) has been applied to the synthesis of several chalcones with antibacterial properties achieving, in all cases, excellent activities and selectivities. A comparative study under non-sonic activation has showed that the yields are lower in silent conditions, indicating that the sonication exerts a positive effect on the activity of the catalyst. Cs-doped carbon is presented as the optimum catalyst, giving excellent activity for this type of condensation. Cs-Norit carbon catalyst can compete with the traditional NaOH/EtOH when the reaction is carried out under ultrasounds. The role of solvent in this reaction was studied with ethanol. High conversion was obtained in absence of solvent. The carbons were characterized by thermal analysis, nitrogen adsorption and X-ray photoelectron spectroscopy. 相似文献
992.
Specific molecules in cardiac tissue of spontaneously hypertensive rats are studied by using time-of-flight secondary ion mass spectrometry (TOF-SIMS). The investigation determines phospholipids, cholesterol, fatty acids and their fragments in the cardiac tissue, with special focus on cardiolipin. Cardiolipin is a unique phospholipid typical for cardiomyocyte mitochondrial membrane and its decrease is involved in pathologic conditions. In the positive polarity, the fragments of phosphatydilcholine are observed in the mass region of 700-850 u. Peaks over mass 1400 u correspond to intact and cationized molecules of cardiolipin. In animal tissue, cardiolipin contains of almost exclusively 18 carbon fatty acids, mostly linoleic acid. Linoleic acid at 279 u, other fatty acids, and phosphatidylglycerol fragments, as precursors of cardiolipin synthesis, are identified in the negative polarity. These data demonstrate that SIMS technique along with Au3+ cluster primary ion beam is a good tool for detection of higher mass biomolecules providing approximately 10 times higher yield in comparison with Au+. 相似文献
993.
A. A. Maleev 《Computational Mathematics and Mathematical Physics》2006,46(12):2031-2039
Stationary and nonstationary Jacobi-like iterative processes for solving systems of linear algebraic equations are examined. For a system whose coefficient matrix A is an H-matrix, it is shown that the convergence rate of any Jacobi-like process is at least as high as that of the point Jacobi method as applied to a system with 〈A〉 as the coefficient matrix, where 〈A〉 is a comparison matrix of A. 相似文献
994.
In this work, the optical and structural properties of high k materials such as tantalum oxide and titanium oxide were studied by spectroscopic ellipsometry, where a Tauc-Lorentz dispersion model based in one (amorphous films) or two oscillators (microcrystalline films) was used. The samples were deposited at room temperature by radio frequency magnetron sputtering and then annealed at temperatures from 100 to 500 °C. Concerning the tantalum oxide films, the increase of the annealing temperature, up to 500 °C does not change the amorphous nature of the films, increasing, however, their density. The same does not happen with the titanium oxide films that are microcrystalline, even when deposited at room temperature. Data concerning the use of a four-layer model based on one and two Tauc-Lorentz dispersions is also discussed, emphasizing its use for the detection of an amorphous incubation layer, normally present on microcrystalline films grown by sputtering. 相似文献
995.
The oxide films formed on AISI 304L stainless steel at 300 °C in the oxidation time range between 2 and 4 h have been studied by photoelectrochemistry. Photocurrents were investigated as a function of the wavelength of the incident light and the electrode potential. The investigation allowed the determination of the semiconductive properties of the oxides. The oxide films showed n-type behaviour. A duplex structure of the oxide films has been suggested on the basis of the photocurrent spectra, with an internal oxide layer having an optical gap (Eg2 = 2.16-2.3 eV) depending on the applied potential and oxidation time, higher to that of the external oxide layer (Eg1 ≈ 1.9 eV). Significant variations in the amplitude of the photocurrent were detected as a function of the applied potential and the oxidation time. 相似文献
996.
Yu. D. Perfiliev V. S. Rusakov L. A. Kulikov A. A. Kamnev K. Alkhatib 《Hyperfine Interactions》2006,167(1-3):881-885
To explain line broadening in emission Mössbauer spectra as compared to the corresponding absorber measurements, the model of trapped electrons has been proposed. Auger electrons (emitted, e.g. after electron capture by 57Co or after the converted isomeric transition of 119mSn), as well as secondary electrons, may be trapped in the proximity to the nucleogenic ion. Electrons captured by lattice traps at different distances from the daughter ion induce an asymmetric distribution of quadrupole splitting in the resulting emission spectra, as shown in a few examples. This model is supported by estimates of quadrupole splitting values which may be caused by such trapped electrons located at specified distances from the nucleogenic atom. 相似文献
997.
The electro-optic response of ferroelectric smectic C* liquid crystals has been studied. Anomalous switching behaviour of such materials which possess a negative dielectric anisotropy has been reported. These materials show a minimum in response time at a sufficiently high field. We present results showing the dependency of this minimum upon spontaneous polarisation and the effect of AC bias. Calculations based upon the equation of motion of the director around the cone are presented which describe this effect and its dependence on the relative magnitudes of the spontaneous polarization and dielectric anisotropy of the material. Good agreement with the experimental results is found. 相似文献
998.
999.
1000.