Two energy scales and slow crossover in YbAl3

Experimental results for the susceptibility, magnetization, specific heat, 4f occupation number, Hall effect, and magnetoresistance for single crystals of the intermediate valence (IV) compound YbAl3 show that, in addition to the Kondo temperature scale T(K) approximately 670 K, there is a low temperature scale T(coh) approximately 30-40 K for the onset of Fermi liquid coherence. Furthermore, the crossover from the low temperature Fermi liquid regime to the high temperature local moment regime is slower than predicted by the Anderson impurity model. We suggest that these effects are generic for IV compounds and we discuss them in terms of the theory of the Anderson lattice.     

Neutron diffraction evidence of microscopic charge inhomogeneities in the CuO2 plane of superconducting La2-xSrxCuO4 (0<or=x<or=0. 30)

High-resolution atomic pair distribution functions have been obtained using neutron powder diffraction data from La2-xSrxCuO4 over the range of doping 0相似文献   

Hydrogen bonding in polymer mixtures

The enthalpy–infrared frequency shift correlation for simple acids and bases is extended to study hydrogen bonding in polymer systems. The acidity of a polymer is calibrated by comparing the shifts in hydroxyl absorption frequency of the acidic polymer when mixed with a series of bases with the corresponding spectral shifts of known acids with the same bases. The basicity of a polymer is calibrated by measuring the hydroxyl frequency shifts of known acids when mixed with the basic polymer. For polymers containing carbonyl groups, the shift in carbonyl absorption is also a measure of basicity. The acidity and basicity constants obtained for polymers are in good agreement with the values for small-molecule analogs. The enthalpies of hydrogen bond formation in polymer mixtures are calculated from the acidity or basicity constants.     

数学规划及其应用在中国

The paper is divided into three parts: The first part gives a brief development of Mathematical Programming (M.P.) in China. The second part discribes a few aspects of the theoretical research work in M. P. in China. The third part gives some examples of the applications of M. P. methods in China.     

Low-temperature dispersion related to methylene units of a polymer main chain

Polymers containing dynamically isolated polymethylene segments of various lengths were obtained from the reaction of bisphenol-A-diglycidyl ether with α,ω-diamines. On the basis of the mechanical damping data of these polymers, it was established that the shortest polymethylene segment to show the ?125°C. γ dispersion, characteristic of polyethylene, must consist of at least five carbon atoms.     

Effects of phenolic compounds on gelation behavior of gelatin gels

The effects of phenolic additives on the gelation behavior of gelatin gels were investigated using thermomechanical analysis (TMA) for study of gel‐melting temperature, dynamic mechanical analysis (DMA) for study of gel‐storage modulus and gel‐aging stability, viscometry for study of gelation time, and texture analyzer for study of gel strength and gel melting. Thermodynamically, the addition of 1,3‐benzenediol, 1,4‐benzenediol or 1,3,5‐benzenetriol favored the gelation process of gelatin solutions (increases in T_m and aging stability) due to the introduction of extra physical crosslinks among gelatin chains through hydrogen bonding, while the addition of 1,2‐benzenediol had a negative effect (decreases in T_m and aging stability) possibly due to intra‐hydrogen bonding of the additive molecule itself. All the phenolic compounds had little effect on gel moduli. Kinetically, the introduction of 1,2‐benzenediol or 1,4‐benzenediol slowed the gelation process, while introduction of catechin, a polyphenol, accelerated the first stage of the gelation process. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 224–231, 2001     

Blends of nylon‐6 with phenol‐containing polymers

The miscibility of nylon‐6 with poly(4‐vinylphenol) (PVPh) or poly(1‐hydroxy‐2,6‐methylphenylene) (p‐Cl‐novolac) was studied with differential scanning calorimetry and small‐angle X‐ray scattering techniques. Both PVPh and p‐Cl‐novolac are miscible with nylon‐6 at the molecular level. The presence of the phenolic polymers affects the crystallization of nylon‐6 and suppresses its melting point. PVPh increases the long space order in crystalline nylon‐6 because it increases the thickness of the amorphous layers. In contrast, a small quantity of p‐Cl‐novolac tends to decrease the long space order. It seems that p‐Cl‐novolac distributed in the amorphous regions introduces more order in these regions and makes the amorphous layers thinner. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 841–850, 2001     

Dynamic pricing and warranty policies for products with fixed lifetime

We consider a repairable product with known market entry and departure times. A warranty policy is offered with product purchase, under which a customer can have a failed item repaired free of charge in the warranty period. It is assumed that customers are heterogeneous in their risk attitudes toward uncertain repair costs incurred after the warranty expires. The objective is to determine a joint dynamic pricing and warranty policy for the lifetime of the product, which maximizes the manufacturer’s expected profit. In the first part of the analysis, we consider a linearly decreasing price function and a constant warranty length. We first study customers’ purchase patterns under several different pricing strategies by the manufacturer and then discuss the optimal pricing and warranty strategy. In the second part, we assume that the warranty length can be altered once during the product lifetime in developing a joint pricing and warranty policy. Numerical studies show that a dynamic warranty policy can significantly outperform a fixed-length warranty policy.     

A comparison of average and discounted cost models for the dynamic lot size inventory problem

It is a common practice in the inventory literature to use average cost models as approximations to the theoretically correct discounted cost models. An average cost model minimizes the average undiscounted cost per period, while a discounted cost model minimizes the total discounted cost over the problem horizon. This paper attempts to answer an important question: How good are the results (the total discounted costs) for the average cost models compared to those for the discounted cost models? This question has been conclusively answered for the simplest inventory model where the demand rate and other parameters are assumed to remain constant in time. This paper addresses this issue for the first time for the case where demand rates are allowed to be nonstationary in time.A discounted cost model has been developed in the paper to carry out this comparison. It is shown that a simple dynamic programming algorithm can be used to find optimal order policies for the discounted cost model.The effect of the varying interest rates and other parameters on the relative performance of the average cost model has been studied by developing an insightful analysis and also by doing a computational study. The results show that, while the average cost model can cost as much as about 26% more than the discounted cost model in extreme cases, this increase is not significant for the parameter values in the range of the common interest.     

Thermal oxidation of blends of poly(ethylene oxide) and poly(methyl methacrylate)

Thermal oxidation of poly(ethylene oxide) (PEO) and its blends with poly(methyl methacrylate) (PMMA) were studied using oxygen uptake measurements. The rates of oxidation and maximum oxygen uptake contents were reduced as the content of PMMA was increased in the blends. The results were indicative of a stabilizing effect by PMMA on the oxidation of PEO. The oxidation reaction at 140°C was stopped at various stages and PMMA was separated from PEO and its molecular weights were measured by gel permeation chromatography (GPC). The decrease in the number-average molecular weight of PMMA was larger as the content of PEO increased in the blends. The visual appearance of the films suggested that phase separation did not occur after thermal oxidation. The activation energy for the rates of oxidation in the blends was slightly increased compared to pure PEO. © 1992 John Wiley & Sons, Inc.