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排序方式: 共有591条查询结果,搜索用时 0 毫秒
141.
H. Kwak G. H. Eom S. H. Lee H. G. Koo S. P. Jang J. Lee W. Shin M. S. Lah C. Kim S.-J. Kim Y. Kim 《Journal of Structural Chemistry》2010,51(5):923-930
Five new Ni(II) complexes with pyridine carboxamide ligands have been synthesized and the crystal structures of three of the complexes were determined. Strong distortion effects of 6-methyl substitution were observed in the complexes with 6-methyl-substituted pyridyl bpb ligands. The C-H...F and C-H...O hydrogen bond interactions build extended architectures in the crystals studied. This result suggests that the steric effect of 6-methyl substitution plays an important role in the distortion of the structure, and the 6-methyl substitution can facilitate hydrogen bond interactions between methyl hydrogen atoms and O(carbonyl) or F atoms. Twelve Ni(II) complexes, including seven complexes reported previously, show reversible redox behavior, implying that the reduced Ni(I) state of each complex is stable in the time scale of CV measurement. The steric effect of R1 substituent and the electronic effects of X1 and X2 groups were found to be the main factors contributing to the shift of the redox potential of the Ni(II) complexes 相似文献
142.
Kim WK Sul OJ Kwak JS Hur HY Latour AM Koller BH Kwon BS Jeong CS 《Experimental & molecular medicine》2010,42(12):805-810
Tumor necrosis factor receptor-related 2 (TR2, HVEM or TNFRSF-14) plays an important role in immune responses, however, the mechanisms regulating its expression are unclear. To understand the control of TR2 gene expression, we studied the upstream region of the gene. Gel supershift assays revealed inducible binding of nuclear factor of activated T cells (NFAT) to a putative NFAT site within the TR2 promoter. Furthermore, cotransfection of a dominant negative NFAT construct, or siRNA for NFAT, resulted in increased expression of a TR2 reporter gene. Our findings demonstrate that NFAT negatively regulates TR2 expression in activated T cells. 相似文献
143.
Henzie J Shuford KL Kwak ES Schatz GC Odom TW 《The journal of physical chemistry. B》2006,110(29):14028-14031
This paper reports the orientation-dependent optical properties of two-dimensional arrays of anisotropic metallic nanoparticles. These studies were made possible by our simple procedure to encapsulate and manipulate aligned particles having complex three-dimensional (3D) shapes inside a uniform dielectric environment. Using dark field or scattering spectroscopy, we investigated the plasmon resonances of 250-nm Au pyramidal shells embedded in a poly(dimethylsiloxane) (PDMS) matrix. Interestingly, we discovered that the scattering spectra of these particle arrays depended sensitively on the direction and polarization of the incident white light relative to the orientation of the pyramidal shells. Theoretical calculations using the discrete dipole approximation support the experimentally observed dependence on particle orientation with respect to incident field. This work presents an approach to manipulate--by hand--ordered arrays of particles over cm(2) areas and provides new insight into the relationship between the shape of well-defined, 3D particles and their supported plasmon resonance modes. 相似文献
144.
Yong-Sil?Kwak Sang-Woo?Park Han-Do?KimEmail author 《Colloid and polymer science》2003,281(10):957-963
Waterborne polyurethane–urea anionomers were prepared by polyaddition reaction using isophorone diisocyanate (IPDI), poly(tetramethylene ether) glycol (PTMG, Mn=1000), dimethylolbutanoic acid (DMBA), and hydrazine monohydrate (HD), ethylene diamine (EDA), 1,4-butane diamine (BDA) as a chain extender, followed by neutralization of pendant COOH groups by NH4OH/Cu(OH)2 or triethylamine (TEA) as a neutralizing agent. The effects of the types of neutralizing agent such as NH4OH/Cu(OH)2 and TEA with various chain extenders on the properties of waterborne polyurethane–urea ionomers were investigated. Two loss modulus peaks for all samples are observed owing to the glass transition temperature of soft segments (Tgs) and the glass transition temperature of hard segments (Tgh). The conductivity, Tgh, Tg, and tensile strength/modulus of TEA-based samples increased in the order of BDA>EDA>HD; however, those of NH4OH/Cu(OH)2-based samples increased in the order of HD>EDA>BDA. TEA-based film samples were found to have higher thermal stability, Tgh, Tg, tensile strength/modulus, and storage modulus than NH4OH/Cu(OH)2-based ones at the same chain extender. On the other hand NH4OH/Cu(OH)2-based samples had higher conductivity and stronger antibacterial halo than TEA-based samples. 相似文献
145.
J. H. Baek Y. K. Kwak S. H. Kim 《Archive of Applied Mechanics (Ingenieur Archiv)》2003,73(5-6):367-376
Summary The paper analyzes how the frequency bandwidth of a servo system is affected by the input voltage of its motor and the magnitude of the total backlash. The bandwidth of the system is defined as the set of antiresonance frequencies, which appears in the frequency-response characteristic. The change in the frequency-response characteristics is investigated depending on motor input voltage and the magnitude of the total backlash. It is shown that at infinite motor input voltage, the servo system has a bandwidth equivalent to that of a backlash-free system. The amount of the systems bandwidth reduction due to the backlash changes greatly with the motor input voltage. It becomes possible then to determine the necessary maximum input voltage of the motor and the admissible magnitude of the total backlash to satisfy the desired bandwidth for a servo system with a gear reducer. 相似文献
146.
147.
Asbury JB Steinel T Kwak K Corcelli SA Lawrence CP Skinner JL Fayer MD 《The Journal of chemical physics》2004,121(24):12431-12446
Vibrational echo correlation spectroscopy experiments on the OD stretch of dilute HOD in H(2)O are used to probe the structural dynamics of water. A method is demonstrated for combining correlation spectra taken with different infrared pulse bandwidths (pulse durations), making it possible to use data collected from many experiments in which the laser pulse properties are not identical. Accurate measurements of the OD stretch anharmonicity (162 cm(-1)) are presented and used in the data analysis. In addition, the recent accurate determination of the OD vibrational lifetime (1.45 ps) and the time scale for the production of vibrational relaxation induced broken hydrogen bond "photoproducts" ( approximately 2 ps) aid in the data analysis. The data are analyzed using time dependent diagrammatic perturbation theory to obtain the frequency time correlation function (FTCF). The results are an improved FTCF compared to that obtained previously with vibrational echo correlation spectroscopy. The experimental data and the experimentally determined FTCF are compared to calculations that employ a polarizable water model (SPC-FQ) to calculate the FTCF. The SPC-FQ derived FTCF is much closer to the experimental results than previously tested nonpolarizable water models which are also presented for comparison. 相似文献
148.
Hwang JW Kim JH Lee H Lee H Kim S Kwak J Do Y 《Journal of the American Chemical Society》2001,123(37):9054-9063
The synthesis and structural analysis of two novel families of three-component reversible redox cycles [(C(2)B(9)H(11))M(mu-SPh)(2)](2)(n)PPN(n) (M = Mo, n = 2-, 2; 1-, 3; 0, 4; and M = W, n = 2-, 6; 1-, 7; 0, 8), where the cleavage and re-formation of the carborane cage C-C bond is observed during the redox reaction, are reported. Electronic saturation of the metal center (18e center) and the lack of bulky substituents on the carborane cage suggest that the deformed carborane cages in 2.PPN(2), 6.PPN(2), and 7.PPN invoke a new kind of deformed cage ("semicloso" framework). The XPS results show that the unprecedented competition for electron density between the metal center and the carborane cage is involved in the cleavage and formation of the carborane C-C bond. 相似文献
149.
Ammar R Ball S Baringer P Coppage D Copty N Davis R Hancock N Kelly M Kwak N Lam H Kubota Y Lattery M Nelson JK Patton S Perticone D Poling R Savinov V Schrenk S Wang R Alam MS Kim IJ Nemati B O'Neill JJ Severini H Sun CR Zoeller MM Crawford G Daubenmeir M Fulton R Fujino D Gan KK Honscheid K Kagan H Kass R Lee J Malchow R Morrow F Skovpen Y Sung M White C Whitmore J Wilson P Butler F Fu X Kalbfleisch G Lambrecht M Ross WR Skubic P Snow J Wang PL Wood M Bortoletto D Brown DN Fast J McIlwain RL 《Physical review letters》1993,71(5):674-678
150.
Selen M Sadoff AJ Ammar R Ball S Baringer P Coppage D Copty N Davis R Hancock N Kelly M Kwak N Lam H Kubota Y Lattery M Nelson JK Patton S Perticone D Poling R Savinov V Schrenk S Wang R Alam MS Kim IJ Nemati B O'Neill JJ Severini H Sun CR Zoeller MM Crawford G Daubenmeir CM Fulton R Fujino D Gan KK Honscheid K Kagan H Kass R Lee J Malchow R Morrow F Skovpen Y Sung M White C Whitmore J Wilson P Butler F Fu X Kalbfleisch G Lambrecht M Ross WR Skubic P Snow J Wang PL Wood M Bortoletto D Brown DN 《Physical review letters》1993,71(13):1973-1977