ACQ‐to‐AIE Transformation: Tuning Molecular Packing by Regioisomerization for Two‐Photon NIR Bioimaging

The traditional design strategies for highly bright solid‐state luminescent materials rely on weakening the intermolecular π–π interactions, which may limit diversity when developing new materials. Herein, we propose a strategy of tuning the molecular packing mode by regioisomerization to regulate the solid‐state fluorescence. TBP‐e‐TPA with a molecular rotor in the end position of a planar core adopts a long‐range cofacial packing mode, which in the solid state is almost non‐emissive. By shifting molecular rotors to the bay position, the resultant TBP‐b‐TPA possesses a discrete cross packing mode, giving a quantum yield of 15.6±0.2 %. These results demonstrate the relationship between the solid‐state fluorescence efficiency and the molecule's packing mode. Thanks to the good photophysical properties, TBP‐b‐TPA nanoparticles were used for two‐photon deep brain imaging. This molecular design philosophy provides a new way of designing highly bright solid‐state fluorophores.     

Control of Absolute Stereochemistry in Transition-Metal-Catalysed Hydrogen-Borrowing Reactions

Hydrogen-borrowing catalysis represents a powerful method for the alkylation of amine or enolate nucleophiles with non-activated alcohols. This approach relies upon a catalyst that can mediate a strategic series of redox events, enabling the formation of C−C and C−N bonds and producing water as the sole by-product. In the majority of cases these reactions have been employed to target achiral or racemic products. In contrast, the focus of this Minireview is upon hydrogen-borrowing-catalysed reactions in which the absolute stereochemical outcome of the process can be controlled. Asymmetric hydrogen-borrowing catalysis is rapidly emerging as a powerful approach for the synthesis of enantioenriched amine and carbonyl containing products and examples involving both C−N and C−C bond formation are presented. A variety of different approaches are discussed including use of chiral auxiliaries, asymmetric catalysis and enantiospecific processes.     

Time-resolved resonance Raman identification and structural characterization of a light absorbing transient intermediate in the photoinduced reaction of benzophenone in 2-propanol

A nanosecond time-resolved resonance Raman (ns-TR3) spectroscopic study of the triplet state benzophenone reaction with the 2-propanol hydrogen-donor solvent and subsequent reactions is presented. The TR3 spectra show that the benzophenone triplet state (npi*) hydrogen-abstraction reaction with 2-propanol is very fast (about 10 to 20 ns) and forms a diphenylketyl radical and an associated 2-propanol radical partner. The temporal evolution of the TR3 spectra also indicates that recombination of these two radical species occurs with a time constant of about 1170 ns to produce a LAT (light absorbing transient) intermediate that is identified as the 2-[4-(hydroxylphenylmethylene)cyclohexa-2,5-dienyl]propan-2-ol (p-LAT) species. Comparison of the TR3 spectra with results obtained from density functional theory calculations for the species of interest was used to elucidate the identity, structure, properties, and major spectral features of the intermediates observed in the TR3 spectra. The structures and properties of the reaction intermediates observed (triplet benzophenone, diphenyl ketyl radical, and p-LAT) are briefly discussed.     

Impact of information technology on the performance of logistics industry: the case of Hong Kong and Pearl Delta region

Over the last decade, a number of research studies have advocated the use of information technology (IT) in different aspects of logistics and distribution operations. This study examines the current state of the use of IT and its impact on logistics service performance through a survey of 210 logistics companies in Hong Kong and the Pearl River Delta region. A hypothetical model is also proposed in which the theories of the market-based view and the resource-based view are applied to link up the implications of IT capabilities with logistic performance. The model was tested using structural equation modelling. The findings suggested that (i) IT implementation directly enhances the service quality of the logistics companies; (ii) the impact of IT implementation improves service quality thereby creating competitiveness.     

Challenges and Solutions in Fabrication of Silica-Based Photonic Crystal Fibers: An Experimental Study

Abstract

The fabrication process of photonic crystal fibers based on a stack-and-draw method is presented in full detail in this article. In addition, improved techniques of photonic crystal fiber preform preparation and fabrication are highlighted. A new method of connecting a handle to a preform using only a fiber drawing tower is demonstrated, which eliminates the need for a high-temperature glass working lathe. Also, a new technique of modifying the photonic crystal fiber structural pattern by sealing air holes of the photonic crystal fiber cane is presented. Using the proposed methods, several types of photonic crystal fibers are fabricated, which suggests potential for rapid photonic crystal fibers fabrication in laboratories equipped with and limited to only a fiber drawing tower.     

An artificial boundary method for the Hull-White model of American interest rate derivatives

The Hull-White (HW) model is a widely used one-factor interest rate model because of its analytical tractability on liquidly traded derivatives, super-calibration ability to the initial term structure and elegant tree-building procedure. As an explicit finite difference scheme, lattice method is subject to some stability criteria, which may deteriorate the computational efficiency for early exercisable derivatives. This paper proposes an artificial boundary method based on the partial differential equations (PDEs) to price interest rate derivatives with early exercise (American) feature under the HW model. We construct conversion factors to extract the market information from the zero-coupon curve and then reduce the infinite computational domain into a finite one by using an artificial boundary on which an exact boundary condition is derived. We then develop an implicit θ-scheme with unconditional stability to solve the PDE in the reduced bounded domain. With a finite computational domain, the optimal exercise strategy can be determined efficiently. Our numerical examples show that the proposed scheme is accurate, robust to the truncation size, and more efficient than the popular lattice method for accurate derivative prices. In addition, the singularity-separating technique is incorporated into the artificial boundary method to enhance accuracy and flexibility of the numerical scheme.     

Comparing the reliability of networks by spectral analysis

Topological effects on the confinement of a moving neutral particle with an induced electric dipole moment confined to a quantum ring and a two-dimensional quantum dot (described by a hard-wall confining potential) are investigated. It is shown in this work that the spectrum of energy depends on the geometric phase obtained by Wei et al. [H. Wei, R. Han, X. Wei, Phys. Rev. Lett. 75, 2071 (1995)] and persistent currents arise from this dependence in both the quantum ring and the quantum dot. Further, the behaviour of the analogue of the Landau system for a moving electric dipole confined to a two-dimensional quantum dot is discussed, and it is shown that persistent currents are absent in this case.     

Analysis of the rewriting time of liquid crystal optical rewritable e-paper

Theoretical and experimental analysis of the rewriting time of liquid crystal (LC) optical rewritable (ORW) e-paper was conducted. The equations of rewriting time of alignment molecule SD1 film with and without interaction with LC based on diffusion model were derived, which shows that the rewriting time of LC ORW e-paper could be shortened by enlarging light intensity or decreasing azimuthal anchoring energy. The rewriting time of pure SD1 films and LC ORW cells was measured under different light intensities. And LC ORW cells with different azimuthal anchoring energy were prepared for rewriting time measurement. A good agreement between experimental and theoretical results was obtained, which indicates that using larger light intensity and making LC cell with smaller azimuthal anchoring energy, ORW rewriting time could be decreased to the amount suitable for practical use.     

A Remarkable cis‐ and trans‐Spanning Dibenzylidene Acetone Diphosphine Chelating Ligand (dbaphos)

A multidentate and flexible diolefin–diphosphine ligand, based on the dibenzylidene acetone core, namely dbaphos ( 1 ), is reported herein. The ligand adopts an array of different geometries at Pt, Pd and Rh. At Pt^II the dbaphos ligand forms cis‐ and trans‐diphosphine complexes and can be defined as a wide‐angle spanning ligand. ¹H NMR spectroscopic analysis shows that the β‐hydrogen of one olefin moiety interacts with the Pt^II centre (an anagostic interaction), which is supported by DFT calculations. At Pd⁰ and Rh^I, the dbaphos ligand exhibits both olefin and phosphine interactions with the metal centres. The Pd⁰ complex of dbaphos is dinuclear, with bridging diphosphines. The complex exhibits the coordination of one olefin moiety, which is in dynamic exchange (intramolecular) with the other “free” olefin. The Pd⁰ complex of dbaphos reacts with iodobenzene to afford trans‐[Pd^II(dbaphos)I(Ph)]. In the case of Rh^I, dbaphos coordinates to form a structure in which the phosphine and olefin moieties occupy both axial and equatorial sites, which stands in contrast to a related bidentate olefin, phosphine ligand (“Lei” ligand), in which the olefins occupy the equatorial sites and phosphines the axial sites, exclusively.     

Inter-laboratory trials for analysis of perfluorooctanesulfonate and perfluorooctanoate in water samples: Performance and recommendations

The ISO 25101 (International Organization for Standardization, Geneva) describes a new international standard method for the determination of perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) in unfiltered samples of drinking and surface waters. The method is based on the extraction of target analytes by solid phase extraction, solvent elution, and determination by high performance liquid chromatography–tandem mass spectrometry (HPLC–MS/MS). For the determination of the performance of this method, more than 20 laboratories from 9 different countries participated in an inter-laboratory trial in 2006. In addition, inter-laboratory trials were conducted in 2008 and 2009 for the analysis of perfluoroalkylsubstances (PFASs), including PFOS and PFOA, in water samples by following the protocols of Japanese Industrial Standard (JIS). Overall, the repeatability coefficients of variation (i.e., within-laboratory precision) for PFOS and PFOA in all water samples were between 3 and 11%, showing a adequate precision of the ISO and JIS methods. The reproducibility coefficients of variation (i.e., between-laboratory precision) were found to vary within a range of 7–31% for surface water and 20–40% for wastewater. The recoveries of PFOS and PFOA, as a measure of accuracy, varied from 84 to 100% for surface water and from 84 to 100% for wastewater among the samples with acceptable criteria for internal standards recovery. The determined concentrations of PFASs in samples compared well with the “true” values. The results of the inter-laboratory trial confirmed that the analytical methods are robust and reliable and can be used as a standard method for the analysis of target compounds in water samples.