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951.
952.
A. V. Barinov N. I. Pechurova L. I. Martynenko K. I. Popov V. I. Spitsyn 《Russian Chemical Bulletin》1977,26(6):1135-1138
Conclusions In solution, the complexes MII(NdA)2 do not have a polynuclear structure. In the conditions studied, hydroxo polynuclear complexes including EDTA and MII and Nd3+ ions are also not formed. Our results are not inconsistent with the hypothesis that the solid complex Ca(NdA)2·17H2O has a polynuclear structure and that the polynuclear character is successively weakened as Ca2+ is replaced by Sr2+ and Ba2+.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1235–1239, June, 1977. 相似文献
953.
Tran Quang Minh Léon Christiaens Pierre Grandclaudon Alain Lablache-Combier 《Tetrahedron》1977,33(17):2225-2229
Photoirradiated in presence of acetophenone, benzo[b]selenophene and its 3-methyl derivative add to dimethyl acetylenedicarboxylate. In each ease, the primary reaction product is unstable and has not been isolated. Photoexeited in its triplet state (the energy of which is in the neighbourhood of 69 ) benzo[b]selenophene and its 2- and 3-methyl, 2,3 dimethyl, 3 acetoxy and 2-methyl-3-acetoxy derivatives add to 1,2 dichloroethylene leading to cyclobutanes. Neither cyclo-addition occurs in absence of photosensitiser. Single-crystal X-ray analysis gave the structures of the two adducts of 3-acetoxybenzo[b]selenophene with trans-1,2-dichloroethylene. In both compounds the chlorine atoms are trans. 相似文献
954.
Russian Chemical Bulletin - 相似文献
955.
956.
957.
958.
959.
Alan D. Potoff Bertrand L. Chamberland Lewis Katz 《Journal of solid state chemistry》1973,8(3):234-237
A single crystal study of hydrothermally prepared eight-layer BaMnO3 has been carried out which confirms the (Zhdanov notation) 121121 layer stacking scheme for the BaO3 layers. The MnO6 octahedra share faces in strings of four, and these strings are connected to each other by corner sharing. The compound has an hexagonal unit cell of dimensions a = 5.667 ± 0.003 and c = 18.738 ± 0.009 Å, probable space group . Its structure has been determined from 352 independent reflections, of which 242 were considered observed, collected manually by a counter technique and refined to a conventional R value of 0.079. 相似文献
960.
Electrical resistivity (4.2–800°K) and magnetic susceptibility (4.2–500°K) measurements are carried out on Cu3–xAs, Cu5–xAs2 and the recently obtained, tetragonal Cu2As. All three compounds appear to be metallic conductors, but have high residual resistances because of the large defect concentrations (resulting from non-stoichiometry and preparation method). Cu3–xAs is diamagnetic; Cu5–xAs2 is Pauli-paramagnetic; Cu2As has a very small, constant, positive susceptibility above room temperature and a more pronounced Curie-Weiss behaviour at lower temperatures. The Pauli-paramagnetic contributions have been estimated. A slight anomaly in the electric and magnetic behaviour of Cu3–xAs is observed at 220°K. To clarify the high-temperature phenomena, a series of D.T.A. and X-ray experiments has also been carried out. 相似文献